BS EN 13346-2000 Characterization of sludges - Determination of trace elements and phosphorous - Aqua regia extraction methods《污泥特性描述 痕量元素和磷的测定 王水萃取法》.pdf

《BS EN 13346-2000 Characterization of sludges - Determination of trace elements and phosphorous - Aqua regia extraction methods《污泥特性描述 痕量元素和磷的测定 王水萃取法》.pdf》由会员分享，可在线阅读，更多相关《BS EN 13346-2000 Characterization of sludges - Determination of trace elements and phosphorous - Aqua regia extraction methods《污泥特性描述 痕量元素和磷的测定 王水萃取法》.pdf（34页珍藏版）》请在麦多课文档分享上搜索。

1、| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS EN 13346:2000 The Euro

2、pean Standard EN 13346:2000 has the status of a British Standard ICS 13.030.20 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Characterization of sludges Determination of trace elements and phosphorus Aqua regia extraction methodsThis British Standard, having been prepared un

3、der the direction of the Health and Environment Sector Committee, was published under the authority of the Standards Committee and comes into effect on 15 October 2000 BSI 10-2000 ISBN 0 580 36291 4 BS EN 13346:2000 Amendments issued since publication Amd. No. Date Comments National foreword This Br

4、itish Standard is the official English language version of EN 13346:2000. The UK participation in its preparation was entrusted to Technical Committee EH/5, Sludge characterization, which has the responsibility to: aid enquirers to understand the text; present to the responsible European committee a

5、ny enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. A list of organizations represented on this committee can be obtained on request to its secretary. Further informati

6、on Users of this standard are informed that the UK submitted some substantial comments at the final voting stage of the draft EN for the following reasons. 1) The scope fails to address the question of whether this method is appropriate for all of the types of sludges in the scope of CEN/TC 308. For

7、 example, is it applicable to sludges containing large amounts of lime? Hence, modify the scope to answer the question of applicability to the scope of the TC. 2) The following note should be added to the scope: “The validation for this standard has only been carried out using materials as described

8、 in annex A. For other sludges, the user should validate the method using recovery and reproducibility tests”. 3) The final phrase, “and sludge products,” in the first sentence of the scope should be removed as it is inappropriate. 4) This is not a single standard since there are 4 alternative metho

9、ds of extraction and 3 alternative methods of pretreatment. The test report in clause 12 should therefore specify which of the 12 permutations has been used. Therefore, either rewrite c) as “describe which method of pretreatment and which method of digestion was used” or modify the document so that

10、there is only one standard method against which others may be benchmarked. 5) In annex D, the data presented for Method D with reference materials appear to condemn this method as unfit since it is almost invariably outside the 95% confidence of the reference sample. Therefore, suggest deleting Meth

11、od D. 6) It is recommended that an additional brief section on the use of adequate AQC as per CEN/TC 223 methods be added: “The analysis described in this standard should be carried out within a quality control system utilizing analytical quality control measures. Where performance data are absent f

12、or the sample type, recovery and reproducibility data should be obtained as a minimum”.BS EN 13346:2000 BSI 10-2000 i Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the secti

13、on entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application.

14、Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, the EN title page, pages 2 to 29 and a back cover. The BSI copyright notice displayed in this document indicate

15、s when the document was last issued.ii blank(8523($167$1$5 1250(8523e(11( (8523b,6&+(1250 (1 $XJXVW ,&6 (QJOLVKYHUVLRQ &KDUDFWHULDWLRQRIVOXGJHVHWHUPLQDWLRQRIWUDFHHOHPHQWV DQGSKRVSKRUXV$TXDUHJLDHWUDFWLRQPHWKRGV &DUDFWpULVDWLRQGHVERXHVpWHUPLQDWLRQGHVpOpPHQWV WUDFHVHWGXSKRVSKRUH0pWKRGHVGHWUDFWLRQjOHDX

16、UpJDOH &KDUDNWHULVLHUXQJYRQ6FKOlPPHQ%HVWLPPXQJYRQ 6SXUHQHOHPHQWHQXQG3KRVSKRU(WUDNWLRQVYHUIDKUHQPLW .|QLJVZDVVHU 7KLV(XURSHDQ6WDQGDUGZDVDSSURYHGE&(1RQ$XJXVW &(1PHPEHUVDUHERXQGWRFRPSOZLWKWKH&(1&(1(/(&,QWHUQDO5HJXODWLRQVZKLFKVWLSXODWHWKHFRQGLWLRQVIRUJLYLQJWKLV(XURSH DQ 6WDQGDUGWKHVWDWXVRIDQDWLRQDOVWDQG

17、DUGZLWKRXWDQDOWHUDWLRQ8SWRGDWHOLVWVDQGELEOLRJUDSKLFDOUHIHUHQFHVFRQFHUQLQJV XFKQDWLRQDO VWDQGDUGVPDEHREWDLQHGRQDSSOLFDWLRQWRWKH&HQWUDO6HFUHWDULDWRUWRDQ&(1PHPEHU 7KLV(XURSHDQ6WDQGDUGHLVWVLQWKUHHRIILFLDOYHUVLRQV(QJOLVK)UHQFK*HUPDQ$YHUVLRQLQDQRWKHUODQJXDJHPDGHEWUD QVODWLRQ XQGHUWKHUHVSRQVLELOLWRID&(1PHP

18、EHULQWRLWVRZQODQJXDJHDQGQRWLILHGWRWKH&HQWUDO6HFUHWDULDWKDVWKHVDPHVWDWXVDVW KHRIILFLDO YHUVLRQV &(1PHPEHUVDUHWKHQDWLRQDOVWDQGDUGVERGLHVRI$XVWULD%HOJLXP&HFK5HSXEOLFHQPDUN)LQODQG)UDQFH*HUPDQ*UHHFH ,FHODQG,UHODQG,WDO/XHPERXUJ1HWKHUODQGV1RUZD3RUWXJDO6SDLQ6ZHGHQ6ZLWHUODQGDQG8QLWHG.LQJGRP (8523($1 &200,77(

19、 )25 67$1$5,=$7,21 &20,7e(8523e(1(1250$/,6$7,21 (8523b,6&+(6.20,7()h5125081* &HQWUDO6HFUHWDULDWUXHGH6WDVVDUW%UXVVHOV &(1 $OOULJKWVRIHSORLWDWLRQLQDQIRUPDQGEDQPHDQVUHVHUYHG ZRUOGZLGHIRU&(1QDWLRQDO0HPEHUV 5HI1R(1(3DJH (1 %6, &RQWHQWV 3DJH )RUHZRUG ,QWURGXFWLRQ 6FRSH 1RUPDWLYHUHIHUHQFHV 7HUPVDQGGHILQLWL

20、RQV 3ULQFLSOH 5HDJHQWV $SSDUDWXV 3UHSDUDWLRQRIWKHODERUDWRUVDPSOH 3URFHGXUH %ODQNWHVW 0HDVXUHPHQWV (SUHVVLRQRIUHVXOWV 7HVWUHSRUW 3UHFLVLRQGDWD $QQH$LQIRUPDWLYH 3UHWUHDWPHQWRIWKHVDPSOH $QQH%LQIRUPDWLYH &DOLEUDWLRQRIWKHPLFURZDYHRYHQ $QQH&LQIRUPDWLYH *XLGHOLQHVIRUPHDVXUHPHQWWHFKQLTXHV $QQHLQIRUPDWLYH 3U

21、HFLVLRQGDWDIRUPHWKRGV&DQGZLWKUHIHUHQFHPDWHULDOV %LEOLRJUDSK 3DJH (1 %6, )RUHZRUG 7KLV(XURSHDQ6WDQGDUGKDVEHHQSUHSDUHGE7HFKQLFDO&RPPLWWHH&(17&KDUDFWHULDWLRQRI VOXGJHVWKH6HFUHWDULDWRIZKLFKLVKHOGE$)125 7KLV(XURSHDQ6WDQGDUGVKDOOEHJLYHQWKHVWDWXVRIDQDWLRQDOVWDQGDUGHLWKHUESXEOLFDWLRQRIDQLGHQWLFDO WHWRUEHQGR

22、UVHPHQWDWWKHODWHVWE)HEUXDUDQGFRQIOLFWLQJQDWLRQDOVWDQGDUGVVKDOOEHZLWKGUDZQ DWWKHODWHVWE)HEUXDU $FFRUGLQJWRWKH&(1&(1(/(&,QWHUQDO5HJXODWLRQVWKHQDWLRQDOVWDQGDUGVRUJDQLDWLRQVRIWKHIROORZLQJ FRXQWULHVDUHERXQGWRLPSOHPHQWWKLV(XURSHDQ6WDQGDUG$XVWULD%HOJLXP&HFK5HSXEOLFHQPDUN )LQODQG)UDQFH*HUPDQ*UHHFH,FHODQG,UH

23、ODQG,WDO/XHPERXUJ1HWKHUODQGV1RUZD3RUWXJDO 6SDLQ6ZHGHQ6ZLWHUODQGDQGWKH8QLWHG.LQJGRP 7KHDQQHHV$WRDUHLQIRUPDWLYH3DJH (1 %6, ,QWURGXFWLRQ (OHPHQWVHWUDFWDEOHLQDTXDUHJLDFDQQRWEHGHVFULEHGDVWRWDOFRQYHUVHOWKHFDQQRWEHUHJDUGHGDV WKHELRDYDLODEOHIUDFWLRQDVWKHHWUDFWLRQSURFHGXUHLVWRRYLJRURXVWRUHSUHVHQWDOOELRORJLFD

24、OSURFHVVHV 2QHHWUDFWLRQPHWKRGLVSURSRVHGXVLQJDTXDUHJLD)RXUKHDWLQJSURFHVVHVDUHGHVFULEHGWKHXVHWKH VDPHUHDJHQWVWKHUHIRUHWKHVDPHSULQFLSOHRIFKHPLFDOUHDFWLRQ 0HWKRG$LVDYLJRURXVGLJHVWLRQSURFHGXUHDOORZLQJODUJHUWHVWSRUWLRQV 0HWKRG%LVDIDVWSURFHGXUHFDUULHGRXWLQDVLQJOHYHVVHOVPDOOHUWHVWSRUWLRQVDUHXVHG 0HWKRGV&DQG

25、DUHPLFURZDYHKHDWLQJSURFHGXUHVXVLQJFORVHGDQGRSHQVVWHPVUHVSHFWLYHO3DJH (1 %6, 6FRSH 7KLVVWDQGDUGVSHFLILHVPHWKRGVIRUWKHHWUDFWLRQZLWKDTXDUHJLDRIWUDFHHOHPHQWVDQGSKRVSKRUXVIURP VOXGJHVDQGVOXGJHSURGXFWV7KHUHVXOWLQJVROXWLRQLVVXLWDEOHIRUWKHGHWHUPLQDWLRQRI$V&G&U&X+J 1L3E6H=QDQG3XVLQJVSHFWURPHWULFWHFKQLTXHV 12

26、7( :LWKKLJKVROXWHFRQFHQWUDWLRQVLQHWUDFWVROXWLRQVVSHFWUDOLQWHUIHUHQFHVDQGEDFNJURXQGHQKDQFHPHQW VKRXOGEHHSHFWHG 127( 7KLVPHWKRGFDQEHXVHGIRURWKHUHOHPHQWVHFHSWWKDWSRUWLRQRIWKHHOHPHQWVERQGHGWRVLOLFD 1RUPDWLYHUHIHUHQFHV 7KLV(XURSHDQ6WDQGDUGLQFRUSRUDWHVEGDWHGRUXQGDWHGUHIHUHQFHSURYLVLRQVIURPRWKHUSXEOLFDWLRQ

27、V 7KHVHQRUPDWLYHUHIHUHQFHVDUHFLWHGDWWKHDSSURSULDWHSODFHVLQWKHWHWDQGWKHSXEOLFDWLRQVDUHOLVWHG KHUHDIWHU)RUGDWHGUHIHUHQFHVVXEVHTXHQWDPHQGPHQWVWRRUUHYLVLRQVRIDQRIWKHVHSXEOLFDWLRQVDSSO WRWKLV(XURSHDQ6WDQGDUGRQOZKHQLQFRUSRUDWHGLQLWEDPHQGPHQWRUUHYLVLRQ)RUXQGDWHGUHIHUHQFHV WKHODWHVWHGLWLRQRIWKHSXEOLFDWLRQUH

28、IHUUHGWRDSSOLHV (1 :DWHUTXDOLWHWHUPLQDWLRQRIFKURPLXP$WRPLFDEVRUSWLRQVSHFWURPHWULFPHWKRGV (1 :DWHUTXDOLWHWHUPLQDWLRQRIPHUFXU (1 &KDUDFWHULDWLRQRIVOXGJHVHWHUPLQDWLRQRIGUUHVLGXHDQGZDWHUFRQWHQW (1,62 :DWHUIRUDQDOWLFDOODERUDWRUXVH6SHFLILFDWLRQDQGWHVWPHWKRGV ,62 (1 ,62 :DWHU TXDOLW HWHUPLQDWLRQ RI FDGPLXP

29、 E DWRPLF DEVRUSWLRQ VSHFWURPHWU ,62 (1,62 :DWHUTXDOLWHWHUPLQDWLRQRIHOHPHQWVELQGXFWLYHOFRXSOHGSODVPDDWRPLFHPLVVLRQ VSHFWURVFRS,62 (1,62 :DWHUTXDOLWHWHUPLQDWLRQRIDUVHQLF$WRPLFDEVRUSWLRQVSHFWURPHWULFPHWKRGKGULGH WHFKQLTXH ,62 ,62 $FFXUDFWUXHQHVVDQGSUHFLVLRQRIPHDVXUHPHQWPHWKRGVDQGUHVXOWV3DUW%DVLFPHWKRG

30、 IRUWKHGHWHUPLQDWLRQRIUHSHDWDELOLWDQGUHSURGXFLELOLWRIDVWDQGDUGPHDVXUHPHQWPHWKRG ,62 :DWHUTXDOLWHWHUPLQDWLRQRIFREDOWQLFNHOFRSSHULQFFDGPLXPDQGOHDG)ODPHDWRPLF DEVRUSWLRQVSHFWURPHWULFPHWKRGV 7HUPVDQGGHILQLWLRQV )RUWKHSXUSRVHVRIWKLV(XURSHDQ6WDQGDUGWKHIROORZLQJWHUPVDQGGHILQLWLRQVDSSO DTXDUHJLD GLJHVWLRQVR

31、OXWLRQREWDLQHGEPLLQJRQHYROXPHRIQLWULFDFLGDQGWKUHHYROXPHVRIKGURFKORULFDFLG GUPDVVGUPDWWHU WKHPDVVRIVROLGVREWDLQHGDIWHUWKHVSHFLILHGGULQJSURFHVV,WLVHSUHVVHGDVJUDPVRUNLORJUDPV (1 3DJH (1 %6, 3ULQFLSOH 7KHODERUDWRUVDPSOHLVSUHSDUHGLQRUGHUWRREWDLQDUHSUHVHQWDWLYHWHVWSRUWLRQZKLFKLVHWUDFWHGZLWK DTXDUHJLDDFFRU

32、GLQJWRRQHRIWKHIROORZLQJKHDWLQJSURFHGXUHV ERLOLQJIRUDERXWKZLWKDUHIOXFRQGHQVHUIROORZHGEILOWUDWLRQDQGPDNLQJXSWRYROXPHLQD YROXPHWULFIODVNPHWKRG$ ERLOLQJIRUDERXWPLQLQDFDOLEUDWHGJODVVWXEHPDNLQJXSWRYROXPHLQWKHVDPHWXEHDOORZLQJWR VHWWOHDQGWKHQGHFDQWLQJWKHVXSHUQDWDQWVROXWLRQIRUDQDOVLVPHWKRG% PLFURZDYHGLJHVWLR

33、QIRUDERXWPLQLQDFORVHGYHVVHOIROORZHGEILOWUDWLRQDQGPDNLQJXSWRYROXPH LQDYROXPHWULFIODVNPHWKRG& PLFURZDYHGLJHVWLRQIRUDERXWPLQLQDQRSHQYHVVHOIROORZHGEILOWUDWLRQDQGPDNLQJXSWRYROXPH LQDYROXPHWULFIODVNPHWKRG 127( 2WKHUKHDWLQJSURFHGXUHVFDQEHXVHGSURYLGLQJWKHGHPRQVWUDWHHTXLYDOHQWSHUIRUPDQFH 5HDJHQWV *HQHUDO 7KH

34、UHDJHQWVXVHGVKDOOEHRIVXIILFLHQWSXULWVRDVQRWWRLQWURGXFHDVLJQLILFDQWHUURULQWRWKHVXEVHTXHQW DQDOVLV$UHDJHQWEODQNFRPSULVLQJWKHVDPHTXDQWLWRIDFLGVVKDOOEHWDNHQWKURXJKWKHHQWLUHSURFHGXUH ZLWKHDFKEDWFKRIDQDOVLV :DWHU HLRQLHGRUGLVWLOOHGZDWHUXVHGVKDOOFRQIRUPWRSXULWJUDGHRI(1,62 +GURFKORULFDFLG VROXWLRQ F+&O PROO

35、 $ERXW PP r JPO 1LWULFDFLGVROXWLRQ F+12 PROO $ERXW PP r JPO 1LWULFDFLGVROXWLRQ DERXW 99IRUFOHDQLQJ 7DNHPORIQLWULFDFLGDQGGLOXWHWROLQDIODVNZLWKZDWHU7KLVGLOXWHQLWULFDFLGVKDOOEHXVHGWR FOHDQWKHJODVVZDUH QRGHFDQH RURWKHUVXLWDEOHDQWLIRDPLQJDJHQWVIRUDGGLWLRQLQPHWKRG% $SSDUDWXV *HQHUDO $OOJODVVZDUHDQGSODVWLFVZDUHVKDOOEHDGHTXDWHOFOHDQHGDQGVWRUHGLQRUGHUWRDYRLGDQFRQWDPLQDWLRQ 127( ,WFDQEHQHFHVVDUWRSHULRGLFDOOFOHDQWKHUHDFWLRQYHVVHOZLWKDVXLWDEOHVXUIDFWDQWWRUHPRYHVWXEERUQ GHSRVLWV3DJH (1 %6, 5HDFWLRQYHVVHOV