DIN EN 71-9-2007 Safety of toys - Part 9 Organic chemical compounds - Requirements German version EN 71-9 2005+A1 2007《玩具安全 第9部分 有机化合物 要求》.pdf

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1、September 2007DEUTSCHE NORM English price group 12No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 97.200.50!$I6“138199

2、4www.din.deDDIN EN 71-9Safety of toys Part 9: Organic chemical compounds Requirements (includes Amendment A1:2007)English version of DIN EN 71-9:2007-09Sicherheit von Spielzeug Teil 9: Organisch-chemische Verbindungen Anforderungen (enthlt nderung A1:2007)Englische Fassung DIN EN 71-9:2007-09Superse

3、desDIN EN 71-9:2005-05 andwww.beuth.deDocument comprises 21 pages 1:2007-06DIN EN 71-9 Corrigendum12.07DIN EN 71-9:2007-09 2 Start of validity This standard is valid from 1 September 2007. National foreword This standard contains safety requirements. This standard has been prepared by Technical Comm

4、ittee CEN/TC 52 “Safety of toys” (Secretariat: DS, Denmark) under a mandate of the European Commission and the European Free Trade Association. The responsible German body involved in its preparation was the Normenausschuss Gebrauchstauglichkeit und Dienstleistungen (Performance Capability and Servi

5、ces Standards Committee), Technical Committee NA 039-02-01-03 UA Organisch-chemische Verbindungen in Spielzeug. This standard is the consolidated version of EN 71-9:2005. It incorporates Amendment EN 71-9:2005/ A1:2007 and Corrigendum EN 71-9:2005/AC:2007. The corrections contained in Corrigendum AC

6、:2007 con-cern the German version only. Amendments This standard differs from DIN EN 71-9:2005-05 and DIN EN 71-9 Corrigendum 1:2007-06 as follows: a) Amendment A1:2007 including the following has been incorporated: 1) At various places in the text the term “document” has been replaced by “standard”

7、. 2) Throughout the text, references to prEN 71-10 and prEN 71-11 have been replaced by references to EN 71-10 and EN 71-11. 3) In the introduction the fourth paragraph has been replaced. 4) In Table 1, line 10, the reference to footnote a has been deleted. 5) Subclause A.1 has been replaced. b) Cor

8、rigendum 1:2007-06 concerns the German version only and includes the following: 1) In Table 2 E, column “Limit”, lines 3 to 7, “5 mg/l (total)” has been changed to “0,5 mg/l (total)”. 2) In Table 2 H, column “Limit”, lines 3 and 4, “10 mg/l” has been changed to “10 mg/kg”. Previous editions DIN EN 7

9、1-9: 2005-05 DIN EN 71-9 Corrigendum 1: 2007-06 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-9:2005+A1 July 2007 ICS 97.200.50 Supersedes EN 71-9:2005English Version Safety of toys - Part 9: Organic chemical compounds - Requirements Scurit des jouets - Partie 9: Composs organiques chimiqu

10、es - Exigences Sicherheit von Spielzeug - Teil 9: Organisch-chemische Verbindungen - Anforderungen This European Standard was approved by CEN on 15 November 2004 and includes Amendment 1 approved by CEN on 26 May 2007. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which s

11、tipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Stand

12、ard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national sta

13、ndards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United K

14、ingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-9:2005+A1:2

15、007: EEN 71-9:2005+A1:2007 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 6 2 Normative references 6 3 Terms and definitions .6 4 Requirements.7 4.1 Limits (see A.4) 7 4.2 Liquids in toys (see A.5) .8 4.3 Formaldehyde (see A.6) 8 4.4 Methods of analysis (see A.7) 8 Annex A (informative) Ratio

16、nale 13 A.1 General13 A.2 Accessible liquid (see 3.2)13 A.3 Polymeric (see 3.6) 13 A.4 Limits (see 4.1).13 A.5 Liquids in toys (see 4.2) 14 A.6 Formaldehyde (see 4.3).14 A.7 Methods of analysis (see 4.4).14 A.8 Colourants and primary aromatic amines (see Table 1, Table 2 B and Table 2 C).14 A.9 Appl

17、icable limit tables (see Table 1)15 A.10 Limit tables (see Tables 2 A to 2 I).15 A.11 Toys containing cosmetic components 16 Annex B (informative) Conformity assessment .17 Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives

18、18 Bibliography 19 Tables of 4.4 Table 1 Applicable limit tables Table 2 A Flame retardants Table 2 B Colourants Table 2 C Primary aromatic amines Table 2 D Monomers (migration) Table 2 E Solvents (migration) Table 2 F Solvents (inhalation) Table 2 G a) and b) Wood preservatives Table 2 H Preservati

19、ves (other than wood preservatives) Table 2 I Plasticisers (migration) EN 71-9:2005+A1:2007 (E) 3 Foreword This document (EN 71-9:2005+A1:2007) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This document shall be given the status of a na

20、tional standard, either by publication of an identical text or by endorsement, at the latest by January 2008 and conflicting national standards shall be withdrawn at the latest by January 2008. This document includes Amendment 1 approved by CEN on 2007-05-26. This document supersedes EN 71-9:2005. T

21、he start and finish of text introduced or altered by amendment is indicated in the text by tags ! “. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationsh

22、ip with EU Directive(s), see informative Annex ZA, which is an integral part of this document. This standard constitutes part 9 of the European Standard on Safety of Toys. This part should be read in conjunction with parts 10 and 11. This !standard“ defines contact routes and specifies limits for th

23、e migration or content of certain chemical compounds in toys. This !standard“ contains three annexes: - Annex A (informative) Rationale - Annex B (informative) Conformity assessment - Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU

24、 Directives. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ire

25、land, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 71-9:2005+A1:2007 (E) 4 Introduction The !standard“ EN 71 for safety of toys consists of the following parts. Part 1: Mechanical an

26、d physical properties Part 2: Flammability Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test me

27、thods Part 8: Swings, slides and similar activity toys for indoor and outdoor family domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The !standards“ EN 71-9, !EN

28、 71-10“ and !EN 71-11“ were mandated by the European Commission (M/229) to address the risks presented by organic compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This !standard“ gives req

29、uirements for organic compounds in certain toys and toy materials. In drafting the !standard“, CEN/TC 52 considered the risks associated with more than 650 organic compounds. It was recognized that not all potentially hazardous organic compounds could be addressed. The Commission further restricted

30、the Mandate to substances classified as dangerous under Council Directive 67/548/EEC. This !standard“, therefore, supports but does not reduce the responsibility of toy manufacturers, importers and suppliers for ensuring that the use of other substances will not endanger the health whilst playing wi

31、th toys as intended or in a reasonably foreseeable way. In addition, there should be no exposure to children from toys, in amounts which may harm their health, of organic chemical substances which are classified by other relevant statutes as carcinogenic, mutagenic or toxic for reproduction and for

32、which no requirements are specified in this !standard“. !Future editions of this standard may address additional organic compounds. Users of this standard are reminded that compliance with the standard can only provide presumption of conformity with the essential safety requirements of the Toys Safe

33、ty Directive in respect of the substances addressed.“ This part should be read in conjunction with !EN 71-10“, which describes sample preparation and extraction procedures, and !EN 71-11“, which specifies methods of analysis. At the date of publication, the standard does not specify requirements for

34、 chemical compounds which are prohibited in toys by Council Directive 76/769/EEC of 27thJuly 1976, as amended, on restrictions on the marketing and use of certain dangerous substances and preparations. This !standard“ takes into account the opinion of the Toxicology Section of the Scientific Advisor

35、y Committee published in 1992 (EUR 13976) which recommended that certain groups of chemical compounds used in toys and toy materials need to be given special attention. In drafting this !standard“ CEN/TC 52 has considered organic chemicals that can be classified within the following groups: Solvents

36、 Preservatives Plasticisers (excluding phthalate plasticisers)1 Flame retardants Monomers Biocides (wood preservatives) 1Phthalate plasticisers were specifically excluded from the scope of mandate M/229. EN 71-9:2005+A1:2007 (E) 5 Processing aids Colouring agents During the development of this !stan

37、dard“, CEN/TC 52 has considered the requirements set out in Council Directive 82/711/EEC as amended and its supporting standards. EN 71-9:2005+A1:2007 (E) 6 1 Scope This Part 9 of the !standard“ EN 71 for safety of toys specifies requirements for the migration or content of certain hazardous organic

38、 chemical compounds from/in certain toys and toy materials (see Table 1) by the following exposure routes: - mouthing - ingestion - skin contact - eye contact - inhalation when used as intended or in a foreseeable way, bearing in mind the normal behaviour of children and the function and design of t

39、he toy. This !standard“ does not contain requirements for chemical toys, experimental sets or finger-paints, which are addressed by other parts of EN 71. Packaging materials used with toys are not within the scope of the !standard“ unless they form part of the toy or have intended play value. 2 Norm

40、ative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. !EN 71-1:2005+A4:2007“, Safety o

41、f toys - Part 1: Mechanical and physical properties EN 71-5, Safety of toys Part 5: Chemical toys (sets) other than experimental sets !EN 71-10, Safety of toys - Part 10: Organic chemical compounds - Sample preparation and extraction“ !EN 71-11, Safety of toys - Part 11: Organic chemical compounds -

42、 Methods of analysis“ EN 645, Paper and board intended to come into contact with foodstuffs Preparation of a cold water extract EN 717-3, Wood-based panels Determination of formaldehyde release Part 3: Formaldehyde release by the flask method EN 1541, Paper and board intended to come into contact wi

43、th foodstuffs - Determination of formaldehyde in an aqueous extract EN ISO 787-9, General methods of test for pigments and extenders Part 9: Determination of pH value of aqueous suspension (ISO 787-9:1981) EN ISO 14184-1, Textiles Determination of formaldehyde Part 1: Free and hydrolysed formaldehyd

44、e (water extraction method) (ISO 14184-1:1998) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. EN 71-9:2005+A1:2007 (E) 7 3.1 accessible contact with the articulated probe when tested in accordance with the accessibility-of-a-part-or-component te

45、st in !EN 71-1:2005+A4:2007“ 3.2 (see A.2) accessible liquid liquid in or on a toy or accompanying a toy to which the child is likely to become exposed during normal or foreseeable use of the toy (e.g. liquid paints, bubble liquids, ink in pens, liquids provided with toys for squirting) 3.3 mouth-ac

46、tuated toy toy which relies on an action of the mouth to operate and which therefore is designed to come into contact with the mouth during play (e.g. toy whistles, toy imitation novelty teeth). Inflatable toys are not considered mouth-actuated toys unless they rely on an action of the mouth after i

47、nflation 3.4 mouthed licked, sucked and chewed 3.5 paper material, marketed as either paper or paperboard, with a maximum mass per unit area of 400 g/m2!EN 71-1:2005+A4:2007“ 3.6 (see A.3) polymeric consisting of plastic, synthetic rubber, natural rubber, silicone polymer but not other natural polym

48、ers 3.7 resin-bonded wood wood-based material, for example, plywood, particle board, chipboard and medium-density fibreboard (MDF) 3.8 textile woven or knitted fabrics, non-woven fibrous material (e.g. felt) 3.9 toy material material from which toys and toy components are made 3.10 toy which a child

49、 can enter any toy, having a door, lid or similar device, which encloses a continuous volume greater than 0,03 m3and in which all internal dimensions are 150 mm or more. 4 Requirements 4.1 Limits (see A.4) 4.1.1 Table 1 specifies toys, toy components and toy materials for which this !standard“ contains requirements. An “X” is indicated in columns 2A 2I when requirements are given in the limit Tables 2 A 2 I for certain groups of organic chemicals. The toys and accessible toy components specified in Table 1