BS EN 13176-2015 Chemicals used for treatment of water intended for human consumption Ethanol《人生活用水的水处理用化学物质 乙醇》.pdf

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1、BSI Standards PublicationBS EN 13176:2015Chemicals used for treatmentof water intended for humanconsumption EthanolBS EN 13176:2015 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 13176:2015. Itsupersedes BS EN 13176:2008 which is withdrawn.The UK participation

2、in its preparation was entrusted to TechnicalCommittee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are res

3、ponsible for its correctapplication. The British Standards Institution 2015. Published by BSI StandardsLimited 2015ISBN 978 0 580 86483 4ICS 13.060.20; 71.100.80Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of

4、theStandards Policy and Strategy Committee on 31 March 2015.Amendments issued since publicationDate Text affectedBS EN 13176:2015EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 13176 March 2015 ICS 71.100.80 Supersedes EN 13176:2008English Version Chemicals used for treatment of water intended

5、for human consumption - Ethanol Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - thanol Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Ethanol This European Standard was approved by CEN on 20 December 2014. CEN members are bound to comply w

6、ith the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Man

7、agement Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same s

8、tatus as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Ma

9、lta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 C

10、EN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 13176:2015 EBS EN 13176:2015EN 13176:2015 (E) 2 Contents Page Foreword 5 Introduction .6 1 Scope 7 2 Normative references 7 3 Description .7 3.1 Identification .7 3.1.1 Chemical name .

11、7 3.1.2 Synonym or common name 7 3.1.3 Relative molecular mass .7 3.1.4 Empirical formula.8 3.1.5 Chemical formula .8 3.1.6 CAS Registry Number ).8 3.1.7 EINECS reference )8 3.2 Commercial form .8 3.3 Physical properties 8 3.3.1 Appearance 8 3.3.2 Density 8 3.3.3 Solubility in water 9 3.3.4 Vapour p

12、ressure (at 20 C) 9 3.3.5 Boiling point at 100 kPa )9 3.3.6 Melting point .9 3.3.7 Specific heat .9 3.3.8 Viscosity, dynamic.9 3.3.9 Critical temperature (for gas) .9 3.3.10 Critical pressure (for gas) .9 3.3.11 Physical hardness .9 3.4 Chemical properties 9 4 Purity criteria 9 4.1 General 9 4.2 Com

13、position of commercial product 10 4.3 Impurities and main by-products 10 4.4 Chemical parameters . 10 5 Test methods . 10 5.1 Sampling 10 5.1.1 Relevant standards . 10 5.1.2 Sampling from drums and bottles 10 5.1.3 Sampling from tanks and tankers . 11 5.2 Analysis . 11 5.2.1 Ethanol (main product) 1

14、1 5.2.2 Impurities . 12 5.2.3 Chemical parameters . 14 6 Labelling - Transportation - Storage . 17 6.1 Means of delivery 17 6.2 Labelling according to the EU legislation )17 6.3 Transportation regulations and labelling . 17 6.4 Marking 18 6.5 Storage . 18 BS EN 13176:2015EN 13176:2015 (E) 3 6.5.1 Ge

15、neral . 18 6.5.2 Long term stability 18 6.5.3 Storage incompatibilities 18 Annex A (informative) General information on synthetic ethanol 19 A.1 Origin 19 A.2 Use 19 Annex B (normative) General rules relating to safety . 20 B.1 Rules for safe handling and use 20 B.2 Emergency procedures . 20 Bibliog

16、raphy 21 Foreword . 5 Introduction . 6 1 Scope 7 2 Normative references 7 3 Description . 7 3.1 Identification 7 3.1.1 Chemical name 7 3.1.2 Synonym or common name . 7 3.1.3 Relative molecular mass. 7 3.1.4 Empirical formula 8 3.1.5 Chemical formula 8 3.1.6 CAS Registry Number ). 8 3.1.7 EINECS refe

17、rence )8 3.2 Commercial form . 8 3.3 Physical properties . 8 3.3.1 Appearance 8 3.3.2 Density 8 3.3.3 Solubility in water 9 3.3.4 Vapour pressure (at 20 C) . 9 3.3.5 Boiling point at 100 kPa )9 3.3.6 Melting point 9 3.3.7 Specific heat 9 3.3.8 Viscosity, dynamic 9 3.3.9 Critical temperature (for gas

18、) . 9 3.3.10 Critical pressure (for gas) . 9 3.3.11 Physical hardness . 9 3.4 Chemical properties 9 4 Purity criteria . 9 4.1 General . 9 4.2 Composition of commercial product . 10 4.3 Impurities and main by-products . 10 4.4 Chemical parameters 10 5 Test methods . 10 5.1 Sampling. 10 5.1.1 Relevant

19、 standards . 10 5.1.2 Sampling from drums and bottles . 10 5.1.3 Sampling from tanks and tankers 11 5.2 Analysis 11 5.2.1 Ethanol (main product) . 11 BS EN 13176:2015EN 13176:2015 (E) 4 5.2.2 Impurities . 12 5.2.3 Chemical parameters . 14 6 Labelling - Transportation - Storage . 17 6.1 Means of deli

20、very 17 6.2 Labelling according to the EU legislation )17 6.3 Transportation regulations and labelling . 17 6.4 Marking 18 6.5 Storage . 18 6.5.1 General . 18 6.5.2 Long term stability 18 6.5.3 Storage incompatibilities . 18 Annex A (informative) General information on synthetic ethanol . 19 A.1 Ori

21、gin . 19 A.1.1 Raw materials 19 A.1.2 Manufacturing process 19 A.2 Use . 19 A.2.1 Function . 19 A.2.2 Form in which it is used . 19 A.2.3 Treatment dose . 19 A.2.4 Means of application 19 A.2.5 Secondary effects . 19 A.2.6 Removal of excess product . 19 Annex B (normative) General rules relating to

22、safety . 20 B.1 Rules for safe handling and use . 20 B.2 Emergency procedures 20 B.2.1 First aid 20 B.2.2 Spillage 20 B.2.3 Fire . 20 Bibliography . 21 BS EN 13176:2015EN 13176:2015 (E) 5 Foreword This document (EN 13176:2015) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the s

23、ecretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2015, and conflicting national standards shall be withdrawn at the latest by September 2015. This do

24、cument supersedes EN 13176:2008. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. Significant technical difference between this edition

25、 and EN 13176:2008 is as follows: a) deletion of reference to EU Directive 67/548/EEC of June 27, 1967 in order to take into account the latest Regulation in force (see 2); b) 6.2 updating of risk and safety labelling according to EU Regulation 2 and its latest Adaptations to Technical Progress). Ac

26、cording to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germa

27、ny, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 13176:2015EN 13176:2015 (E) 6 Introduction In respect of potential adverse effects

28、on the quality of water intended for human consumption, caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, whil

29、e awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States

30、 of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. BS EN 13176:2015EN 13176:2015 (E) 7 1 Scope This European Standard is applicable to synthetic ethanol used for treatment of water intended for human consumption.

31、It describes the characteristics of synthetic ethanol and specifies the requirements and the corresponding test methods for synthetic ethanol. It gives information on its use in water treatment. NOTE This European Standard does not apply to anhydrous ethanol which is not used for drinking water trea

32、tment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including an

33、y amendments) applies. EN 1233, Water quality - Determination of chromium - Atomic absorption spectrometric methods EN ISO 12846, Water quality - Determination of mercury - Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) EN 26595, Water quality Determination

34、 of total arsenic Silver diethyldithiocarbamate spectrophotometric method (ISO 6595) EN ISO 3696, Water for analytical laboratory use - Specification and test methods (ISO 3696) ISO 3165, Sampling of chemical products for industrial use Safety in sampling ISO 3856-2, Paints and varnishes Determinati

35、on of “soluble“ metal content Part 2: Determination of antimony content Flame atomic absorption spectrometric method and Rhodamine B spectrophotometric method ISO 6206, Chemical products for industrial use Sampling Vocabulary ISO 8288:1986, Water quality Determination of cobalt, nickel, copper, zinc

36、, cadmium and lead Flame atomic absorption spectrometric methods ISO 9965, Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique) 3 Description 3.1 Identification 3.1.1 Chemical name Ethanol. 3.1.2 Synonym or common name Ethyl alcohol. 3.1.3 Relative molec

37、ular mass 46,07 BS EN 13176:2015EN 13176:2015 (E) 8 3.1.4 Empirical formula C2H60 3.1.5 Chemical formula C2H5OH 3.1.6 CAS Registry Number 1)64-17-5 3.1.7 EINECS reference 2)200-57-86 3.2 Commercial form The product is available as colourless liquid. 3.3 Physical properties 3.3.1 Appearance The produ

38、ct is colourless liquid at 20 C. 3.3.2 Density The density at 20 C is given in Table 1 (see 3 and 4). Table 1 Density Concentration Mass fraction % Density g/ml 95 0,8114 95,1 0,8110 95,2 0,8106 95,3 0,8104 95,4 0,8100 95,5 0,8096 95,6 0,8092 95,7 0,8088 95,8 0,8084 95,9 0,8080 96 0,8076 1)Chemical

39、Abstracts Service Registry Number. 2)European Inventory of Existing Commercial Chemical Substances. BS EN 13176:2015EN 13176:2015 (E) 9 3.3.3 Solubility in water Miscible. 3.3.4 Vapour pressure (at 20 C) 5,81 kPa (for pure ethanol) 3.3.5 Boiling point at 100 kPa 3)78,2 C (for pure ethanol) 3.3.6 Mel

40、ting point - 112,3 C (for pure ethanol) 3.3.7 Specific heat 2,399 kJ/(kg K) at 20 C (for pure ethanol) 3.3.8 Viscosity, dynamic 1,2 mPa.s at 20 C (for pure ethanol) 3.3.9 Critical temperature (for gas) 240,77 C 3.3.10 Critical pressure (for gas) 6 400 kPa 3.3.11 Physical hardness Not applicable. 3.4

41、 Chemical properties Ethanol is a polar and protic organic solvent. 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for Ethanol used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the produ

42、ct. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. Users of this product should check the national regulations in order to clarify whether it is of appropriate puri

43、ty for treatment of water intended for human consumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the product not stated in the product standard. 3)100 kPa = 1 bar BS EN 13176:2015EN 13176:2015 (E) 10 Limits have been given for impur

44、ities and chemicals parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead(s) to significant quantities of impurities, by-products or additives being present, this shall be notif

45、ied to the user. 4.2 Composition of commercial product The product shall contain a mass fraction of at least 95 % synthetic ethanol. The commercial product may contain up to a mass fraction of 5 % water. 4.3 Impurities and main by-products The acetaldehyde content shall not exceed 100 mg/kg of pure

46、ethanol. 4.4 Chemical parameters NOTE For the purpose of this European Standard, “chemical parameters” are those defined in the EU Directive 98/83/EC of 3 November 1998 (see 1). The content of chemical parameters shall conform to the requirements specified in Table 2. Table 2 Chemical parameters Par

47、ameter Limit in mg/kg of pure ethanol Arsenic (As) max. 1 Cadmium (Cd) max. 2 Chromium (Cr) max. 5 Mercury (Hg) max. 2 Nickel (Ni) max. 1 Lead (Pb) max. 2 Antimony (Sb) max. 1 Selenium (Se) max. 1 NOTE Cyanide does not exist in ethanol solvent medium. Pesticides and polycyclic aromatic hydrocarbons

48、are not by-products of the manufacturing process. 5 Test methods 5.1 Sampling 5.1.1 Relevant standards Observe the general recommendations of ISO 3165 and take account of ISO 6206. 5.1.2 Sampling from drums and bottles 5.1.2.1 General 5.1.2.1.1 Mix the contents of the container to be sampled by shak

49、ing the container, by rolling it or by rocking it from side to side, taking care not to damage the container or spill any of the liquid. BS EN 13176:2015EN 13176:2015 (E) 11 5.1.2.1.2 If the design of the container is such (for example, a narrow-necked bottle) that it is impracticable to use a sampling implement, take a sample by pouring after the contents have been thoroughly mixed. Otherwise, proceed as described in 5.1.2.1.3. 5.1.2.1.3 Examine the surface of the liquid. If there are signs of surface contamination, take s