AASHTO R 16-2004 Standard Practice for Regulatory Information for Chemicals Used in AASHTO Tests《美国国家公路与运输协会试验用化学品常规信息标准推荐规范》.pdf

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1、Standard Practice for Regulatory Information for Chemicals Used in AASHTO Tests AASHTO Designation: R 16-04 (2016) Release: Group 1 (April 2016) American Association of State Highway and Transportation Officials 444 North Capitol Street N.W., Suite 249 Washington, D.C. 20001 TS-5b R 16-1 AASHTO Stan

2、dard Practice for Regulatory Information for Chemicals Used in AASHTO Tests AASHTO Designation: R 16-04 (2016) Release: Group 1 (April 2016) 1. SCOPE 1.1. This standard practice provides a reference listing of chemicals used in the various AASHTO Test Methods (see Table 1). It includes current regul

3、atory codes and hazard classifications. The list does not include radiation hazards. This practice is not intended as a substitute for law or regulation. 1.2. The chemical list must be provided to all laboratory employees engaged in performing AASHTO tests. In addition, all laboratory employees must

4、 be trained in proper handling procedures as stated in the OSHA 1910.1200 Hazard Communication Standard or governing state regulation. Laboratories performing AASHTO tests shall establish a Chemical Hygiene Plan as set out in 29 CFR 1910.1450, including the training requirements therein. 1.3. This p

5、ractice supplements data found in Material Safety Data Sheets (MSDSs) supplied by manufacturers. This practice is for quick reference ability and is not intended to replace MSDSs. 2. INTRODUCTION 2.1. In an effort to assure uniform compliance with regulations, the following definitions are cited: 2.

6、1.1. A hazardous chemical includes any substance that is in the definition of health hazard adopted by the United States Occupational Safety and Health Administration. 2.1.2. A hazardous waste includes, but is not limited to, any substance that has been assigned a code number from the EPA “Unlisted

7、(Characteristic) Hazardous Wastes” code. All hazardous waste must be disposed of in accordance with EPA, state, and local regulations. 2.2. Should there be any questions regarding whether a substance is hazardous, contact the local governing authority. 3. CHEMICAL LIST 3.1. This section contains def

8、initions of the terms and abbreviations contained in the list. All information is valid as of the date of this practice. 3.2. CAS No. is the number assigned to a substance by the Chemical Abstracts Service. 3.3. Test Method refers to the AASHTO test method in which the chemical is used. 2016 by the

9、American Association of State Highway and Transportation Officials. All rights reserved. Duplication is a violation of applicable law.TS-5b R 16-2 AASHTO 3.4. NIOSH REL is the Recommended Exposure Limit established by the National Institute for Occupational Safety and Health. The value corresponds t

10、o the concentration in air to which the employee may be exposed. These limits are a time-weighted average for an eight-hour workday. 3.4.1. Abbreviations under NIOSH REL and OSHA PEL: ppm is parts per million mg/m3is milligrams per cubic meter g/m3is micrograms per cubic meter CL is Ceiling Limit ST

11、EL is Short-Term Exposure Limit, which is for a 15-minute duration f is fume d is dust rf is respirable fraction 3.5. OSHA PEL is the Permissible Exposure Limit established by the Occupational Safety and Health Administration. These PELs went into effect September 1, 1989. The PELs are time-weighted

12、 average concentrations, just as the NIOSH RELs are. 3.5.1. See Section 3.4.1 for abbreviations used. 3.6. Carcin denotes substances that are listed as carcinogens in one of the following three sources: 3.6.1. NTP denotes a substance listed on National Toxicology Programs Annual Report on Carcinogen

13、s. 3.6.2. IARC denotes a substance listed in the International Agency for Research on Cancers Monographs, Groups I and II. 3.6.3. OSHAs 29 CFR 1910, subpart Z. 3.7. SkinAn “X” in this column denotes a substance for which skin contact is to be avoided, as it may be a route of entry. This includes muc

14、ous membranes and eyes. 3.8. DOT Label denotes Department of Transportation Hazard Class for transportation of these substances. 3.8.1. Abbreviations under DOT Label: Flam. is flammable Liq. is liquid St. Andr. is St. Andrews Cross (poison label) 3.9. RCRA No. is the number assigned to a substance u

15、nder the Resource Conservation and Recovery Act. 3.10. SHIP Code is the identification number assigned by the U.S. Department of Transportation in the Emergency Response Guidebook to hazardous materials for international and domestic shipment. 3.11. DOT Guide is a number assigned by the U.S. Departm

16、ent of Transportation for providing guidance primarily during the initial phases of an incident. 2016 by the American Association of State Highway and Transportation Officials. All rights reserved. Duplication is a violation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures Substance

17、 CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Acetic Acid 64-19-7 105, 192, 260, 281 10 ppm 25 mg/m310 ppm 25 mg/m3Corrosive Flam. Liq. UN2789 UN2790 29 Acetone 67-64-1 151, 201, 202, 250 250 ppm 590 mg/m3750 ppm 1800 mg/m3Hazardous Flam. Liq. U002 UN109

18、0 26 Acetylene 74-86-2 1 ppm 14 mg/m3CL: 2500 ppm Hazardous Flam. Gas UN1001 17 Alumina (Aluminum oxide) 1344-28-1 105 rf: 5 mg/m3d: 15 mg/m3Ammonium Acetate 631-61-8 105 NA9079 31 Ammonium Carbonate 10361-29-2 111, 143, 164 31 Ammonium Chloride 12125-02-9 105, 143 X 10 mg/m3STEL: 20 mg/m3NA9085 31

19、Ammonium Hydroxide 1336-21-6 105, 143, 144, 250 Corrosive 60 Ammonium Molybdate 12027-67-7 105 5 mg(Mo)/m3Ammonium Nitrate 6484-52-2 105, 144 Oxidizer Explosive NA1942 UN2067 UN2426 35 43 Ammonium Oxalate 1113-38-8 105, 143, 144 31 Ammonium Persulfate 7727-54-0 Oxidizer 35 Ammonium Phosphate 7783-28

20、-0 143 Oxidizer Ammonium Sulfate 7782-20-2 250 Anhydrous Denatured Alcohol 64-17-5 255 X 1000 ppm Flam. Liq. UN1170 26 Antimony Reagent 7440-36-0 0.5 mg(Sb)/m30.5 mg(Sb)/m3Poison St. Andr. UN2871 53 Antimony Trichloride 10025-91-9 65, 213 0.5 mg(Sb)/m3Corrosive UN1733 60 Antimonyl Tartrate X00001-05

21、-8 0.5 mg(Sb)/m30.5 mg(Sb)/m3Poison St. Andr. 53 Arsenic 7440-38-2 2 g/m3IARC 1 NTP X Poison B UN1558 53 Arsenic Trioxide 1327-53-3 105 2 g(As)/m3Poison B P012 UN1561 53 Barium Chloride 10361-37-2 104 0.5 mg/m30.5 mg/m3Continued on next page. TS-5bR16-3AASHTO 2016 by the American Association of Stat

22、e Highway and Transportation Officials. All rights reserved. Duplication is a violation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures (Continued) Substance CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Barium Hydroxide 17194-00-2 105 0

23、.5 mg/m30.5 mg/m3Benzene 71-43-2 62, 110 0.1 ppm CL: 1 ppm 10 ppm CL: 50 ppm IARC 1 NTP X OSHA X Flam. Liq. U019 UN1114 27 Bromine 7726-95-6 105 0.1 ppm 0.7 mg/m30.3 ppm STEL 2 mg/m3STEL 0.1 ppm 0.7 mg/m3X Corrosive UN1744 59 Cadmium 7440-43-9 Lowest Feas. Lim. f: 0.1 mg/m3d: 0.2 mg/m3IARC 2B NTP X

24、Cadmium Chloride 10108-64-2 105 NA2570 53 Calcium Carbide 75-20-7 217 Flam. Solid 40 Calcium Carbonate 471-34-1 105, 260 d: 15 mg/m3rf: 5 mg/m3Calcium Chloride 10043-52-4 59, 210 Calcium Hydroxide 1305-62-0 106, 132, 143, 160 X 5 mg/m3Irr. Caustic Calcium Metasilicate 1344-95-2 278, 279 X d:15 mg/m3

25、rf: 5 mg/m3Calcium Oxide 1305-78-8 218, 219, 220, 258 X 5 mg/m3UN1910 60 Carbon Dioxide 124-38-9 170 10000 ppm 10000 ppm STEL: 3000 ppm Non-Flam. Gas UN1013 UN1845 UN2187 21 Carbon Disulfide 75-15-0 42 1 ppm 4 ppm X P022 UN1131 28 5-Chloro-2-methyl-4- isothiazolin-3-one 26172-55-4 176 X Corrosive D0

26、02 Chloroacetic Acid 79-11-8 Corrosive 50 Chloroform 67-66-8 105, 151 2 ppm 2 ppm IARC 2B NTP X Poison B U044 UN1888 55 Chromic Acid 1308-14-1 72, 201, 202 CL: 0.1 mg/m3Corrosive 60 Cobalt Naphthenate 61789-51-3 278, 279 Flam. Solid 32 Copper 7440-50-8 1 mg/m31 mg/m3Copper Sulfate 7758-98-7 NA9109 C

27、reosote 8001-58-9 62 Toxic UN1993 27 m-CRESOL 108-39-4 2.3 ppm 5 ppm Poison U052 Dibutyl Phtalate 84-74-2 153 5 mg/m3Dichlorofluorescein 76-54-0 143 Continued on next page. TS-5bR16-4AASHTO 2016 by the American Association of State Highway and Transportation Officials. All rights reserved. Duplicati

28、on is a violation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures (Continued) Substance CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Dioctylsodium Sulfosuccinate 577-11-7 59 Ethanol 64-17-5 103, 105, 126, 219, 260, 264 X 1000 ppm Flam.

29、Liq. UN1170 26 EDTA 60-00-4 NA9117 Ethylene Glycol 107-21-1 53, 79, 151 X CL: 50 ppm 26 Ferric Chloride 10025-77-1 31 Ferric Sulfate 10028-22-5 194 NA9121 31 Ferrous Ammonium Sulfate 7783-85-9 31 Ferrous Sulfate 7720-78-7 105, 194 31 Formaldehyde 50-00-0 176 0.016 ppm 0.75 ppm 2.00 ppm STEL IARC-2A

30、X Flam. U122 UN1198 29 Glutaraldehyde (1,5- Pentanedial) 111-30-8 176 X UN2810 Glycerol 56-81-5 105 X d: 10 mg/m3rf: 5 mg/m3Gypsum 7778-18-9 22, 24, 126, 177, 231, 276 X d: 15 mg/m3rf: 5 mg/m3Heptane 142-82-5 102 85 ppm 400 ppm Flam. Liq. UN1206 27 Hexane 100-54-3 250 50 ppm 50 ppm Flam. UN1208 27 H

31、ydrochloric Acid 7647-01-0 42, 65, 105, 143, 144, 178, 192, 211, 213 219 232 250, 257, 264, 281 X CL: 5 ppm CL 7 mg/m3Corrosive Non-Flam. Gas UN1050 UN1789 NA1789 UN2186 60 Hydrofluoric Acid 7664-39-3 105, 178 3 ppm STEL: 5 ppm 3 ppm STEL: 5 ppm Corrosive Poison U134 UN1052 UN1790 39 Hydrogen Peroxi

32、de 7722-84-1 105, 260 X 1 ppm Oxidizer UN2014 UN2984 45, 47 60 Hydrogen Sulfide 778306-4 22, 24, 126, 177, 231, 276 10 ppm 10 ppm 14 mg/m3U135 UN1053 Isobutanol 78-83-1 105 50 ppm 50 ppm Flam. Liq. U140 UN1212 26 Isooctane 540-84-1 55 Flam. Liq. 27 Isopropanol 67-63-0 23, 103, 113, 126, 152, 157, 15

33、9, 160, 161, 196, 199, 260, 271 400 ppm CL: 800 ppm 400 ppm Flam. Liq. UN1219 26 Kerosene 8008-20-6 98, 113, 133, 250, 270 Flam. Liq. 27 Continued on next page. TS-5bR16-5AASHTO 2016 by the American Association of State Highway and Transportation Officials. All rights reserved. Duplication is a viol

34、ation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures (Continued) Substance CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Lead Acetate 301-04-2 NTP X Poison U144 UN1616 53 Lubricating Oil No CAS # 270 27 Magnesium Chloride 7786-30-3 176

35、Magnesium Nitrate 10377-60-3 176 Oxidizer UN1474 Magnesium Perchlorate 10034-81-8 105 X Oxidizer UN1475 35 Magnesium Sulfate 7487-88-9 104 40 Manganese Sulfate 7785-87-7 5 mg(Mn)/m3Manganous Sulfate Monohydrate 10034-96-5 5 mg(Mn)/m3Mercuric Chloride 7487-94-7 264 0.05 mg/m30.1 mg/m3Poison B UN1524

36、53 Mercuric Nitrate 10045-94-0 0.05 mg/m30.1 mg/m3Poison B Oxidizer UN1625 42 Mercuric Sulfate 7783-35-9 0.05 mg/m30.1 mg/m3Poison B UN1645 53 Mercury 7439-97-6 92, 153 0.05 mg/m30.05 mg/m3CL: 0.1 mg/m3X U151 UN2809 NA2809 60 Methanol 67-56-1 260 200 ppm CL: 800 ppm 200 ppm STEL: 250 ppm NTP X X Poi

37、son Flam. Liq. U154 UN1230 28 Methylene Chloride 75-09-2 164, 170 Lowest Feas. Lim. 500 ppm CL: 1000 ppm IARC X Poison St. Andr. U080 UN1593 74 25-Methyl-4- isothiazolin-3-one 2682-20-4 176 X Corrosive D002 Methyl Ethyl Ketone 78-93-3 250 200 ppm 590 mg/m3200 ppm STEL: 300 ppm Flam. Liq. U159 UN1193

38、 26 Methyl Ethyl Ketone Peroxide 1338-23-4 278, 279 X CL: 0.7 ppm Forbidden U160 UN2127 UN2550 51 Methyl Methacrylate 80-62-6 X 100 ppm 410 mg/m3Flam. Liq. U162 UN1247 26 Methyl Orange 547-58-0 26, 105, 143, 260 60 Methyl Red 493-52-7 105 Mineral Spirits 64475-85-0 49, 201, 202 27 n-Propyl Bromide 1

39、06-94-5 319 X Flam. Liq. UN2344 2344 Naphtha 8030-30-6 55, 102 X 100 ppm 400 mg/m3Flam. Liq. UN1255 UN1256 UN2553 27 Nitric Acid 7697-37-2 105, 143, 144, 260, 264, 281 2 ppm 5 mg/m32 ppm STEL: 4 ppm Corrosive Oxidizer NA1760 UN2031 44 Continued on next page. TS-5bR16-6AASHTO 2016 by the American Ass

40、ociation of State Highway and Transportation Officials. All rights reserved. Duplication is a violation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures (Continued) Substance CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Nitrogen 7727-37-

41、9 244, 266 Non. Flam. Gas 21 Nonylphenoxy poly (ethyleneoxy) ethanol 9016-45-9 252, 294 Paraffin 8002-74-2 233, 275 X f: 2 mg/m3Perchloric Acid 7601-90-3 105 Corrosive Oxidizer 45, 47 Petroleum Oil 8002-05-9 24, 126, 157, 177, 231, 244, 266 Flam. Liq. 27 Polyester Resin 109-16-0 278, 279 26 Potassiu

42、m Bromate 7758-01-2 105 Oxidizer 35 Potassium Chlorate 3811-04-9 Oxidizer 35, 44 Potassium Chromate 7789-00-6 143 CL: 0.1 mg (Cr03)/m3NA9142 31 Potassium Cyanide 151-50-8 5 mg(CN)/m3Poison B P098 UN1680 55 Potassium Dichromate 7778-50-9 21, 105, 194 CL: 0.1 mg (Cr03)/m3NA1479 35 Potassium Nitrate 77

43、58-09-0 105 Oxidizer 35 Potassium Permanganate 7722-64-7 105, 143, 144, 250 CL: 5 mg(Mn)/m3Oxidizer 35 Potassium Pyrosulfate 7790-62-7 105 Corrosive UN2509 Pyridine 110-86-1 X 5 ppm 15 mg/m3Flam. Liq. Poison U196 UN1282 26 Silicic Acid 7699-41-4 178 6 mg/m3Silicon 7440-21-3 227 X d: 10 mg/m3rf: 5 mg

44、/m3Flam. Solid UN1346 Silicon Dioxide 7631-86-9 278, 279 rf: 50 g/m3rf: 0.1 mg/m30.01 mg(Ag)/m3Oxidizer UN1493 45 Silver Nitrate 7761-88-8 105, 143, 194, 260 Silver Sulfate 10294-26-5 194 0.01 mg(Ag)/m345 Soda Lime 8006-28-8 280 Corrosive 60 Sodium Arsenite 7784-46-5 Poison B St. Andr. UN1686 53 Sod

45、ium Bisulfate 7681-38-1 5 mg/m3Corrosive 60 Continued on next page. TS-5bR16-7AASHTO 2016 by the American Association of State Highway and Transportation Officials. All rights reserved. Duplication is a violation of applicable law.Table 1Chemicals Used in AASHTO Test Procedures (Continued) Substance

46、 CAS No. Test Method NIOSH REL OSHA PEL Carcin Skin DOT Label RCRA No. SHIP Codes DOT Guide Sodium Chromate 7775-11-3 143 CL: 0.1 mg (Cr03)/m3NA9145 31 Sodium Cyanide 143-33-9 5 mg/m35 mg(CN)/m3X Poison B Corrosive P106 UN1689 55 Sodium Hexametaphosphate 88 Sodium Hydroxide 1310-73-2 21, 71, 105, 14

47、3, 178, 213, 219, 227, 257, 264, 277, 303 CL: 2 mg/m3CL: 2 mg/m3Corrosive UN1823 UN1824 60 Sodium Nitrate 7631-94-4 105, 260 Oxidizer 35 Sodium Nitrite 7632-00-0 Oxidizer UN1500 35 Sodium Oleate 143-19-1 59 Sodium Phosphate 7601-54-9 NA9148 31 Sodium Pyrosulfate 7681-38-1 105 Corrosive Sodium Sulfat

48、e 7757-82-6 104 Sodium Thiosulfate 772-98-27 264 Sodium Tripolyphosphate 7758-29-4 88 NA9148 Stannous Chloride 7772-99-8 105, 213 2 mg(5n)/m360 Stibine 7803-52-3 64, 213 0.1 ppm 0.1 ppm UN2676 18 Strontium Nitrate 10042-76-9 105 Oxidizer 35 Sulfamic Acid 5329-14-7 Irr Corrosive 60 Sulfuric Acid 7664-93-9 21, 105, 143, 144, 178, 194, 250, 264, 281 1 mg/m31 mg/m3UN1830 UN2796 39 Terpene 164 Flam. UN2319 27 1,1,2,2,-Tetra Bromoethane 79-27-6 113 1 ppm 1 ppm 14 mg/m3Poison B St. Andr. UN2504 58 Thioacetamide 62-55-5 NTP X U218 Thorium Nitrate 13823-29-5 Titanium Dioxide