DIN EN 15072-2013 Chemicals used for treatment of swimming pool water - Sodium dichloroisocyanurate anhydrous German version EN 15072 2013《游泳池水处理用化学品 无水二氯异氰脲酸钠 德文版本EN 15072-2013》.pdf

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1、August 2013 Translation by DIN-Sprachendienst.English price group 12No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、 71.100.80!%(28“2051521www.din.deDDIN EN 15072Chemicals used for treatment of swimming pool water Sodium dichloroisocyanurate, anhydrous;English version EN 15072:2013,English translation of DIN EN 15072:2013-08Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser Natriumdichlorisocyanurat, was

3、serfrei;Englische Fassung EN 15072:2013,Englische bersetzung von DIN EN 15072:2013-08Produits chimiques utiliss pour le traitement de leau des piscines Dichloroisocyanurate de sodium, anhydre;Version anglaise EN 15072:2013,Traduction anglaise de DIN EN 15072:2013-08SupersedesDIN EN 15072:2008-06www.

4、beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.1707.13 DIN EN 15072:2013-08 2 A comma is used as the decimal marker. National foreword This document (EN 15072:2013) has been prepared by Technical Committee CEN/TC 164 “Water supply” (S

5、ecretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Committee NA 119-04-02 AA Wasseraufbereitung. Amendments This standard differs from DIN EN 15072:2008-06 as follows: a) specifications

6、 concerning hazard and safety related symbols have been brought in line with the “Globally Harmonized System of Classification, Labelling and Packaging of Chemicals (GHS)” (Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien). b) purity criteria have been adapted to DIN EN

7、12931. Previous editions DIN EN 15072: 2006-09, 2008-06 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15072 May 2013 ICS 71.100.80 Supersedes EN 15072:2006+A1:2008English Version Chemicals used for treatment of swimming pool water - Sodium dichloroisocyanurate, anhydrous Produits chimiques ut

8、iliss pour le traitement de leau des piscines - Dichloroisocyanurate de sodium, anhydre Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser - Natriumdichlorisocyanurat, wasserfreiThis European Standard was approved by CEN on 28 March 2013. CEN members are bound to comply with the CEN/CENELEC

9、 Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or t

10、o any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the offici

11、al versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, N

12、orway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation i

13、n any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15072:2013: EEN 15072:2013 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 5 2 Normative reference 5 3 Description .5 3.1 Identification .5 3.2 Commercial form .6 3.3 Physical properties 6 3.4 Chemical proper

14、ties 7 4 Purity criteria 7 4.1 General 7 4.2 Composition of commercial product .7 4.3 Impurities and main by-products .7 4.4 Toxic substances .7 5 Test methods 8 6 Labelling - Transportation - Storage 8 6.1 Means of delivery .8 6.2 Labelling according to the EU legislation 8 6.3 Transportation regul

15、ations and labelling . 10 6.4 Marking 10 6.5 Storage . 10 Annex A (informative) General information on sodium dichloroisocyanurate, anhydrous . 12 A.1 Origin . 12 A.2 Use . 12 Annex B (normative) General rules relating to safety 14 B.1 Rules for safe handling and use . 14 B.2 Emergency procedures 14

16、 Bibliography . 15 DIN EN 15072:2013-08 EN 15072:2013 (E) 3 Foreword This document (EN 15072:2013) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publica

17、tion of an identical text or by endorsement, at the latest by November 2013, and conflicting national standards shall be withdrawn at the latest by November 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC

18、shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 15072:2006+A1:2008. Significant technical differences between this edition and EN 15072:2006+A1:2008 are as follows: Replacement of warning and safety precautions notes by labelling according to

19、Regulation (EC) No 1272/2008. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Repu

20、blic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 15072:2013-08 EN 15072:2013 (E) 4 Introduction In

21、respect of potential adverse effects on the quality of water intended for swimming pools caused by the product covered by this European Standard, the following statements apply: a) This European Standard provides no information as to whether the product may be used without restriction in any of the

22、Member States of the EU or EFTA. b) It should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE 1 Conformity with this European Standard does not confer or impl

23、y acceptance or approval of the products in any of the Member States of the EU or EFTA. The use of the products covered by this European Standard is subject to regulation or control by National Authorities. NOTE 2 This product is a biocide and needs to comply with the relevant legislation in force.

24、In the European Union, at the time of publication, this legislation is Directive 1998/8/EC 1. DIN EN 15072:2013-08 EN 15072:2013 (E) 5 1 Scope This European Standard is applicable to sodium dichloroisocyanurate, anhydrous used directly or used to prepare commercial formulations for disinfecting swim

25、ming pool water. It describes the characteristics of sodium dichloroisocyanurate, anhydrous and specifies the requirements and the corresponding test methods for sodium dichloroisocyanurate, anhydrous. It gives information on its use for treating swimming pool water and determines the rules relating

26、 to safe handling and use (see Annex B). 2 Normative reference The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the

27、referenced document (including any amendments) applies. EN 12931, Chemicals used for treatment of water intended for human consumption Chemicals for emergency use Sodium dichloroisocyanurate, anhydrous 3 Description 3.1 Identification 3.1.1 Chemical name 1-sodium - 3,5-dichloro - 1,3,5-triazine - 2,

28、4,6-trione. 3.1.2 Synonym or common name Sodium dichloroisocyanurate. 3.1.3 Relative molecular mass 219,98. 3.1.4 Empirical formula C3N3O3Cl2Na. 3.1.5 Chemical formula DIN EN 15072:2013-08 EN 15072:2013 (E) 6 3.1.6 CAS Registry Number 1)2893-78-9. 3.1.7 EINECS reference 2)2-207-67-7. 3.2 Commercial

29、form The product is available in various granular forms. 3.3 Physical properties 3.3.1 Appearance and odour The product is a white granular solid with chlorinous odour. 3.3.2 Density The bulk density is approximately 0,9 g/cm3. 3.3.3 Solubility in water The solubility in water is 250 g/l at 25 C. 3.

30、3.4 Vapour pressure Not applicable. 3.3.5 Boiling point at 100 kPa 3)Not applicable, the product decomposes before fusion. 3.3.6 Melting point Not applicable. 3.3.7 Specific heat (1 090 40) J/kg.K at 20 C. 3.3.8 Viscosity, (dynamic) Not applicable. 3.3.9 Critical temperature Not applicable. 1) Chemi

31、cal Abstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. 3) 100 kPa = 1 bar. DIN EN 15072:2013-08 EN 15072:2013 (E) 7 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties The product is a strong oxid

32、ant. It is corrosive and hygroscopic; sodium dichloroisocyanurate decomposes into hydrochloric acid and cyanuric acid. When dissolved in an excess of water, it liberates chlorine by hydrolysis. 4 Purity criteria 4.1 General Limits have been given for impurities and toxic substances where these are l

33、ikely to be present in significant quantities from the current production process and raw materials. If a change in the production process or raw materials leads to significant quantities of other impurities or by-products being present, the user shall be notified. 4.2 Composition of commercial prod

34、uct The product shall contain at least 62 percent by mass (% (m/m) of available chlorine. 4.3 Impurities and main by-products The water content shall be less than 3 % (m/m) of the product. The sodium chloride content shall be less than 0,05 % (m/m) of the product. 4.4 Toxic substances NOTE For the p

35、urpose of this standard, “toxic substances“ are those defined in the EU Directive 80/778/EEC of 15 July, 1980 1. The content of toxic substances shall conform to the requirements specified in Table 1. DIN EN 15072:2013-08 EN 15072:2013 (E) 8 Table 1 Toxic substances Element Limit mg/kg of product Ty

36、pe 1 Type 2 Arsenic (As) max. 10 10 Cadmium (Cd) max. 1 1 Chromium (Cr) max. 6 10 Mercury (Hg) max. 0,02 0,02 Nickel (Ni) max. 3 5 Lead (Pb) max. 4 15 Antimony (Sb) max. 5 5 Selenium (Se) max. 1 1 NOTE Cyanide, which does not exist in a strong oxidising medium such as sodium dichloroisocyanurate, is

37、 not a relevant toxic substance (see 2). Pesticides and polycyclic aromatic hydrocarbons are not by-products of the manufacturing process. 5 Test methods The sampling and the analytical methods are those described in EN 12931. 6 Labelling - Transportation - Storage 6.1 Means of delivery The product

38、shall be delivered in fibre or polyethylene drums or semi-bulk containers. To ensure the purity of the product, the means of delivery shall not have previously been used for any different product or it shall have been specially cleaned and prepared before use. 6.2 Labelling according to the EU legis

39、lation 4)The following labelling requirements shall apply to sodium dichloroisocyanurate anhydrous at the date of the publication of this European Standard. 4) See 3. DIN EN 15072:2013-08 EN 15072:2013 (E) 9 Figure 1 GHS 03 Figure 2 GHS 07 Figure 3 GHS 09 Signal word: Danger Classification and hazar

40、d statement: H272 May intensify fire; oxidiser H 302 Harmful if swallowed H400 Very toxic to aquatic life DIN EN 15072:2013-08 EN 15072:2013 (E) 10 The regulation 3, and its amendments for the purposes of its adaptation to technical and scientific progress, contains a list of substances classified b

41、y the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to the criteria in the regulation by the person responsible for the marketing of the substance. 6.3 Transportation regulations and labelling Sodium dichloroisocyanurate, anhyd

42、rous is listed as UN Number 5)2465 and is classified as follows: RID 6): class 5.1, classification code O2, packing group II; ADR 7): class 5.1, classification code O2, packing group II; IMDG 8): class 5.1; IATA 9): class 5.1. 6.4 Marking The marking shall include the following: name “sodium dichlor

43、oisocyanurate, anhydrous”, trade name and type; net mass; name and the address of supplier and/or manufacturer; statement “this product conforms to EN 15072“. 6.5 Storage 6.5.1 General The product shall be stored in its original package, firmly closed in a cool and dry place, away from any sources o

44、f heat or incompatible materials. 6.5.2 Long term stability When stored in above conditions, the product is stable for at least three years. 6.5.3 Storage incompatibilities Store the product on its own if possible. Keep it away from: water; strong acids; 5) United Nations Number. 6) Regulations conc

45、erning International carriage of Dangerous goods by rail. 7) European Agreement concerning the international carriage of Dangerous goods by Road. 8) International maritime transport of Dangerous Goods. 9) International Air Transport Association. DIN EN 15072:2013-08 EN 15072:2013 (E) 11 nitrogenated

46、 products; organic solvents; hydrocarbons; peroxides; hypochlorites; oils, greases and organic materials; ammonium salts; basic products. DIN EN 15072:2013-08 EN 15072:2013 (E) 12 Annex A (informative) General information on sodium dichloroisocyanurate, anhydrous A.1 Origin A.1.1 Raw materials Sodiu

47、m dichloroisocyanurate, anhydrous is manufactured from isocyanuric acid (CNOH)3, sodium hydroxide (NaOH) and chlorine (Cl2). A.1.2 Manufacturing process Sodium dichloroisocyanurate, anhydrous is produced by chlorination of disodium cyanurate (Na2H(NCO)3) using chlorine (Cl2) and neutralisation with

48、sodium hydroxide (NaOH). Disodium cyanurate is obtained by action of sodium hydroxide on isocyanuric acid. A.2 Use A.2.1 Function The product is used as a disinfectant of swimming pool water. It is an indirect source of free chlorine (HOCl) when dissolved in water via an organic carrier substance (sodium cyanurate, C3N3O3H2Na): C3N3O3Cl2Na + 2H2O - C3N3O3H2Na + 2HOCl (A.1) As the disinfectant (HOCl) is used up, more chlorine atoms are released from “sodium dichloroisocyanurate, anhydrou