ASTM D5363-2003e1 Standard Specification for Anaerobic Single-Component Adhesives (AN)《厌氧的单一成分胶粘剂(AN)的标准规范》.pdf

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1、Designation: D 5363 03e1Standard Specification forAnaerobic Single-Component Adhesives (AN)1This standard is issued under the fixed designation D 5363; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A nu

2、mber in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.e1NOTEEditorial corrections were made in Table 1 and footnote 1 in

3、Table AN in August 2006.1. Scope1.1 This specification covers single-component anaerobicadhesives suitable for locking, sealing, and retaining threadedor cylindrical assemblies. The adhesives are cured to a solidstate when confined between closely fitting active metalsurfaces.1.2 This specification

4、is intended to be a means of classify-ing anaerobic adhesives. It is not intended for engineeringdesign purposes.1.3 This specification is intended to replace Military Speci-fications MIL-S-22473, MIL-S-46163, and MIL-R-46082.1.4 The values stated in SI units are to be regarded as thestandard.1.5 Th

5、e following safety hazards caveat pertains only to thetest methods portion, Section 7, of this specification. Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to establish appropriate safety and

6、healthpractices and determine the applicability of regulatory limita-tions prior to use.2. Referenced Documents2.1 ASTM Standards:2A 109/A 109M Specification for Steel, Strip, Carbon (0.25Maximum Percent), Cold-RolledB 36/B 36M Specification for Brass Plate, Sheet, Strip,AndRolled BarB 209 Specifica

7、tion for Aluminum and Aluminum-AlloySheet and PlateB 633 Specification for Electrodeposited Coatings of Zincon Iron and SteelD56 Test Method for Flash Point by Tag Closed Cup TesterD 439 Specification for Automotive Gasoline3D 445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids

8、(and Calculation of Dynamic Viscos-ity)D 770 Specification for Isopropyl AlcoholD 907 Terminology of AdhesivesD 1084 Test Methods for Viscosity of AdhesivesD 1193 Specification for Reagent WaterD 2693 Specification for Ethylene GlycolD 3951 Practice for Commercial PackagingD 4562 Test Method for She

9、ar Strength ofAdhesives UsingPin-and-Collar SpecimenD 4800 Guide for Classifying and Specifying AdhesivesD 5648 Test Method for Torque-Tension Relationship ofAdhesives Used on Threaded Fasteners (Lubricity)D 5649 Test Method for Torque Strength ofAdhesives Usedon Threaded FastenersD 5657 Test Method

10、 for Fluid Tightness Ability of Adhe-sives Used on Threaded FastenersE 122 Practice for Calculating Sample Size to Estimate,With a Specified Tolerable Error, the Average for aCharacteristic of a Lot or Process2.2 Military Standards:MIL-STD-105 Sampling Procedures and Tables for Inspec-tion by Attrib

11、utes4MIL-STD-129 Marking for Shipment and Storage4MIL-STD-810 Environmental Test Methods and Engineer-ing Guides4MIL-STD-118 Commercial Packaging of Supplies andEquipment42.3 Federal Standards:FED-STD-313 Material Safety Data Sheets, Preparationand Submission of42.4 Federal Specifications:FF-N-836 N

12、ut: Square, Hexagon, Cap, Slotted, Castle,Knurled, Welding and Single Ball Seat41This specification is under the jurisdiction of ASTM Committee D14 onAdhesives and is the direct responsibility of Subcommittee D14.60 on AdhesiveMaterial Classification System.Current edition approved Dec. 1, 2003. Pub

13、lished January 2004. Originallyapproved in 1993. Last previous edition approved in 1997 as D 5363 97.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards D

14、ocument Summary page onthe ASTM website.3Withdrawn.4Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http:/www.dodssp.daps.mil.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-

15、2959, United States.PPP-B-636 Box, Shipping, Fiberboard4QQ-P-416 Plating, Cadmium, Electrodeposited42.5 Military Specifications:MIL-R-46082 Retaining Compounds, Single-Component,Anaerobic4MIL-S-22473 Sealing, Locking, Retaining Compounds;Single-Component4MIL-S-46163 Sealing, Lubricating, and Wicking

16、 Com-pounds: Thread-Locking, Anaerobic, Single-Component4MIL-T-5624 Turbine Fuel,Aviation, Grades JP-4 and JP-542.6 U.S. Department of Transportation (DOT):Code of Federal Regulations, Parts 100 to 199 , Departmentof Transportation Rules and Regulations for the Transpor-tation of Explosives and Othe

17、r Dangerous Articles52.7 Society of Automotive Engineers:SAE J311 Fluid for Passenger Care Type Automatic Trans-missions, Information Report6SAE J429 Mechanical and Material Requirements for Ex-ternally Threaded Fasteners6SAE AMS 2629 Jet Reference Fuel63. Terminology3.1 DefinitionsSome terms in thi

18、s specification are de-fined in Terminology D 907.3.1.1 active metal surface, nrelative to anaerobic adhe-sives, a metal surface that initiates the formation of freeradicals within anaerobic adhesives.3.1.2 anaerobic adhesive, nan adhesive that is kept in theuncured state by oxygen, as in air, and t

19、hat cures in the absenceof oxygen when exposed to metal ions, especially copper oriron.3.1.3 Newtonian behavior, nthe property of a liquid inwhich its viscosity is constant over a stated range of strainrates. (Compare non-Newtonian behavior.)3.1.4 non-Newtonian behavior, nthe property of a liquidin

20、which its viscosity is not constant over a stated range ofstrain rates. (Compare Newtonian behavior.)3.1.5 thixotropy, nin a liquid, the property of thinningwhen subjected to strains greater than the yield strain and ofrethickening with time upon subsequent rest.3.1.5.1 DiscussionThe liquid must exh

21、ibit yield to bethixotropic. If the liquid is deformed more than the yield strain,the underlying elastic network is disrupted and its viscosity isreduced. The network reestablishes itself in time when at rest.3.2 Definitions of Terms Specific to This Standard:3.2.1 breakaway torquethe initial torque

22、 required to breakthe bond, measured at the first movement between the nut andthe bolt, when unscrewing an unseated assembly.3.2.2 prevailing torque, nthe torque measured at 180rotation of the nut.3.2.2.1 DiscussionPrevailing torque was originally de-fined in MIL-S-46163 and MIL-S-22473 as the avera

23、ge of thefour torques measured at 90, 180, 270, and 360 rotation of thenut. Studies have shown that the torque measured at 180rotation of the nut is statistically equivalent to the average ofthe torque measured at the four14 turns. Since measuring thetorque at the one angle of rotation is more effic

24、ient, prevailingtorque is most often defined as the torque measured at 180rotation of the nut. However, for purposes of this specification,the definition of prevailing torque as the average of the fourtorques measured at 90, 180, 270, and 360 rotation of the nutis also acceptable.4. Classification4.

25、1 Anaerobic adhesives are classified into groups in accor-dance with their performance properties. These groups aresubdivided into classes and grades, as shown in Table AN.NOTE 1For example, the designation AN 0411 would indicate:AN = anaerobic adhesive (from Guide D 4800),04 (Group) = retaining com

26、pound,1 (Class) = low strength, and1 (Grade) = viscosity of 100500 mPa.5. Requirements5.1 General RequirementsGeneral requirements are prop-erties that are inherent in every lot of adhesive produced, butmay be tested in accordance with Table AN at a frequencyagreed on by the purchaser and the manufa

27、cturer in order toverify specification conformance.5.1.1 Ultraviolet FluorescenceThe uncured adhesiveshall fluoresce under ultraviolet illumination when tested inaccordance with 7.1.5.1.2 Color and WorkmanshipThe color supplied shall bethe color for the given group, class, and grade, as specified in

28、Table AN. The uncured adhesive shall be smooth and homo-geneous after shaking, free from lumps, caked material, andparticles of foreign matter when examined in accordance with7.2.5.1.3 Flash PointThe uncured adhesive shall have a flashpoint above 93C when tested in accordance with 7.3.5.1.4 Storage

29、StabilityThe strength shall conform to theproperties specified for the given class in Table AN. Theviscosity shall increase no more than 50 % above the upper-most limit for the given grade in Table AN when tested inaccordance with 7.12.5.1.5 ToxicityThe supplier shall furnish a Material SafetyData S

30、heet (MSDS) in accordance with FED-STD-313 so thatthe user can evaluate the safety of the material for the proposeduse.5.1.6 Solvent ResistanceThe average strength of eachadhesive, after solvent immersion testing in accordance with7.11, shall meet the requirements specified for the given classin Tab

31、le AN.5.1.7 Hot StrengthThe average strength of each adhesive,after hot-strength testing in accordance with 7.8, shall meet therequirements specified for the given class in Table AN.5.1.8 Heat AgingThe average strength of each adhesive,after heat-aging testing in accordance with 7.9, shall meet ther

32、equirements specified for the given class in Table AN.5Available from U.S. Government Printing Office Superintendent of Documents,732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http:/www.access.gpo.gov.6Available from Society of Automotive Engineers (SAE), 400 CommonwealthDr., Warrend

33、ale, PA 15096-0001, http:/www.sae.org.D536303e125.1.9 Cold StrengthThe average strength of each adhe-sive, after cold-strength testing in accordance with 7.10, shallmeet the requirements specified for the given class inTable AN.5.1.10 LubricityGroup 03 products shall show lubricityon the thread flan

34、ks to within 610 % of an as-receivedphosphate and oil,38 in.-16 grade 5 bolt, when tested inaccordance with 7.14.5.1.11 Fluid TightnessGroups 01, 02, and 03 productsshall be capable of making leak-tight assemblies when tested inaccordance with 7.15.5.1.12 WickingThe average breakaway and prevailingt

35、orque strength for Group 02, Class 4, 5, and 6 products, whentested in accordance with 7.16, shall meet the requirementsspecified in Table 1.5.2 Detail RequirementsDetail requirements are proper-ties which are adjusted in each lot of adhesive produced toprovide different groups, classes, and grades,

36、 and are tested onevery lot in accordance with Table AN to verify specificationconformance.5.2.1 ViscosityThe uncured adhesive shall have a viscos-ity within the range given in Table AN for the grade specifiedwhen tested in accordance with 7.4.5.2.2 Speed of CureThe average strength of each adhe-siv

37、e, when tested in accordance with 7.7, shall meet therequirements specified for the given class in Table AN.5.2.3 Strength at Standard ConditionsStandard conditionsare 21 to 25C (69.8 to 77F) and 45 to 55 % relative humidity.5.2.3.1 Groups 01, 02, and 03 ProductsThe averagestrength of each adhesive,

38、 when tested in accordance with 7.5,shall meet the requirements specified for the given class inTable AN.5.2.3.2 Group 04 ProductsThe minimum strength of eachadhesive, when tested in accordance with 7.6, shall meet therequirements specified for the given class in Table AN.6. Other Requirements6.1 Su

39、ffxesWhen requirements are needed that supersedeor supplement Table AN, they shall be specified through theuse of suffixes.6.2 When using the callout for materials covered by thisspecification, the suffixes that are found in Annex A1 may beused for the specific requirements for the material for thea

40、pplication intended. In general, the suffix letter gives thegeneral requirement needed, the first digit following gives thetest condition, and the second digit gives the specific require-ment.6.3 Additional suffixes will be added to this specification astest methods and requirements are developed. A

41、 further list ofsuffixes can be found in Guide D 4800 and may be used foradditional requirements as appropriate.NOTE 2Using the information from Note 1, an example of the suffixsystem follows. The designation AN 0411 H11 P15 would indicate:AN 0411 = information from Note 1,H = hot strength,1 = to be

42、 tested in accordance with 7.8 at a test temperatureof 204C,1 = hot strength shall meet the requirement stated in Table 2,P = package/container,1 = bottle (plastic), and5 = 250 mL.6.4 Qualification of PrimersPrimers Grade N and GradeT shall be tested in accordance with 7.17 with adhesivespecified by

43、 the adhesive manufacturer, and shall meet therequirements specified in Table 3.TABLE 1 Wicking Requirements for Group 02 Products, N mminPretorqued Non-PretorquedSteel Plated Steel PlatedPrevail Prevail Break Prevail Break PrevailClass 4 1.1 0.6 1.1 1.1 0.6 0.6Class 5 5.6 0.8 1.1 5.6 0.8 0.8Class 6

44、 8.5 4.2 1.1 8.5 0.6 4.2 Nm value for Class 6 was corrected editorially.TABLE 2 Cure Time for Speed-of-Cure TestGroup Class Time01 all 6 h02 1, 2, 3 90 min02 4, 5, 6 15 min03 all 60 minTABLE 3 Primer Qualification Requirements % of Strength atStandard ConditionsGrade N Grade TPlated Steel PlatedCure

45、 Strength Cure Strength Cure Strength6h 50% 10min 50% 30min 50%24 h 100 % 40 min 100 % 2 h 100 %D536303e13TABLEANBasicPropertiesAnaerobicAdhesivesGroup1ProductsGroupDescriptionClassDescriptionGradeColor(5.1.2)StrengthatStandardConditions,PrevailingTorqueStrength(5.2.3.1),NmViscosity(5.2.1),mPasSolve

46、ntResistance(5.1.6),PrevailingTorque,Nm,minHotStrength(5.1.7),PrevailingTorque,Nm,minHeatAging(5.1.8),PrevailingTorque,Nm,minColdStrength(5.1.9),PrevailingTorque,Nm,minSpeedofCure(5.2.2),PrevailingTorque,Nm,min01Threadlockingandretainingadhesives;slowcuring;Newtonianflowproperties110green17.042.4102

47、517.010.2A8.5A17.08.521red11.328.2102511.36.8A5.6A11.35.62orange11.328.2408011.36.8A5.6A11.35.63red11.328.210025011.36.8B5.6A11.35.64red11.328.210001000011.36.8B5.6A11.35.6031yellow7.919.81002007.94.7B3.9A7.93.9041blue4.511.310254.52.7A2.3A4.52.32blue4.511.31002504.52.7B2.3A4.52.33blue4.511.31000100

48、004.52.7A2.3A4.52.3051purple2.35.610252.31.3A1.1A2.31.12purple2.35.61002502.31.3B1.1A2.31.1061brown1.12.810251.10.7A0.6A1.10.62brown1.12.81002501.10.7B0.6A1.10.63brown1.12.81000100001.10.7A0.6A1.10.6071yellow0.81.51002500.80.4A0.4A0.80.400other0D536303e14TABLEANContinuedGroups2and3ProductsGroupDescr

49、iptionClassDescriptionGradeColor(5.1.2)StrengthatStandardConditions,TorqueStrength(5.2.3.1),NmViscosity(5.2.1),mPasSolventResistance(5.1.6),Nm,minSteelHotStrength(5.1.7),Nm,minASteelSteelPlatedBreakPrevailBreakPrevailBreakPrevailBreakPrevail02Threadlockingadhesives; fastcuring;Newtonianflowproperties110red16.939.516.956.55.639.54.556.5600080008.48.48.48.4C21red16.939.516.956.54.539.54.556.54006008.48.48.48.4A031blue11.322.65.617.03.422.62.322.61101505.62.85.62.8C04wicking