DIN EN 15799-2010 Products used for treatment of swimming pool water - Powdered activated carbon German version EN 15799 2010《游泳池水处理用化学品 粉状活性炭 德文版本EN 15799-2010》.pdf

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1、May 2010 English price group 8No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 71.100.80!$bB“1633196www.din.deDDIN E

2、N 15799Products used for treatment of swimming pool water Powdered activated carbonEnglish translation of DIN EN 15799:2010-05Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser Pulver-AktivkohleEnglische bersetzung von DIN EN 15799:2010-05Produits utiliss pour le traitement de leau des pisc

3、ines Charbon actif en poudreTraduction anglaise de DIN EN 15799:2010-05www.beuth.deDocument comprises 12 pagesTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.04.10 A comma is used as the decimal marker.National foreword This standard

4、 has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Committee NA 119-04-02 AA Wasseraufbereitung. 2 DIN EN 15799:201

5、0-05 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15799 January 2010 ICS 71.100.80 English Version Products used for treatment of swimming pool water Powdered activated carbon Produits utiliss pour le traitement de leau des piscines Charbon actif en poudre Produkte zur Aufbereitung von Schwi

6、mm-und Badebeckenwasser Pulver-Aktivkohle This European Standard was approved by CEN on 4 December 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration

7、. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translati

8、on under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, G

9、ermany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORM

10、UNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15799:2010: EEN 15799:2010 (E) 2 Contents PageForeword 3Introduction .41 Scope 52 Normative references 53 Description .54

11、 Physical properties 55 Purity criteria 55.1 General 55.2 Impurities and main by-products .65.3 Water-extractable substances 65.4 Specific properties.66 Test methods 67 Labelling - Transportation - Storage 67.1 Means of delivery .67.2 Risk and safety labelling according to the EU Directives .67.3 Tr

12、ansportation regulations and labelling 77.4 Marking .77.5 Storage 7Annex A (informative) General information on powdered activated carbon8A.1 Origin 8A.2 Properties .8A.3 Use 8A.4 Rules for safe handling and use 9A.5 Emergency procedures .9Bibliography . 10DIN EN 15799:2010-05 EN 15799:2010 (E) 3 Fo

13、reword This document (EN 15799:2010) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by

14、July 2010, and conflicting national standards shall be withdrawn at the latest by July 2010. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent r

15、ights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

16、Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 15799:2010-05 EN 15799:2010 (E) 4 Introduction In respect of potential adverse effects on the quality of swimming pool w

17、ater, caused by the product covered by this document: a) this document provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing na

18、tional regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this document does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this document is subjec

19、t to regulation or control by National Authorities. DIN EN 15799:2010-05 EN 15799:2010 (E) 5 1 Scope This European Standard is applicable to powdered activated carbon used for treatment of swimming pool water. It describes the characteristics of powdered activated carbon and specifies the requiremen

20、ts and the corresponding test methods for powdered activated carbon. It gives information on its use in swimming pool water treatment. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applie

21、s. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12902, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materials Methods of test EN 12903:2009, Products used for the treatment of wa

22、ter intended for human consumption Powdered activated carbon 3 Description For the identification, the commercial form, and the chemical properties see the relevant subclauses of EN 12903. 4 Physical properties For the physical properties, the product shall conform to the requirements specified in t

23、he relevant subclauses of EN 12903. NOTE For very small particle size (1 m), powdered activated carbon used in conjunction with ultra-filtration, the contents of oversize and undersize particles should not exceed a mass fraction of 5 %. 5 Purity criteria 5.1 General This standard specifies the minim

24、um purity requirements for powdered activated carbon used for the treatment of swimming pool water. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the u

25、ser and when necessary to relevant authorities. NOTE Users of the product should check national regulations in order to clarify whether it is of appropriate purity for treatment of swimming pool water, taking into account water quality, required dosage, and contents of other impurities and additives

26、 used in the product not stated in the product document. Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to significant

27、quantities of other impurities, by-products or additives being present, this shall be notified to the user. DIN EN 15799:2010-05 EN 15799:2010 (E) 6 5.2 Impurities and main by-products The content of ash, water and water-soluble material shall conform to the requirements specified in EN 12903. 5.3 W

28、ater-extractable substances The content of arsenic, cadmium, chromium, mercury, nickel, lead, antimony, selenium, cyanide and PAH shall conform to the requirements specified in EN 12903. NOTE Polycyclic Aromatic Hydrocarbons (PAH): the sum of the detected concentrations of fluoranthene, benzo(b)fluo

29、ranthene, benzo(k)fluoranthene, benzo(a)pyrene, benzo(ghi)perylene, indeno(1,2,3-cd)pyrene. 5.4 Specific properties The iodine number of the powdered activated carbon shall be not less than 600 mg/g. NOTE In certain applications lower values are acceptable. 6 Test methods The methods for sampling an

30、d analysis are those specified in EN 12902 and EN 12903. 7 Labelling - Transportation - Storage 7.1 Means of delivery Powdered activated carbon shall be delivered in paper sacks (10 kg to 25 kg), semi-bulk containers (polypropylene bags, metal or cardboard drums, or corrugated boxes containing 200 k

31、g to 800 kg), or in bulk (up to 50 m). In order that the purity of the product is not affected, the means of delivery shall not have been used previously for any different product or it shall have been specially cleaned and prepared before use. 7.2 Risk and safety labelling according to the EU Direc

32、tives1)Powdered activated carbon is not subject to labelling regulations at the date of the publication of this document. NOTE Annex I of the Directive 67/548/EEC on Classification, packaging and labelling of dangerous substances and its amendments and adaptations in the European Union contains a li

33、st of substances classified by the EU. Substances not in that Annex I should be classified on the basis of their intrinsic properties according to the criteria in the Directive by the person responsible for the marketing of the substance. 1) See Bibliography, 1. DIN EN 15799:2010-05 EN 15799:2010 (E

34、) 7 7.3 Transportation regulations and labelling At the date of the publication of this document: steam activated carbon is not classified as a dangerous substance; chemically activated carbon is listed as UN Number2)1362. RID3) ADR4): class 4.2, classification code S2, packing group III. IMDG5): cl

35、ass 4.2. IATA6): Prohibited. 7.4 Marking The marking shall include the following: the name “powdered activated carbon“, trade name and grade; the net mass; the name and address of supplier and/or manufacturer; the statement “This product conforms to EN 15799“. 7.5 Storage 7.5.1 Long term stability T

36、he product is stable but hygroscopic. It can be stored for an unlimited time if kept dry and away from volatile materials. 7.5.2 Storage incompatibilities The product shall be kept away from oxidants (e.g. hydrogen peroxide, potassium permanganate, chlorates, nitrates), volatile solvents and moistur

37、e. NOTE Local regulations could apply to bulk storage (e.g. in silos). 2) United Nations Number. 3) Regulations concerning International carriage of Dangerous goods by rail. 4) European Agreement concerning the international carriage of Dangerous goods by Road. 5) International Maritime transport of

38、 Dangerous Goods. 6) International Air Transport Association. DIN EN 15799:2010-05 EN 15799:2010 (E) 8 Annex A (informative) General information on powdered activated carbon A.1 Origin A.1.1 Raw materials Powdered activated carbon can be produced from virtually any carbonaceous material, e.g. coal,

39、lignite, peat, coconut shell and wood. A.1.2 Manufacturing process The carbonaceous material is subjected to controlled oxidation during which a highly porous structure is developed. The raw material is activated, thermally (most commonly) or chemically. Thermal activation involves heating to betwee

40、n 800 C and 1 100 C in the presence of an oxidizing gas (usually steam) under carefully controlled conditions for several hours. Chemical activation involves heating to between 400 C and 700 C in the presence of a dehydrating agent (e.g. phosphoric acid). After activation the material is cooled, the

41、n prepared, e.g. by pulverizing and sieving to extract the desired particle size, and packaged. A.2 Properties For the particle size range, the density, the chemical composition and the adsorption properties, see the relevant subclauses in Annex A of EN 12903:2009. A.3 Use A.3.1 Function Powdered ac

42、tivated carbon is used as an adsorbent for the removal of trace organic contaminants (e.g. pesticides, chlorinated solvents, oils), taste- and odour-producing compounds and trihalomethane precursors. It may be used in preference to granular activated carbon particularly to deal with seasonal or inte

43、rmittent problems. A.3.2 Form in which the product is used It is used as delivered. A.3.3 Treatment dose The treatment dose is typically in the range 5 mg/l to 50 mg/l (normally less than 20 mg/l) dependent on pool water quality, treatment objectives and type of filtration (conventional filtration o

44、r ultrafiltration). DIN EN 15799:2010-05 EN 15799:2010 (E) 9 A.3.4 Means of application Powdered activated carbon is dosed as a slurry into the water and removed by subsequent treatment processes (coagulation/flocculation, sedimentation, filtration or ultrafiltration). Dosing equipment should be sel

45、ected so as to avoid the possibility of overdosing. A.4 Rules for safe handling and use It is recommended to handle the product so as to avoid dust formation. Powdered activated carbon preferentially removes oxygen from air. In closed or partially closed containers and vessels, oxygen depletion can

46、reach hazardous levels. If workers are to enter a vessel containing carbon, appropriate sampling and work procedures for potentially low-oxygen areas should be followed. Certain types of chemically activated carbon might have special requirements for transport and storage in bulk; advice should be s

47、ought from the manufacturer. Local regulations can require transfer equipment to be electrically grounded to avoid ignition/explosion of dust by discharge of static electricity. A.5 Emergency procedures A.5.1 First aid In case of skin contact, it is recommended to wash with soap and water. In case o

48、f eye contact, it is recommended to flush with plenty of water for 15 min. In case of inhalation, it is recommended to move to fresh air. A.5.2 Spillage It is recommended to sweep or to vacuum unused carbon and to discard in a refuse container or repackage. A.5.3 Fire Any extinguishing media can be used; it is recommended to use foam extinguishers. Self-contained breathing apparatus should be worn because carbon dioxide and carbon