DIN EN ISO 177-2017 Plastics - Determination of migration of plasticizers (ISO 177 2016) German version EN ISO 177 2017《塑料 增塑剂分散性的测定(ISO 177-2016) 德文版本EN ISO 177-2017》.pdf

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1、May 2017 English price group 8No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 83.080.01!%dB“2659431www.din.deDIN EN

2、 ISO 177Plastics Determination of migration of plasticizers (ISO 177:2016);English version EN ISO 177:2017,English translation of DIN EN ISO 177:2017-05Kunststoffe Bestimmung der Migration von Weichmachern (ISO 177:2016);Englische Fassung EN ISO 177:2017,Englische bersetzung von DIN EN ISO 177:2017-

3、05Plastiques Dtermination de la migration des plastifiants (ISO 177:2016);Version anglaise EN ISO 177:2017,Traduction anglaise de DIN EN ISO 177:2017-05SupersedesDIN EN ISO 177:199910www.beuth.deDocument comprises 11 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language origi

4、nal shall be considered authoritative.05.17 DIN EN ISO 177:2017-05 2 A comma is used as the decimal marker. National foreword This document (EN ISO 177:2017) has been prepared by Technical Committee ISO/TC 61 “Plastics” in collaboration with Technical Committee CEN/TC 249 “Plastics” (Secretariat: NB

5、N, Belgium). The responsible German body involved in its preparation was DIN-Normenausschuss Kunststoffe (DIN Standards Committee Plastics), Working Committee NA 054-01-04 AA “Behaviour towards environmental effects”. The DIN Standards corresponding to the International Standards referred to in this

6、 document are as follows: ISO 291 DIN EN ISO 291 ISO 293 DIN EN ISO 293 ISO 294-1 DIN EN ISO 294-1 ISO 294-3 DIN EN ISO 294-3 ISO 4649 DIN ISO 4649 Amendments This standard differs from DIN EN ISO 177:1999-10 as follows: a) normative references have been updated; b) the standard has been editorially

7、 revised and harmonized with current rules of presentation. Previous editions DIN 53405: 1955-07, 1962-12, 1981-12 DIN EN ISO 177: 1999-10 National Annex NA (informative) Bibliography DIN EN ISO 291, Plastics Standard atmospheres for conditioning and testing DIN EN ISO 293, Plastics Compression moul

8、ding of test specimens of thermoplastic materials DIN EN ISO 294-1, Plastics Injection moulding of test specimens of thermoplastic materials Part 1: General principles, and moulding of multipurpose and bar test specimens DIN EN ISO 294-3, Plastics Injection moulding of test specimens of thermoplasti

9、c materials Part 3: Small plates DIN ISO 4649, Rubber, vulcanized or thermoplastic Determination of abrasion resistance using a rotating cylindrical drum device EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 177 January 2017 ICS 83.080.01 Supersedes EN ISO 177:1999English Version Plastics

10、- Determination of migration of plasticizers(ISO 177:2016) Plastiques - Dtermination de la migration des plastifiants (ISO 177:2016) Kunststoffe - Bestimmung der Migration von Weichmachern (ISO 177:2016) This European Standard was approved by CEN on 21 January 2017. CEN members are bound to comply w

11、ith the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Man

12、agement Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same s

13、tatus as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Ma

14、lta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussel

15、s 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 177:2017 EEuropean foreword .31 Scope . 52 Normative references 53 Terms and definitions . 54 Principle 65 Apparatus . 66 Test specimens 67 Conditioning 78 Procedure. 79 Ex

16、pression of results 810 Test report . 8Bibliography 9Contents PageDIN EN ISO 177:2017-05 EN ISO 177:2017 (E)2Foreword .4European foreword This document (EN ISO 177:2017) has been prepared by Technical Committee ISO/TC 61 “Plastics” in collaboration with Technical Committee CEN/TC 249 “Plastics” the

17、secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2017 and conflicting national standards shall be withdrawn at the latest by July 2017. Attention is drawn

18、to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 177:1999. According to the CEN-CENELEC Internal Regulations, the national

19、 standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuan

20、ia, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 177:2016 has been approved by CEN as EN ISO 177:2017 without any modification. DIN EN ISO 177:2017-05 EN IS

21、O 177:2017 (E)3 ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subjec

22、t for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC)

23、 on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be not

24、ed. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying

25、any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of

26、users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the followi

27、ng URL: www.iso.org/iso/foreword.html.The committee responsible for this document is ISO/TC 61, Plastics, Subcommittee SC 6, Ageing, chemical and environmental resistance.This third edition cancels and replaces the second edition (ISO 177:1988), of which it constitutes a minor revision with the foll

28、owing change: the normative references have been updated.DIN EN ISO 177:2017-05 EN ISO 177:2017 (E)4 1 ScopeThis document specifies a method for the determination of the tendency of plasticizers to migrate from plastics in which they are contained into other materials or other plastics when they are

29、 brought into close contact.NOTE 1 The surfaces into which the migration can proceed can also consist of organic surface coatings, such as lacquers.This test is suitablea) for evaluating the tendency displayed by plastics, particularly in the form of films and sheets, to lose certain of their liquid

30、 constituents when they are brought into contact with materials that have an affinity for plasticizers, andb) for studying the tendency to migrate of plasticizers contained in a resin or a series of resins, in one or more concentrations.In case b), standard compounds are prepared on the basis of a w

31、ell-characterized resin with well-defined ratios of plasticizer to resin.NOTE 2 When the absorbent sheets themselves contain a substance capable of migrating, simultaneous migrations can occur from the test specimens into the absorbent sheets and vice versa.The results may also be affected by the mi

32、gration of other constituents of the plastic material (for example, oligomers) or by the loss of any volatile constituents other than plasticizers from the plastic material or the absorbent layer.2 Normative referencesThe following documents are referred to in the text in such a way that some or all

33、 of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 291, Plastics Standard atmospheres for conditioning and testingISO 293, Plas

34、tics Compression moulding of test specimens of thermoplastic materialsISO 294-1, Plastics Injection moulding of test specimens of thermoplastic materials Part 1: General principles, and moulding of multipurpose and bar test specimensISO 294-3, Plastics Injection moulding of test specimens of thermop

35、lastic materials Part 3: Small plates3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.ISO and IEC maintain terminological databases for use in standardization at the following addresses: IEC Electropedia: available at http:/www.electropedia.org/ ISO

36、 Online browsing platform: available at http:/www.iso.org/obpDIN EN ISO 177:2017-05 EN ISO 177:2017 (E)5 3.1migration of plasticizersloss of mass of a sheet of plasticized plastic when placed in close contact between two absorbent sheets of another material, under specified conditions4 PrincipleA te

37、st specimen cut from a sheet or plate of the material or from the finished product to be tested is placed in close contact with two sheets, capable of absorbing plasticizers. It is then subjected to heating under defined conditions. The loss in mass of the test specimen, theoretically equal to the i

38、ncrease in mass of the sheets, is a measure of the migration of the plasticizer.5 Apparatus5.1 Analytical balance, accurate to 0,001 g.5.2 Micrometer, accurate to 0,01 mm.5.3 Air circulating oven, capable of maintaining the temperature to within 2 C, in the range 50 C to 100 C.5.4 Glass plates, with

39、 plane surfaces, of sufficient size to cover the absorbent backing discs (5.6).5.5 Weights, of 5 kg.5.6 Absorbent backing discs, with an affinity for plasticizers, 60 mm 1 mm in diameter and at least 0,5 mm in thickness.The materials recommended for the test are: a standard rubber (according to ISO

40、4649), or polyethylene without additive, or polyvinyl acetate without plasticizer.In the case of a particular application, an absorbent backing disc of the material with which the plastic under test will be in contact when in service shall be used. The surface of the absorbent backing disc shall be

41、sufficiently smooth to ensure continuous contact with the test specimen.6 Test specimens6.1 The test specimens shall be in the form of discs 50 mm 1 mm in diameter and at least 0,5 mm in thickness, cut from a compression-moulded (in accordance with ISO 293) or injection-moulded (in accordance with I

42、SO 294-1 and ISO 294-3) sheet of suitable thickness.The surface of the test specimens shall be sufficiently smooth to ensure continuous contact with the absorbent backing discs (5.6).6.2 In the case of films, the test specimen of not less than 0,5 mm thickness shall be produced by pressing an adequa

43、te number of films at a suitable temperature for about 1 min.6.3 If the test is intended to determine the migration from a finished product, the latter shall be tested at a uniform thickness.DIN EN ISO 177:2017-05 EN ISO 177:2017 (E)6 6.4 If the product to be tested consists of a support (fabric, pa

44、per or other suitable material), coated on one face only by the spreading or calendering of a plasticized resin (such as fabrics coated with vinyl resins or with similar products), the test specimens shall consist of two discs cut from the material itself and superposed in such a way that the uncoat

45、ed surfaces of the support are touching and the plastic is situated on the other faces of the sandwich so formed.6.5 Three test specimens shall be tested for each material.7 ConditioningUnless otherwise specified, the test specimens and absorbent backing discs (5.6) shall be conditioned in one of th

46、e atmospheres specified in ISO 291.8 Procedure8.1 After conditioning, weigh the test specimens (see Clause 6) and the discs (5.6) to the nearest 0,001 g and determine their mean thickness to the nearest 0,01 mm.8.2 Place a test specimen of the material under test between two absorbent backing discs,

47、 in such a way that their axes coincide and the assembly forms a sandwich. Place the latter between two glass plates (5.4).8.3 If the test is intended to determine the characteristics of particular plasticizers, standard compounds of a specified composition shall be used, as agreed between the inter

48、ested parties.8.4 To equalize the distribution of pressure between the absorbent backing disc and the test specimen, a sheet of rubber shall be inserted between the absorbent backing disc and the glass plate. The absorbent backing disc shall be separated from the sheet of rubber by aluminium foil.8.5 Place one of the 5 kg weights (5.5) on the assembly of discs and plates to be tested and place the assembly in the oven (5.3), maintained a