DIN EN 16003-2012 Chemicals used for treatment of water intended for human consumption - Calcium magnesium carbonate German version EN 16003 2011《用于供人类食用的水处理化学品 碳酸镁 德文版本EN 16003-20.pdf

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1、February 2012 Translation by DIN-Sprachendienst.English price group 10No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 71.100.80!$y|“1866189www.din.deDDIN EN 16003Chemicals used for treatment of water intended for humanconsumption Calcium magnesium carbonateEnglish translation of DIN EN 16003:2012-02Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch CalciummagnesiumcarbonatEnglische bersetzung von

3、DIN EN 16003:2012-02Produits chimiques utiliss pour le traitement de leau destine la consommationhumaine Carbonate de calcium et de magnsiumTraduction anglaise de DIN EN 16003:2012-02www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.

4、1501.12 DIN EN 16003:2012-02 2 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Pr

5、actice Standards Committee), Working Committee NA 119-04-02 AA Wasseraufbereitung. Users of this standard are advised of the reservations stated in the Introduction of the European Standard and should note that national regulations exist in Germany dealing with water for human consumption, in partic

6、ular the Trinkwasserverordnung (TrinkwV2001) (German Drinking Water Ordinance). National Annex NA (informative) Bibliography Verordnung zur Novellierung der Trinkwasserverordnung (German Regulation amending the German Drinking Water Ordinance), as of 21 May 2001, Bundesgesetzblatt (German Federal La

7、w Gazette) Part 1, No. 24, pp. 959-980)Erste Verordnung zur nderung der Trinkwasserverordnung (First Ordinance amending the German Drinking Water Ordinance) as of 3 May 2011, Bundesgesetzblatt (German Federal Law Gazette) Part 1 (2011), No. 21, pp. 748 774) Recorded in the DITR database of DIN Softw

8、are GmbH, obtainable from Beuth Verlag GmbH, 10772 Berlin, Germany. EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16003 November 2011 ICS 71.100.80 English Version Chemicals used for treatment of water intended for human consumption - Calcium magnesium carbonate Produits chimiques utiliss pou

9、r le traitement de leau destine la consommation humaine - Carbonate de calcium et de magnsium Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Calciummagnesiumcarbonat This European Standard was approved by CEN on 8 October 2011. CEN members are bound to comply with the CEN/CENELE

10、C Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or

11、to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the offic

12、ial versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slov

13、akia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reserved worldwide

14、 for CEN national Members. Ref. No. EN 16003:2011: EEN 16003:2011 (E) 2 Contents Page Foreword 4Introduction .51 Scope 62 Normative references 63 Description .63.1 Identification .63.1.1 Chemical name .63.1.2 Synonym or common name 63.1.3 Relative molecular mass .63.1.4 Empirical formula.63.1.5 Chem

15、ical formula .63.1.6 CAS Registry Number 63.1.7 EINECS reference .73.2 Commercial forms .73.3 Physical properties 73.3.1 Appearance 73.3.2 Density 73.3.3 Solubility in water 73.3.4 Vapour pressure 73.3.5 Boiling point at 100 kPa.73.3.6 Melting point .73.3.7 Specific heat .73.3.8 Viscosity (dynamic)

16、.73.3.9 Critical temperature .73.3.10 Critical pressure.73.3.11 Physical hardness .83.3.12 Particle size 83.4 Chemical properties 84 Purity criteria 84.1 General 84.2 Composition of commercial product .84.3 Impurities and main by-product .84.4 Chemical parameters 95 Test methods 95.1 Sampling .95.2

17、Analyses .96 Labelling - Transportation - Storage 96.1 Means of delivery .96.2 Risk and safety labelling according to the EU Directives 96.3 Transportation regulations and labelling . 106.4 Marking 106.5 Storage . 106.5.1 Long term stability 106.5.2 Storage incompatibilities . 10Annex A (informative

18、) General information on calcium carbonate . 11A.1 Origin . 11A.1.1 Raw materials 11A.1.2 Manufacturing process 11A.2 Use . 11DIN EN 16003:2012-02 EN 16003:2011 (E) 3 A.2.1 Function 11A.2.2 Other properties 11A.2.3 Form in which it is used 11A.2.4 Treatment dose 11A.2.5 Means of application . 12A.2.

19、6 Secondary effects 12A.2.7 Removal of excess product 12A.3 Rules for safe handling and use 12A.4 Emergency procedures . 12A.4.1 First aid . 12A.4.2 Spillage . 12A.4.3 Fire 12Bibliography 13DIN EN 16003:2012-02 EN 16003:2011 (E) 4 Foreword This document (EN 16003:2011) has been prepared by Technical

20、 Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2012, and conflicting national standards shall be withdrawn at

21、the latest by May 2012. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the nationa

22、l standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, No

23、rway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 16003:2012-02 EN 16003:2011 (E) 5 Introduction In respect of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this Standard

24、: this Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the character

25、istics of this product remain in force. NOTE Conformity with the standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities

26、. DIN EN 16003:2012-02 EN 16003:2011 (E) 6 1 Scope This European Standard is applicable to calcium magnesium carbonate used for treatment of water intended for human consumption. It describes the characteristics of calcium magnesium carbonate and specifies the requirements and the corresponding test

27、 methods for calcium magnesium carbonate. It gives information on its use in water treatment. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edi

28、tion of the referenced document (including any amendments) applies. EN 12485, Chemicals used for treatment of water intended for human consumption Calcium carbonate, high-calcium lime, half-burnt dolomite, magnesium oxide and calcium magnesium carbonate Test methods ISO 3165, Sampling of chemical pr

29、oducts for industrial use Safety in sampling ISO 6206, Chemical products for industrial use Sampling Vocabulary 3 Description 3.1 Identification 3.1.1 Chemical name Calcium magnesium carbonate. 3.1.2 Synonym or common name Dolomite. 3.1.3 Relative molecular mass 184,39. 3.1.4 Empirical formula CaCO3

30、MgCO3. 3.1.5 Chemical formula CaCO3MgCO3. 3.1.6 CAS Registry Number 1)16389-88-1. 1) Chemical Abstracts Service Registry Number. DIN EN 16003:2012-02 EN 16003:2011 (E) 7 3.1.7 EINECS reference 2)240-440-2. 3.2 Commercial forms Calcium magnesium carbonate is available in crushed and granular form of

31、various particle size ranges. 3.3 Physical properties 3.3.1 Appearance The product is a white or grey to brownish material in crushed and granular form. 3.3.2 Density The density is from 2,2 g/cm3to 2,9 g/cm3at 20 C. The bulk density is from 1,2 g/cm3to 1,6 g/cm3. 3.3.3 Solubility in water The solub

32、ility of product is equal to 0,032 g/l at 10 C. 3.3.4 Vapour pressure Not applicable. 3.3.5 Boiling point at 100 kPa3)Not applicable. 3.3.6 Melting point Not applicable. 3.3.7 Specific heat Not applicable. 3.3.8 Viscosity (dynamic) Not applicable. 3.3.9 Critical temperature Not applicable. 3.3.10 Cr

33、itical pressure Not applicable. 2) European Inventory of Existing Commercial Chemical Substances. 3) 100 kPa = 1 bar. DIN EN 16003:2012-02 EN 16003:2011 (E) 8 3.3.11 Physical hardness Not relevant. 3.3.12 Particle size It varies depending on the application (see A.2.3). 3.4 Chemical properties Calci

34、um magnesium carbonate product reacts as an alkali when dissolved in water. With carbon dioxide and water it reacts to form calcium hydrogen carbonate and magnesium hydrogen carbonate. 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for calcium magnesiu

35、m carbonate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary t

36、o the relevant authorities. NOTE Users of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for human consumption, taking into account raw water quality, required dosage, contents of other impurities and additiv

37、es used in the product not stated in this product standard. Limits have been given for impurities and toxic substances where these are likely to be present in significant quantities from the current production process and raw materials. If a change in the production process or raw materials leads to

38、 significant quantities of other impurities or by-products being present, this shall be notified to the user. 4.2 Composition of commercial product The product shall conform to the requirements specified in Table 1. Table 1 Composition of commercial product Parameter Content in mass fraction in % Co

39、ntent of Calcium magnesium carbonate, in dry substance 95 Total content of magnesium carbonate (MgCO3), in dry substance 39 4.3 Impurities and main by-product The product shall conform to the requirements specified in Table 2. Table 2 Impurities Impurity Content in mass fraction in % Content of resi

40、due not soluble in hydrochloric acid., in dry substance 3 DIN EN 16003:2012-02 EN 16003:2011 (E) 9 4.4 Chemical parameters The content of chemical parameters shall conform to the requirements specified in Table 3. Table 3 Chemical parameters Parameter Limit of product mg/kg, in dry substance Antimon

41、y (Sb) max. 3 Arsenic (As) max. 3 Cadmium (Cd) max. 2 Chromium (Cr) max. 10 Lead (Pb) max. 10 Mercury (Hg) max. 0,5 Nickel (Ni) max. 10 Selenium (Se) max. 3 NOTE Other chemical parameters and indicator parameters are not relevant in calcium magnesium carbonate because the raw materials used in the m

42、anufacturing process are free of them. For parametric values of calcium magnesium carbonate on trace metal content in drinking water, see 3. 5 Test methods 5.1 Sampling Observe the general recommendations of ISO 3165 and take account of ISO 6206. Prepare the laboratory sample(s) required by the rele

43、vant procedure described in EN 12485. 5.2 Analyses Use the relevant methods for analysis described in EN 12485. 6 Labelling - Transportation - Storage 6.1 Means of delivery Calcium magnesium carbonate can be delivered in bags, containers and as a bulk material. In order that the purity of the produc

44、ts is not affected, the means of delivery shall not have been used previously for any different product or it shall have been specially cleaned and prepared before use. 6.2 Risk and safety labelling according to the EU Directives 4)At the date of the publication of this European Standard no labellin

45、g requirements apply to calcium magnesium carbonate. 4) See 4 and 6. DIN EN 16003:2012-02 EN 16003:2011 (E) 10 NOTE Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REAC

46、H), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC contains a list of

47、substances classified by the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to the criteria in the Regulation by the person responsible for placing the product on the market. 6.3 Transportation regulations and labelling At the date of the publication of this European standard, calcium magnesium carbonate products are not classified as dangerous goods. 6.4 Marking The marking shall include the following: “calcium magnesium carbonate“, trade name; net mass; name and address of suppli