BS 7755-3 12-1996 Soil quality Chemical methods Determination of the potential cation exchange capacity and exchangeable cations using barium chloride solution buffered at pH = 8 1.pdf
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1、BRITISH STANDARD BS 7755-3.12: 1996 ISO 13536: 1995 Soil quality Part 3: Chemical methods Section 3.12. Determination of the potential cation exchange capacity and exchangeable cations using barium chloride solution buffered at pH = 8.1 ICS 13.080BS 7755-3.12:1996 This British Standard, having been
2、prepared under the directionof the Health and Environment Sector Board, was published under the authority of the Standards Board and comes into effect on 15 February 1996 BSI 07-1999 The following BSI references relate to the work on this standard: Committee reference EH/4/3 Draft for comment 94/501
3、662 DC ISBN 0 580 25334 1 Committees responsible for this British Standard The preparation of this British Standard was entrusted by Technical Committee EH/4, Soil quality, to Subcommittee EH/4/3, Chemical methods, upon which the following bodies were represented: Association of Consulting Scientist
4、s Association of Public Analysts British Ceramic Research Ltd. British Gas plc British Society of Soil Science Department of the Environment (Drinking Water Inspectorate) Department of Trade and Industry (Laboratory of the Government Chemist) National Rivers Authority Royal Society of Chemistry Soci
5、ety of Chemical Industry Soil Survey and Land Research Centre Water Research Centre Water Services Association of England and Wales Amendments issued since publication Amd. No. Date CommentsBS 7755-3.12:1996 BSI 07-1999 i Contents Page Committees responsible Inside front cover National foreword ii 1
6、 Scope 1 2 Normative references 1 3 Principle 1 4 Procedures 1 5 Test report 5 Annex A (informative) Bibliography 6 List of references Inside back coverBS 7755-3.12:1996 ii BSI 07-1999 National foreword This Section of BS7755 has been prepared by Subcommittee EH/4/3 and is identical with ISO13536:19
7、95 Soil quality Determination of the potential cation exchange capacity and exchangeable cations using barium chloride solution buffered atpH=8,1, published by the International Organization for Standardization (ISO). ISO 13536 was prepared by Subcommittee3, Chemical methods, of Technical Committee
8、ISO/TC190, Soil quality, with the active participation and approval of the UK. BS 7755 is being published in a series of Parts subdivided into Sections and Subsections that will generally correspond to particular international standards. Other Parts of BS7755 are, or will be, as follows. Part 1: Ter
9、minology and classification; Part 2: Sampling; Part 3: Chemical methods; Part 4: Biological methods; Part 5: Physical methods; Textual error. When adopting the text of the international standard, the following textual error was discovered. It has been marked in the text and has been reported to ISO
10、in a proposal to amend the text of the international standard. In4.2.5, the correct presentation of the second formula is: Additional information Although the use of ICP-AES is mentioned inclause3, no instructions are given in the procedural clauses for this method of analysis. In4.1.2, typical stor
11、age conditions are approximately 4 C for a maximum of24h. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from le
12、gal obligations. Cross-references International standard Corresponding British Standard ISO 3696:1987 BS EN ISO 3696:1995 Water for analytical laboratory use Specification and test methods (Identical) ISO 11464:1994 BS 7755 Soil quality Part: 3 Chemical methods Section 3.5:1995 Pretreatment of sampl
13、es for physico-chemical analyses (Identical) CEC 3 000c 2 c b1 () m - = Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, pages1 to 6, an inside back cover and a back cover. This standard has been updated (see copyright date) and may have had amendments i
14、ncorporated. This will be indicated in the amendment table on the inside front cover.BS 7755-3.12:1996 BSI 07-1999 1 WARNING Barium is a very toxic element if ingested. The barium ion has health risks for laboratory personnel working with this chemical; it is also harmful for the environment. 1 Scop
15、e This International Standard specifies a method for the determination of the potential cation exchange capacity (CEC) of soil buffered at pH=8,1 and of the determination of the content of exchangeable sodium, potassium, calcium and magnesium in soil. This International Standard is applicable to all
16、 types of air-dried soil samples. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this International Standard. At the time of publication, the editions indicated were valid. All standards are subject to revision, and p
17、arties to agreements based on this International Standard are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Members of IEC and ISO maintain registers of currently valid International Standards. ISO 3696:1987, Water for analytical lab
18、oratory use Specification and test methods. ISO 11464:1994, Soil quality Pretreatment of samples for physico-chemical analyses. 3 Principle The determination of CEC as specified in this International Standard is a modification of the method proposed by Mehlich1, 2 and modified by Bascomb3. The CEC o
19、f soil samples is determined in barium chloride solution buffered at pH=8,1 using triethanolamine. The soil is first saturated with respect to barium by treating the soil three times with buffered barium chloride solution. Subsequently, a known excess of0,02mol/l magnesium sulfate solution is added.
20、 All the barium present, in solution as well as adsorbed, is precipitated in the form of highly insoluble barium sulfate and the sites with exchangeable ions are then readily occupied by magnesium. The excess magnesium is determined by either flame atomic absorption spectrometry (FAAS) or inductivel
21、y coupled plasma atomic emission spectrometry (ICP-AES). It is also possible to determine sodium, potassium, calcium and magnesium (and other elements) in the barium chloride extract of the soil. NOTE 1Besides sodium, potassium, calcium and magnesium, it is also possible to determine other cations,
22、for example manganese, in the same extract. NOTE 2A yellowish-brown colour of the barium chloride extract indicates that some organic matter has been dissolved. Since organic matter contributes to the CEC, the measured value will be an underestimate of the potential CEC. NOTE 3The sum of exchangeabl
23、e cations may give a result that is greater than the CEC due to the dissolution of salts present in the soil. Preliminary washing of the soil with water to remove these salts should not be employed because it could change the relative proportions of cations in the CEC. 4 Procedures 4.1 Leaching 4.1.
24、1 Reagents Use only reagents of recognized analytical grade and distilled water or deionized water for all solutions. 4.1.1.1 Water, with a specific conductivity not higher than0,2mS/m at25 C (water conforming to grade2of ISO3696). 4.1.1.2 Barium chloride solution, c(BaCl 2 =1 mol/l. Dissolve 244 g
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