DIN EN 14742-2015 Characterization of sludges - Laboratory chemical conditioning procedure German version EN 14742 2015《污泥的特性 试验室化学条件程序 德文版本EN 14742-2015》.pdf

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1、July 2015Translation by DIN-Sprachendienst.English price group 12No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13

2、.030.20!%CoZ“2327655www.din.deDDIN EN 14742Characterization of sludges Laboratory chemical conditioning procedure;English version EN 14742:2015,English translation of DIN EN 14742:2015-07Charakterisierung von Schlmmen Laborverfahren zur chemischen Konditionierung;Englische Fassung EN 14742:2015,Engl

3、ische bersetzung von DIN EN 14742:2015-07Caractrisation des boues Mode opratoire de conditionnement chimique en laboratoire;Version anglaise EN 14742:2015,Traduction anglaise de DIN EN 14742:2015-07SupersedesDIN-Fachbericht CEN/TR 14742:2006-10www.beuth.deIn case of doubt, the German-language origin

4、al shall be considered authoritative.Document comprises 21 pages06.15 DIN EN 14742:2015-07 2 A comma is used as the decimal marker. National foreword This document (EN 14742:2015) has been prepared by Technical Committee CEN/TC 308 “Characterization of sludges” (Secretariat: AFNOR, France). The resp

5、onsible German body involved in its preparation was the DIN-Normenausschuss Wasserwesen (DIN Standards Committee Water Practice), Working Committee NA 119-01-02-02 UA Chemische und physika-lische Verfahren of NA 119-01-02 AA Abfall- und Bodenuntersuchung. The DIN Standard corresponding to the Intern

6、ational Standard referred to in this document is as follows: ISO 5725-2 DIN ISO 5725-2 Amendments This standard differs from DIN-Fachbericht CEN/TR 14742:2006-10 as follows: a) normative references have been updated; b) Clause 3 “Terms and definitions” has been updated; c) Clause 4 “Principle” has b

7、een updated and supplemented with notes on conditioning agents; d) Clause 6 “Procedure” has been updated; e) figures have been updated. Previous editions DIN-Fachbericht CEN/TS 14742: 2006-10 National Annex NA (informative) Bibliography DIN ISO 5725-2, Accuracy (trueness and precision) of measuremen

8、t methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method EN 14742 April 2015 ICS 13.030.20 Supersedes CEN/TR 14742:2006English Version Characterization of sludges - Laboratory chemical conditioning procedure Caractrisation

9、 des boues - Mode opratoire de conditionnement chimique en laboratoire Charakterisierung von Schlmmen - Laborverfahren zur chemischen Konditionierung This European Standard was approved by CEN on 28 February 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipul

10、ate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European St

11、andard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the n

12、ational standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,

13、Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14742:2015 EEUROPEAN STANDARDNORME EUR

14、OPENNEEUROPISCHE NORMEUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGEN 14742:2015 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 5 2 Normative references 5 3 Terms and definitions .5 4 Principle 5 5 Apparatus .6 6 Procedure .7 7 Test report

15、8 8 Precision .9 Annex A (informative) Results of Validation trials . 10 Annex B (informative) Examples for mixing devices for chemical conditioning procedure . 15 Annex C (informative) Example of table summarizing the operating conditions and the results of the characterization tests 17 Bibliograph

16、y . 19 DIN EN 14742:2015-07EN 14742:2015 (E) 3 Foreword This document (EN 14742:2015) has been prepared by Technical Committee CEN/TC 308 “Characterization of sludges”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publi

17、cation of an identical text or by endorsement, at the latest by October 2015, and conflicting national standards shall be withdrawn at the latest by October 2015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC

18、shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TR 14742:2006. The main changes with respect to CEN/TR 14742 are listed below: a) normative references have been updated; b) terms and definitions have been updated; c) principle has been update

19、d and supplemented with notes on conditioning agents; d) procedure has been updated; e) figures have been updated. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulga

20、ria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Tur

21、key and the United Kingdom. DIN EN 14742:2015-07EN 14742:2015 (E) 4 Introduction This method gives a standardized procedure for the conditioning operation when selecting a conditioning product at laboratory scale and also for the production of flocculated thickened sludge for subsequent dewatering t

22、ests. These tests may also provide details regarding energy requirements, provided information on stirring power is available. DIN EN 14742:2015-07EN 14742:2015 (E) 5 1 Scope The laboratory assessment of sludge dewaterability is sensitive to the operating procedure adopted for the conditioning step.

23、 No generalized ranking of products in order of effectiveness can be given since the ranking changes with the sludge type, dosage of conditioning agent, degree of shearing and dewatering device. The scope of this European Standard applies for sludges and suspensions from: storm water handling; urban

24、 wastewater collecting systems; urban wastewater treatment plants; industrial wastewater that has been treated similarly to urban wastewater (as defined in Directive 91/271/EEC); water supply plants. This method is applicable to sludge and suspensions of other origin. 2 Normative references The foll

25、owing documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12832, Chara

26、cterization of sludges Utilization and disposal of sludges Vocabulary EN 12880, Characterization of sludges Determination of dry residue and water content EN 14701-4, Characterization of sludges Filtration properties Part 4: Determination of the drainability of flocculated sludges EN 15933, Sludge,

27、treated biowaste and soil Determination of pH ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method 3 Terms and definitions For the purposes of this document, t

28、he terms and definitions given in EN 12832 and the following apply. 3.1 chemical conditioning mixing of a chemical product with the sludge in order to increase its thickenability/dewaterability 4 Principle Sludge conditioned in accordance with this procedure (Clause 6) can subsequently be used in sp

29、ecific characterization tests in order to determine the most suitable operating conditions for each particular sludge or suspension; these tests determine particularly the required nature of the reagent, the dosage, and the sequence of adding the reagent. Each test is performed as a batch process. D

30、IN EN 14742:2015-07EN 14742:2015 (E) 6 Variables and/or parameters that can have significant effects on the conditioned sludge are either chemical or physical. Chemical parameters: characteristics of the sludge, e.g. pH, dry residue, loss on ignition; characteristics of the conditioning product, e.g

31、. charge density, molecular weight, chemical structure; concentration and dosage of the chemical product; water used for on-site product preparation when polyelectrolytes are added. Physical parameters: method of preparing the solution and its storage; intensity and duration of stirring; characteris

32、tics of the stirrer, i.e. type, dimensions, position; method of injecting the conditioning product into the sludge; (separation-) time between the end of mixing and the dewatering procedure itself. The method of mixing the conditioning product into the sludge is particularly important since inadequa

33、te mixing, leading to poor initial dispersion or strong floc shearing, can result in very poor test performances: a large portion of the product may react instantly with particles upon first contact, without dispersing throughout the mixture. Inorganic coagulants are generally injected into a reacto

34、r with a short residence time (1 min to 5 min) in a high shearing condition. For this purpose, the reactor is equipped with a high rotating speed stirrer that enables an instantaneous dispersion of the product and brings the high energy needed (e.g. 80 W/m3to 100 W/m3). Polyelectrolytes are injected

35、 into a reactor with a residence time of a few seconds to a few minutes. As far as mechanical degradation can occur, the shearing rate is 4 to 10 times lower than for coagulants and the energy needed lower (e.g. 40 W/m3to 50 W/m3). The conditioning procedure may concern the addition of more than one

36、 product. In that case, the addition sequence is another parameter that requires careful instructing. 5 Apparatus 5.1 Device with control and measurement of physical parameters (variable stirrer/mixer speed and time, position of mechanical stirrer depending on sludge volume, see Annex B). A magnetic

37、 stirrer is not recommended, as it does not ensure homogenous and reproducible mixing. A mechanical stirrer with 4 horizontal perpendicular blades is recommended for proper polymer dispersion and floc maturation. In case the formed flocs are very sensitive to shearing, a tilted 3-blade stirrer (see

38、Annex B) should be used. The characteristics of mechanical stirrer shall be the same in comparative tests. Length of each impeller blade should be between 1/4 and 1/3 of the beaker diameter. 5.2 Beakers, volume 200 ml to 1 000 ml. 5.3 Volumetric pipettes or syringe or automatic polymer injection sys

39、tem at constant flow rate. 5.4 Analytical balance with a precision of at least 0,1 mg. DIN EN 14742:2015-07EN 14742:2015 (E) 7 5.5 pH-meter 5.6 Chronometer, e.g. stopwatch, computer. 5.7 Apparatus for evaluation of flocculation drainability, e.g. drainage cell (see EN 14701-4). 6 Procedure 6.1 Measu

40、re the pH of the sludge to be tested according to EN 15933. If necessary, adjust the pH to meet the requirements of the conditioning agent to be used. 6.2 Measure the dry residue of the sludge to be tested according to EN 12880. NOTE The loss on ignition could be determined for additional informatio

41、n. For details, see EN 15935. 6.3 Put a defined amount of sludge into a beaker. The amount of sludge should be between 25 % and 50 % of the capacity of the beaker to avoid loss of sludge during mixing and sludge height between 0,5 and 1 diameter of the cell to ensure proper mixing. It should be take

42、n into account that the whole flocculated sludge will be transferred in a drainage cell and the quantity of dry matter deposited on the filter cloth should be between 0,25 kg/m2and 1,5 kg/m2. 6.4 Adjust the position of the stirrer to the sludge volume (the stirrer should be positioned from the beake

43、r bottom at 1/3 of the sludge volume). 6.5 Polymer addition and dispersion Add a precise amount of conditioning agent using a volumetric pipette or syringe before stirring. Ensure proper distribution of the polymer, across the level surface of the sludge. If the conditioning agent injection is prepa

44、red during the stirring of the sludge, add it in the shortest amount of time possible at a controlled and constant flow rate. It is recommended to report the time of the beginning of the injection (TB1) and the time at the end of the injection (TE1). The solution of conditioning agent should be prep

45、ared according to the recommendations of suppliers and should be used the day of preparation within 3 h after preparation. NOTE Rapid pre-selection of conditioning agents can be made by pouring the sludge back and forth between two beakers in order to check if flocs are formed. In case of coagulant

46、use, disperse the product at high speed (1 700 rpm) for 2 min and let the microflocs grow at 700 rpm. In case of polymer use, the mixing speed of the horizontal 4-blade impeller should be kept constant at 700 rpm since polymer dispersion and floc maturation occur simultaneously. In case of highly sh

47、ear-sensitive flocs, it is recommended to disperse the flocculent in the sludge using an axial impeller (tilted 3-blade impeller) at high speed (1 700 rpm) for a very short time (2 s max), followed by a low speed (700 rpm) to enable floc growing. In this case, it is useful to differentiate: TBB1: Be

48、ginning time of polymer dispersion = TE1 TEE1: End of polymer dispersion TBB2: Beginning of polymer maturation DIN EN 14742:2015-07EN 14742:2015 (E) 8 TEE2: End of polymer maturation 6.6 Floc maturation Continue stirring until polymer maturation (TEE2) is reached. Mixing time is the variable paramet

49、er for floc growth, depending on the sludge and conditioning agent characteristics. Preliminary tests are recommended to evaluate this parameter by visual observation of floc formation without shearing or by quantitative measurement (torque measurement, particle size). Then, mixing time will be fixed and kept constant for comparative tests. 6.7 Transfer the whole flocculated sludge into a drainage cell to evaluate flocculation drainability according t