CGSB 3 24-2012-CGSB-2012 Aviation Turbine Fuel (Military Grades F-34 and F-44).pdf

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1、CGSB3.242012Supersedes CGSB-3.24-2008Aviation Turbine Fuel (Military Grades F34 and F44) ICS 75.160.20CGSB StandardCopyright Canadian General Standards Board Provided by IHS under license with CGSBNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-The CANADIAN GENERAL

2、 STANDARDS BOARD (CGSB), under whose auspices this standard has been developed is a government agency within Public Works and Government Services Canada. CGSB is engaged in the production of voluntary standards in a wide range of subject areas through the media of standards committees and the consen

3、sus process. The standards committees are composed of representatives of relevant interests including producers, consumers and other users, retailers, governments, educational institutions, technical, professional and trade societies, and research and testing organizations. Any given standard is dev

4、eloped on the consensus of views expressed by such representatives. CGSB has been accredited by the Standards Council of Canada as a national standards-development organization. The standards that it develops and offers as National Standards of Canada conform to the criteria and procedures establish

5、ed for this purpose by the Standards Council of Canada. In addition to standards it publishes as national standards, CGSB produces standards to meet particular needs, in response to requests from a variety of sources in both the public and private sectors. Both CGSB standards and CGSB national stand

6、ards are developed in conformance with the policies described in the CGSB Policy Manual for the Development and Review of Standards. CGSB standards are subject to review and revision to ensure that they keep abreast of technological progress. Suggestions for their improvement, which are always welco

7、me, should be brought to the notice of the standards committees concerned. Changes to standards are issued either as separate amendment sheets or in new editions of standards. An up-to-date listing of CGSB standards, including details on latest issues and amendments, and ordering instructions, is fo

8、und in the CGSB Catalogue, which is published annually and is available without charge upon request. More information is available about CGSB products and services at our Web site www.ongc-cgsb.gc.ca. Although the intended primary application of this standard is stated in its Scope, it is important

9、to note that it remains the responsibility of the users of the standard to judge its suitability for their particular purpose. The testing and evaluation of a product against this standard may require the use of materials and/or equipment that could be hazardous. This document does not purport to ad

10、dress all the safety aspects associated with its use. Anyone using this standard has the responsibility to consult the appropriate authorities and to establish appropriate health and safety practices in conjunction with any applicable regulatory requirements prior to its use. CGSB neither assumes no

11、r accepts any responsibility for any injury or damage that may occur during or as the result of tests, wherever performed. Attention is drawn to the possibility that some of the elements of this Canadian standard may be the subject of patent rights. CGSB shall not be held responsible for identifying

12、 any or all such patent rights. Users of this standard are expressly advised that determination of the validity of any such patent rights are entirely their own responsibility. Further information on CGSB and its services and standards may be obtained from: The Manager Standards Division Canadian Ge

13、neral Standards Board Gatineau, Canada K1A 1G6 How to order Publications: by telephone 819-956-0425 or 1-800-665-2472 by fax 819-956-5740 by mail CGSB Sales Centre Gatineau, Canada K1A 1G6 in person Place du Portage Phase III, 6B1 11 Laurier Street Gatineau, Quebec by email ncr.cgsb-ongctpsgc-pwgsc.

14、gc.ca on the Web www.tpsgc-pwgsc.gc.ca/ongc-cgsb Copyright Canadian General Standards Board Provided by IHS under license with CGSBNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Canadian General Standards Board CGSB3.242012Supersedes CGSB-3.24-2008 AVIATION TURBIN

15、E FUEL (MILITARY GRADES F34 AND F44) NATIONAL STANDARD OF CANADA CAN/CGSB3.142006Prepared by the Canadian General Standards BoardPublished April 2012 by the Canadian General Standards Board Gatineau, Canada K1A 1G6 HER MAJESTY THE QUEEN IN RIGHT OF CANADA, as represented by the Minister of Public Wo

16、rks and Government Services, the Minister responsible for the Canadian General Standards Board (2012). No part of this publication may be reproduced in any form without the prior permission of the publisher.Copyright Canadian General Standards Board Provided by IHS under license with CGSBNot for Res

17、aleNo reproduction or networking permitted without license from IHS-,-,-CANADIAN GENERAL STANDARDS BOARDCOMMITTEE ON AVIATION FUELS(Voting membership at date of approval)ChairPoitras, P. National Defence (User)General Interest CategoryHanganu, A. OTI Canada GroupPickard, A.L. ConsultantTharby, R.D.

18、Tharby Technology, ConsultantsVidian-Jones, C. Certispec Services Inc.Wispinski, D. Alberta Innovates Technology FuturesProducer CategoryBurgazli, J. Innospec Inc.Conn, A. Ethyl CorporationJobin, J.L. Ultramar Ltd.Kenney, B. Suncor Energy Inc.Lund, C. Imperial OilMillard, P. GE Water and Process Tec

19、hnologiesMitchell, K. Shell Canada Ltd.Robichaud S. Irving Oil Ltd.Regulator CategoryDhaliwal, R. Transport CanadaUser CategoryBrar, C. Air CanadaEveleigh, S. Government of Northwest TerritoriesMacLeod, B. Public Works and Government Services CanadaMolinari, J. Air Transport Association of CanadaTau

20、vette, G. WestJet Airlines Ltd.Waddleton, D. Pratt however, when results are obtained by both methods, D2276 shall be considered the referee method.Copyright Canadian General Standards Board Provided by IHS under license with CGSBNot for ResaleNo reproduction or networking permitted without license

21、from IHS-,-,-CGSB3.242012 5F34 F44 Test MethodASTMMin. Max. Min. Max.5.12 Electrical Conductivity (par. 6.2)5.12.1 At point, time and temperature of delivery, pS/m 50 600 600 D26245.13 Additives (par. 8.6)5.13.1 Static dissipator additive (par. 6.2), mg/La. Original addition 3 3b. Cumulative 5 55.13

22、.2 Antioxidant (par. 6.3), mg/La. Hydrogen-processed11portion 17.2 24 17.2 24b. Non-hydrogen-processed portion Optional Optional 24 245.13.3 Metal deactivator (par. 6.4), mg/L Optional Optional 5.7 5.75.13.4 Fuel system icing inhibitor (par. 6.5), % by volume 0.10 0.15 0.10 0.15 D50065.13.5 Corrosio

23、n inhibitor/lubricity improver (par. 6.6) QPL-25017 QPL-250175.13.6 Leak detection additive (par. 6.7), mg/kg Optional Optional 1 15.14 Extended requirements for fuels containing synthesized hydrocarbons12(par. 4.2.1)5.14.1 Synthetic hydrocarbon content13, % by volume 50 505.14.2 Aromatics14, % by v

24、olumea. or 8 8 D13191b. 8.4 8.4 D637910The minimum micro-separometer (MSEP) rating applies at the point immediately before the fuel enters dedicated transportation to military storage. MSEP by ASTM D7224 can be useful in determining the water separation characteristics of a batch of jet fuel even wh

25、en additized with static dissipator additive and certain other additives that do not actually degrade water separation performance in coalescing separators. When the fuel enters dedicated transportation to military storage, or when the fuel is already in military storage, the MSEP rating requirement

26、 shall not apply. When a corrosion inhibitor/lubricity improver (par. 6.6) is added, the MSEP limits apply before its addition. For clarity MSEP results shall be reported by test method (i.e. MSEP by ASTM D3948 or MSEP by ASTM D7224).11Hydrogen-processing is any petroleum refining process that uses

27、hydrogen in the presence of a catalyst.12The synthetic hydrocarbon content, aromatics, distillation slope, and lubricity criteria only apply to aviation turbine fuels produced to this specification that contain syntheteic hydrocarbons. The criteria do not apply to aviation turbine fuels produced to

28、CGSB-3.24 from conventional hydrocarbons and that do not contain synthetic hydrocarbons. The criteria are also not applicable to aviation turbine fuels containing synthesized hydrocarbons after the fuels have been manufactured, blended and released to CGSB-3.24.Copyright Canadian General Standards B

29、oard Provided by IHS under license with CGSBNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-6 CGSB3.242012F34 F44 Test MethodASTMMin. Max. Min. Max.5.14.3 Distillation temperature differences15, C D28873or D861a. T50 - T10 15 15 b. T90 - T10 40 40 5.14.4 Lubricity,

30、 at point of manufacture, mm 0.85 0.85 D500113The synthetic hydrocarbon content of the blend shall be calculated from metered (measured) volumes used to prepare the blend.14Minimum aromatics content limits are based on current experience with synthetic fuels, and these values were established from w

31、hat is typical for jet fuel produced from conventional hydrocarbons.15The distillation slope limits are based on current experience with synthetic fuels, and these values were established from what is typical for jet fuel produced from conventional hydrocarbons.16Stadis 450, a registered trademark o

32、f Innospec Fuel Specialties LLC, is manufactured in the United States and distributed globally by Innospec Fuel Specialties LLC.5.15 Sulphur The precision and bias of sulphur determinations using ASTM D7039 on diluted samples have not been determined. The accuracy of this method for jet fuel beyond

33、2000 ppm sulphur has not been validated by an interlaboratory study. Users are cautioned to conduct their own validation when using this test method for jet fuel containing more than 2000 ppm sulphur.6. ADDITIVE REQUIREMENTS6.1 Only the additives listed in par. 6.2 to 6.7 may be added to the fuel. R

34、efer to par. 5.13 for the specified limiting values and test method for each property. The supplier shall record the amount and names of each additive.6.1.1 The amount of each additive used in the fuel shall be determined by the test method (par. 5.13 and par. 8.6) or by volume reconciliation. Proce

35、dures for volume reconciliation should include recording the volume of additive introduced to the fuel and the volume of fuel additized in appropriate units.6.2 Static Dissipator Additive (SDA) Static dissipator additive Stadis 450116shall be added to the fuel to meet the electrical conductivity req

36、uirements specified in par. 5.12.1. The original concentration of the SDA shall not exceed 3 mg/L.6.2.1 When additive depletion is evident by a conductivity loss, further addition of the SDA is permitted as follows: If the original concentration of the SDA is not known, then an original addition of

37、3 mg/L is assumed and further addition of SDA shall not exceed 2 mg/L. The cumulative concentration of the SDA shall not exceed 5 mg/L.6.2.2 Electrical conductivity varies with temperature. A typical relationship follows:( )ktttakt1loglog1+=where:kt= electrical conductivity at temperature t, Ckt1= e

38、lectrical conductivity at temperature t1, Ca = a factor that depends on fuel composition but normally is within the range 0.013 to 0.018 for kerosene-type aviation turbine fuelsCopyright Canadian General Standards Board Provided by IHS under license with CGSBNot for ResaleNo reproduction or networki

39、ng permitted without license from IHS-,-,-CGSB3.242012 76.2.2.1 The temperature-conductivity factor, a, increases at or below an approximate temperature of -10C. For conductivity at very low temperatures, it is recommended that a separate factor be determined based on actual measurements at the lowe

40、st temperatures that are assumed will be encountered. For more information on how low temperature affects conductivity, see Appendix X2 of ASTM D2624.6.3 Antioxidants The addition of antioxidants is mandatory for the hydrogen-processed portion of the fuel, but optional for the non-hydrogen-processed

41、 portion of the fuel (par. 5.13.2). 6.3.1 Only the following antioxidants may be added separately or in combination to the fuel.a. 2,6-di-tert-butylphenolb. 2,6-di-tert-butyl-4-methylphenolc. 2-tert-butyl-4,6-dimethylphenol (2,4-dimethyl-6-tertiary butylphenol)d. 75% minimum, 2,6-di-tert-butylphenol

42、25% maximum mixture of tert- and tri-tert-butylphenolse. 55% minimum, 2-tert-butyl-4,6-dimethylphenol (2,4-dimethyl-6-tertiary butylphenol)15% minimum, 2,6-di-tert-butyl-4-methylphenolRemainder as methyl and dimethyl tert-butylphenolsf. 72% minimum 2-tert-butyl-4,6-dimethylphenol (2,4-dimethyl-6-ter

43、tiary butylphenol)28% maximum, methyl and dimethyl tert-butylphenols.Note: The names of the antioxidants conform to the International Union of Pure and Applied Chemistry (IUPAC) naming convention. In some cases, the common name of the antioxidant has been included in brackets after the IUPAC name.6.

44、4 Metal Deactivator Only N,N-disalicylidene-1,2-propane-diamine may be added as a metal deactivator at a concentration not exceeding 2.0 mg/L (not including mass of solvent) on the initial fuel manufactured at the refinery. Higher concentrations are permitted in circumstances where copper contaminat

45、ion is suspected to occur during distribution. Cumulative concentration of metal deactivator when re-treating the fuel shall not exceed 5.7 mg/L (par. 8.3).6.5 Fuel System Icing Inhibitor A fuel system icing inhibitor conforming to ASTM D4171 (Type III DIEGME) shall be added to the fuel within the l

46、imits specified in par. 5.13.4.6.6 Corrosion Inhibitors/Lubricity Improvers A corrosion inhibitor/lubricity improver qualified to U.S. Military Specification MlL-PRF-25017 and listed in the associated Qualified Product List (QPL) 25017 shall be added to the fuel (par. 8.2). The concentration of the

47、additive in the fuel shall be as specified in the QPL, and its introduction into the fuel shall be separate from the addition of other additives.6.7 Leak Detection Additive117 Only Tracer A (LDTA-A)218may be added as a leak detection additive. The maximum concentration is 1 mg/kg.7. INSPECTION7.1 Sa

48、mpling A sample of the size specified by the testing authority shall be obtained in accordance with ASTM D4057. For automatic sampling ASTM D4177 shall be used.17The Tracer Tight methodology to detect and locate leaks in ground-based fuel storage, delivery and dispensing systems does not form part o

49、f this standard. Refer to the additive supplier for this information. Praxair Services, Inc. can be contacted at 3755 N. Business Center Drive, Tucson, AZ 85705, U.S.A., telephone 1-800-989-9929, Web site .18Tracer A (LDTA-A) is a registered trademark of Praxair Services, Inc.Copyright Canadian Gene