DIN ISO 16000-14-2012 Indoor air - Part 14 Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins dibenz.pdf

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1、March 2012 Translation by DIN-Sprachendienst.English price group 23No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、13.040.20!$z9“1872257www.din.deDDIN ISO 16000-14Indoor air Part 14: Determination of total (gas and particle-phase) polychlorinateddioxin-like biphenyls (PCBs) and polychlorinateddibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up and analysis by high-resolution gaschromatography and

3、mass spectrometry (ISO 16000-14:2009)English translation of DIN ISO 16000-14:2012-03Innenraumluftverunreinigungen Teil 14: Bestimmung der Summe gasfrmiger und partikelgebundener polychlorierterdioxin-hnlicher Biphenyle (PCB) und polychlorierter Dibenzo-p-dioxine/Dibenzofurane(PCDD/PCDF) Extraktion,

4、Reinigung und Analyse mit hochauflsender Gaschromatographie undMassenspektrometrie (ISO 16000-14:2009)Englische bersetzung von DIN ISO 16000-14:2012-03Air intrieur Partie 14: Dosage des polychlorobiphnyles (PCB) de type dioxine et despolychlorodibenzo-p-dioxines (PCDD)/polychlorodibenzofuranes (PCDF

5、) totaux (en phasegazeuse et en phase particulaire) Extraction, purification et analyse par chromatographie en phase gazeuse hautersolution et spectromtrie de masse (ISO 16000-14:2009)Traduction anglaise de DIN ISO 16000-14:2012-03www.beuth.deDocument comprises 60 pagesDiese Norm ist Bestandteil des

6、 VDI/DIN-Handbuches Reinhaltung der Luft, Band 5.In case of doubt, the German-language original shall be considered authoritative.03.12 A comma is used as the decimal marker. Contents Page National forewordNational Annex NIntroduction 7 1 Scope 8 2 Normative references . 8 3 Terms, definitions and a

7、bbreviated terms . 9 4 Principle. 12 5 Apparatus and materials 12 6 Analysis . 14 7 Minimum requirements for extraction and clean-up. 22 8 Identification and quantification . 22 9 Quality assurance criteria for the procedure blanks 27 10 Recovery 28 11 Calculation and presentation of results . 29 12

8、 Safety measures . 30 13 Performance characteristics . 31 14 Interferences . 33 Annex A (informative) Structure, toxicity and calculation of toxic equivalents .34 Annex B (informative) Example for the clean-up of PCBs/PCDDs/PCDFs and the separation of PCBs from PCDDs/PCDFs . 39 Annex C (informative)

9、 GC/MS analysis 43 Annex D (informative) Masses of the ions for PCDDs/PCDFs and PCBs. 49 Annex E (informative) Interferences. 50 Annex F (normative) Calibration solutions for GC/MS calibration 53 Annex G (informative) Standard deviations, detection limits and indoor air concentrations for PCBs. 57 B

10、ibliography . 59 . 53DIN ISO 16000-14:2012-03 2National foreword International technical regulation pertaining to indoor air This standard has been prepared by Technical Committee ISO/TC 146 “Air quality”, Subcommittee SC 6 “Indoor air” (Secretariat: DIN, Germany). The responsible German body involv

11、ed in its preparation was the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section IV Umweltmesstechnik. General and substance-specific aspects which should be taken into account before and during s

12、ampling, as well as methods for determining individual substances or groups of substances and microorganisms in indoor air are described in the various parts of DIN ISO 16000 and DIN EN ISO 16000. The DIN Standard corresponding to the International Standard referred to in Clause 2 of this document i

13、s as follows: ISO 16000-13 DIN ISO 16000-13 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. National technical regulation pertaining to indoor air Ge

14、neral conditions and other aspects to be taken into consideration when planning indoor air measurements are described for individual substances and substance groups in the VDI 4300 series (see also “National Annex NA”). Many of these served as the sole basis for parts of the ISO 16000 series (e.g. I

15、SO 16000-1, ISO 16000-2, ISO 16000-5, ISO 16000-7, ISO 16000-12, ISO 16000-15, ISO 16000-16, ISO 16000-17 and ISO 16000-18). The specific procedures (sampling, analysis) are described in the VDI 4301 series for individual substances and substance groups. Methods which can be used for both indoor and

16、 ambient air measurements are described in further VDI guidelines. DIN ISO 16000 series and DIN EN ISO 16000 series consist of the following parts, under the general title Indoor air: DIN EN ISO 16000-1, General aspects of sampling strategy DIN EN ISO 16000-2, Sampling strategy for formaldehyde DIN

17、ISO 16000-3, Determination of formaldehyde and other carbonyl compounds Active sampling method DIN ISO 16000-4, Determination of formaldehyde Diffusive sampling method DIN EN ISO 16000-5, Sampling strategy for volatile organic compounds (VOCs) DIN ISO 16000-6, Determination of volatile organic compo

18、unds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID DIN EN ISO 16000-7, Sampling strategy for determination of airborne asbestos fibre concentrations DIN ISO 16000-8, Determination of local mean ages of air in buildings fo

19、r characterizing ventilation conditions DIN EN ISO 16000-9, Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN ISO 16000-14:2012-03 3 DIN EN ISO 16000-10, Determination of the emission of volatile organic compounds from

20、building products and furnishing Emission test cell method DIN EN ISO 16000-11, Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens DIN EN ISO 16000-12, Sampling strategy for polychlorinated

21、biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs) DIN ISO 16000-13: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzof

22、urans (PCDDs/PCDFs) Collection on sorbent-backed filters DIN ISO 16000-14, Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up and analysis by high-resolution gas chromatog

23、raphy and mass spectrometry DIN EN ISO 16000-15, Sampling strategy for nitrogen dioxide (NO2) DIN ISO 16000-16, Detection and enumeration of moulds Sampling by filtration DIN ISO 16000-17, Detection and enumeration of moulds Culture-based method DIN ISO 16000-18, Detection and enumeration of moulds

24、Sampling by impaction DIN ISO 16000-19, Sampling strategy for moulds DIN ISO 16000-23, Performance test for evaluating the reduction of formaldehyde concentrations by sorptive building materials DIN ISO 16000-24, Performance test for evaluating the reduction of volatile organic compounds and carbony

25、l compounds without formaldehyde concentrations by sorptive building materials DIN ISO 16000-25, Determination of the emission of semi-volatile organic compounds by building products Micro-chamber method DIN ISO 16000-26, Measurement strategy for carbon dioxide (CO2) DIN ISO 16000-28, Sensory evalua

26、tion of emissions from building materials and products The following parts are under preparation: DIN ISO 16000-21, Detection and enumeration of moulds Sampling from materials DIN ISO 16000-27, Standard method for the quantitative analysis of asbestos fibres in settled dust DIN ISO 16000-29, Test me

27、thods for VOC detectors DIN ISO 16000-30, Sensory testing of indoor air DIN ISO 16000-31, Measurement of flame retardants and plasticizers based on organophosphorus compounds Phosphoric acid ester DIN ISO 16000-32, Investigation of constructions on pollutants and other injurious factors Inspections

28、The following parts are planned: DIN ISO 16000-20, Detection and enumeration of moulds Sampling from house dust DIN ISO 16000-22, Detection and enumeration of moulds Molecular methods DIN ISO 16000-14:2012-03 4National Annex NA (informative) Bibliography DIN EN ISO 5492, Sensory analysis Vocabulary

29、DIN EN ISO 8589, Sensory analysis General guidance for the design of test rooms DIN 50014, Climates and their technical application Standard atmospheres DIN EN ISO 8199, Water quality General guidance on the enumeration of micro-organisms by culture DIN EN ISO 9169, Air quality Definition and determ

30、ination of performance characteristics of an automatic measuring system DIN ISO 12219-1, Indoor air of road vehicles Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors 2 DIN ISO 12219-2, Indoor air of road vehicles Part

31、2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method DIN ISO 12219-3, Indoor air of road vehicles Part 3: Screening method for the determination of the emissions of volatile organic compounds from vehicle interi

32、or parts and materials Micro-chamber method DIN ISO 12219-4, Indoor air of road vehicles Part 4: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Small chamber method (under preparation) DIN ISO 12884, Ambient air Determi

33、nation of total (gas and particle phase) polycyclic aromatic hydrocarbons Collection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN V EN V 13005, Guide to the expression of uncertainty in measurement DIN EN 14412, Indoor air quality Diffusive samplers for the dete

34、rmination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling 4 DIN EN ISO 160

35、17-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling 5 DIN ISO 16362, Ambient air Determination of particle-phase polycyclic aromatic hydrocarbons by high performance liq

36、uid chromatography DIN EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories VDI 2464 Blatt 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphynyls (PCBs) GC/MS method for PCB 28, 52, 101,138, 153, 180 VDI 2464 Blatt 2, A

37、mbient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) HR-GC/HR-MS method for coplanar PCBs VDI 2464 Blatt 3, Ambient air measurement Indoor air measurement Measurement of polybrominated diphenylether, hexabromocyclododecane and hexabromobenzene VDI 3484 Blatt

38、1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with the sulfite pararosaniline method DIN ISO 16000-14:2012-03 5 VDI 3484 Blatt 2, Gaseous ambient air measurements Indoor-air pollution measurements Measureme

39、nt of the formaldehyde concentration with the acatylacetone method VDI 3498 Blatt 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using large filters VDI 3498 Blatt 2, Ambient air measurement Indoor air measurement Measureme

40、nt of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4252 Blatt 2, Measurement of airborne microorganisms and viruses in ambient air Active sampling of bioaerosols Separation of airborne mould on gelatine/polycarbonate filters VDI 4253 Blatt 2 Measurement of airbo

41、rne microorganisms and viruses in ambient air Culture based method for the determination of the concentration of mould in air Indirect method after sampling with gelatine/polycarbonate filters VDI 4300 Blatt 1, Indoor-air pollution measurement General aspects of measurement strategy VDI 4300 Blatt 2

42、, Indoor-air pollution measurement Measurement strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated bibhenyle (PCBs) VDI 4300 Blatt 4, Indoor air pollution measurement Measurement strategy for penta

43、chlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Blatt 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Blatt 6, Measurement of indoor air pollution Measurement strategy for volatile organic compounds (VOCs) VDI 4300 Blatt 7,

44、Indoor-air pollution measurement Measurement of indoor air change rate VDI 4300 Blatt 8, Measurement of indoor air pollution Sampling of house dust VDI 4300 Blatt 9, Measurement of indoor air pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Blatt 10, Measurement of indoor air polluti

45、on Measurement strategies for determination of mould fungi in indoor environment VDI 4301 Blatt 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide Manual photometric method (Saltzman) VDI 4301 Blatt 2, Indoor air pollution measurement Measurement of pentaclorp

46、henol (PCP) and -hexachlorcyclohexane (lindane) GC/MS-method VDI 4301 Blatt 3, Measurement of indoor air pollution Measurement pentaclorophenol (PCP) and -hexachlorcyclohexane (lindane) GC/ECD method VDI 4301 Blatt 4, Measurement of indoor air pollution Measurement of pyrethroids and piperonyl butox

47、ide in air, house dust and solvent wipe samples VDI 4301 Blatt 5, Measurement of indoor air pollution Measurement of flame retardants and plasticizers based on organophosphorous compounds Phosphoric acid ester VDI 4301 Blatt 6, Measurement of indoor air pollution Measurement of phthalates with DC/MS The following VDI Guidelines are under preparation: VDI 4300 Blatt 11, Measurement of indoor air pollution Measurement strategies for determination of airborne partic