DIN EN ISO 16373-1-2016 Textiles - Dyestuffs - Part 1 General principles of testing coloured textiles for dyestuff identification (ISO 16373-1 2015) German version EN ISO 16373-1 2.pdf

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1、May 2016 English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 59.080.01; 87.060.10!%UVo“2505176www

2、.din.deDIN EN ISO 16373-1Textiles Dyestuffs Part 1: General principles of testing coloured textiles for dyestuff identification (ISO 16373-1:2015);English version EN ISO 16373-1:2015,English translation of DIN EN ISO 16373-1:2016-05Textilien Farbstoffe Teil 1: Allgemeine Grundlagen der Prfung farbig

3、er Textilien zur Farbstoff-Identifikation (ISO 16373-1:2015);Englische Fassung EN ISO 16373-1:2015,Englische bersetzung von DIN EN ISO 16373-1:2016-05Textiles Colorants Partie 1: Principes gnraux dessais des textiles colors pour lidentification des colorants (ISO 16373-1:2015);Version anglaise EN IS

4、O 16373-1:2015,Traduction anglaise de DIN EN ISO 16373-1:2016-05www.beuth.deDocument comprises 24 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.05.16 DIN EN ISO 16373-1:2016-05 2 A comma is used as the decimal marker. Nationa

5、l foreword This document (EN ISO 16373-1:2015) has been prepared by Technical Committee CEN/TC 248 “Textiles and textile products” (Secretariat: BSI, United Kingdom) in collaboration with Technical Committee ISO/TC 38 “Textiles”. The responsible German body involved in its preparation was DIN-Normen

6、ausschuss Materialprfung (DIN Standards Committee Materials Testing), Working Committee NA 062-05-12 AA Textilchemische Prfverfahren und Fasertrennung. The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 2076 DIN EN ISO 2076 ISO 3696 DIN IS

7、O 3696 ISO 5089 E DIN EN ISO 5089 ISO 6938 DIN EN ISO 6938 National Annex NA (informative) Bibliography DIN EN ISO 2076, Textiles Man-made fibres Generic names E DIN EN ISO 5089, Textiles Preparation of laboratory test samples and test specimens for chemical testing DIN EN ISO 6938, Textiles Natural

8、 fibres Generic names and definitions DIN ISO 3696, Water for analytical laboratory use Specification and test methods EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 16373-1 December 2015 ICS 59.080.01 English Version Textiles - Dyestuffs - Part 1: General principles of testing coloured te

9、xtiles for dyestuff identification(ISO 16373-1:2015) Textiles - Colorants - Partie 1: Principes gnraux dessais des textiles colors pour lidentification des colorants (ISO 16373-1:2015) Textilien - Farbstoffe - Teil 1: Allgemeine Grundlagen der Prfung farbiger Textilien zur Farbstoff-Identifikation (

10、ISO 16373-1:2015) This European Standard was approved by CEN on 31 October 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and b

11、ibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the res

12、ponsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav R

13、epublic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NOR

14、MALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 16373-1:2015 EEuropean foreword .3Introduction 51 Scope . 62 Normat

15、ive references 63 Terms and definitions . 64 Fibre identification 75 Dye classes, based on the method of applying the dye 75.1 Acid dye . 75.2 Metal complex acid dye 75.2.1 1:1 Metal complex dye 75.2.2 1:2 Metal complex dye 75.3 Azoic dye. 75.4 Basic dye (also called cationic dye) . 75.5 Mordant dye

16、 85.6 Direct dye . 85.7 Disperse dye 85.8 Reactive dye . 85.8.1 General 85.8.2 Anthraquinone reactive dye . 85.9 Sulfur dye . 85.10 VAT dye 86 Complementary dye class, based on chemist classification: Azo dye 87 Reagents 98 Apparatus 109 Conditioning and testing atmosphere . 1010 Preparation of the

17、test specimens 1011 Procedures (examples) . 1011.1 Pigment identification . 1011.2 Finishing removal treatment . 1011.3 Acid dyes, basic, direct dyes and reactive dyes . 1011.4 VAT dyes, sulfur dyes, reactive dyes, aniline black, azoic dyes, direct dyes, developed disperse dyes and chrome dyes . 101

18、1.5 Metal-complex dyes and disperse dyes 1011.6 Extraction test. 1011.7 Ash test . 1011.8 Miscellaneous tests 1112 Testing report . 11Annex A (informative) Explanatory table of colourants (dyes and pigments) used in various textile materials .18Annex B (informative) Comparison between ISO 16373-2 an

19、d ISO 16373-3: Recovery rates 20Bibliography .22Contents PageForeword 4DIN EN ISO 16373-1:2016-05 EN ISO 16373-1:2015 (E)2 European foreword This document (EN ISO 16373-1:2015) has been prepared by Technical Committee ISO/TC 38 “Textiles“ in collaboration with Technical Committee CEN/TC 248 “Textile

20、s and textile products” the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2016, and conflicting national standards shall be withdrawn at the latest by J

21、une 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards or

22、ganizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembour

23、g, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 16373-1:2015 has been approved by CEN as EN ISO 16373-1:2015 without any modification. DIN EN ISO 16373-1:2016-05 EN ISO 16373-1

24、:2015 (E)3 ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for

25、 which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on a

26、ll matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. T

27、his document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any o

28、r all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users

29、 and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary

30、 informationISO 16373-1 was prepared by the European Committee for Standardization (CEN) Technical Committee CEN/TC 248, Textiles and textile products, in collaboration with ISO Technical Committee TC 38, Textiles, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna

31、 Agreement).ISO 16373 consists of the following parts, under the general title Textiles Dyestuffs: Part 1: General principles of testing coloured textiles for dyestuff identification Part 2: General method for the determination of extractable dyestuffs including allergenic and carcinogenic dyestuffs

32、 (method using pyridine-water) Part 3: Method for determination of certain carcinogenic dyestuffs (method using triethylamine/methanol)DIN EN ISO 16373-1:2016-05 EN ISO 16373-1:2015 (E)4 IntroductionThe ISO 16373- series deals with dyes used in textiles for qualification and quantification.This part

33、 of ISO 16373 includes the definition of the classes of dyes, the description of some procedures to identify qualitatively the class of dyes used in textile material.The other parts of ISO 16373 are related to the quantification of some dyes. The principle of the test method in ISO 16373-2 is based

34、on the extraction using pyridine-water solution, which has been found to be the most efficient solution to extract a large range of dyes, including allergenic and carcinogenic dyes. The principle of the test method in ISO 16373-3 is based on the extraction using triethylamine-methanol solution. This

35、 solution has been found efficient to extract some dyes in some cases.Additional information related to the recovery rates (to characterize the extraction efficiency) obtained from the application of ISO 16373-2 and ISO 16373-3 are summarized in Annex B.It is important to note that there are other t

36、est methods related to azo dyes, for which a reduction of the extracted azo dyes leads to the release of some aromatic amines to be detected and determined using chromatography (See Bibliography/Aromatic amines determination).DIN EN ISO 16373-1:2016-05 EN ISO 16373-1:2015 (E)5 WARNING This document

37、calls for the use of substances/procedures that may be injurious to the health/environment if appropriate conditions are not observed. It refers only to technical suitability and does not absolve the user from legal obligations relating to health and safety/environment at any stage.1 ScopeThis part

38、of ISO 16373 gives the definition of the colourant classes and the relationship to textile fibres.It describes some procedures to identify qualitatively the colourant class used in textile material.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this

39、 document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 3696, Water for analytical laboratory use Specification and test methodsISO 5089, Te

40、xtiles Preparation of laboratory test samples and test specimens for chemical testing3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1colourantdye or pigment3.2dyedyestuffwater-insoluble or water-soluble molecule which has dyeing affinity with fi

41、breNote 1 to entry: The defining difference between a dye and a pigment is its solubility in an aqueous medium. In this part of ISO 16373, the term “affinity” is used as a qualitative expression, although affinity is the quantitative expression of substantivity and usually expressed in Joules per mo

42、le, where substantivity is the attraction between a substrate and a dye or other substance under precise conditions where the latter is selectively extracted from the application medium by the substrate.DIN EN ISO 16373-1:2016-05 EN ISO 16373-1:2015 (E)6 3.3pigmentwater-insoluble molecule which has

43、no dyeing affinity with fibreNote 1 to entry: The defining difference between a dye and a pigment is its solubility in an aqueous medium. In this part of ISO 16373, the term “affinity” is used as a qualitative expression, although affinity is the quantitative expression of substantivity and usually

44、expressed in Joules per mole, where substantivity is the attraction between a substrate and a dye or other substance under precise conditions where the latter is selectively extracted from the application medium by the substrate.4 Fibre identificationPrior to any colourant identification (including

45、dye class), the fibre nature of the textile product shall be known. The fibre nature may be based on information given by manufacturer, etc. or can be identified, using one or more techniques as described in ISO/TR 11827, for example.An explanatory table of colourants used in various textile materia

46、ls is given in Annex A.5 Dye classes, based on the method of applying the dye5.1 Acid dyeAcid dye is water-soluble anionic dye using neutral to acid dye baths. Attachment to the fibre (e.g. protein fibres and polyamide fibres) is attributed, at least partly, to salt formation between anionic groups

47、in the dye and cationic groups in the fibre.5.2 Metal complex acid dyeA metal complex dye is an acid dye that has a coordinate metal atom in its molecule.5.2.1 1:1 Metal complex dye1 molecule of dye is combined with 1 metal ion.5.2.2 1:2 Metal complex dye2 molecules of dye are combined with 1 metal

48、ion. 1:2 metal complex dyes are the most frequent.5.3 Azoic dyeAzoic dye is water-insoluble dye which is formed on the fibre by coupling a water-soluble diazo compound with a water soluble coupling compound having affinity for cellulose.NOTE 1 The definition of the class “azoic dye” (dyers classification) is distinct from the definition of the class “azo dye”