BS PD CEN TR 16741-2015 Textiles and textile products Guidance on health and environmental issues related to chemical content of textile products intended for clothing int.pdf

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1、BSI Standards Publication PD CEN/TR 16741:2015 Textiles and textile products Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholsteryPD CEN/TR 16741:2015 PUBLISHED DOCUMENT National foreword This Published Doc

2、ument is the UK implementation of CEN/TR 16741:2015. The UK participation in its preparation was entrusted to Technical Committee TCI/80, Chemical testing of textiles. A list of organizations represented on this committee can be obtained on request to its secretary. This publication does not purport

3、 to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2015. Published by BSI Standards Limited 2015 ISBN 978 0 580 85884 0 ICS 59.080.01 Compliance with a British Standard cannot confer immunity from legal obligat

4、ions. This Published Document was published under the authority of the Standards Policy and Strategy Committee on 31 August 2015. Amendments issued since publication Date Text affectedPD CEN/TR 16741:2015TECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHER BERICHT CEN/TR 16741 August 2015 ICS 59.080.01 En

5、glish Version Textiles and textile products - Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery Textiles et produits textiles - Guide sur les consquences environnementales et sur la sant lies aux substa

6、nces chimiques prsentes dans les produits textiles destins lhabillement, aux textiles dintrieur et lameublement Textilien und textile Erzeugnisse - Anleitung fr Gesundheits-und Umweltfragen in Bezug auf den Chemikaliengehalt von Textilerzeugnissen fr Bekleidung, Heimtextilien und Polstermbel This Te

7、chnical Report was approved by CEN on 14 May 2015. It has been drawn up by the Technical Committee CEN/TC 248. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germa

8、ny, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR

9、NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 16741:2015 EPD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 2 Contents Page European foreword .4 Introduct

10、ion .5 1 Scope 6 2 Terms and definitions .6 3 General recommendations .7 3.1 CMR chemicals 7 3.2 PBT and vPvB substances .7 3.3 SVHC (“Substances of Very High Concern”) 7 4 Specific criteria for textile products 8 4.1 Formaldehyde . 14 4.1.1 General . 14 4.1.2 Why is it a critical substance? 14 4.1.

11、3 Regulation/Specific tests method . 15 4.2 Chlorophenols (pentachlorophenol, isomers of tetrachlorophenol) 15 4.2.1 General . 15 4.2.2 Why is PCP a critical substance? . 15 4.2.3 Regulation/Specific tests method . 15 4.3 Orthophenylphenol (OPP) 16 4.3.1 General . 16 4.3.2 Why is it a critical subst

12、ance? 16 4.3.3 Tests method . 16 4.4 Heavy metals . 16 4.4.1 General . 16 4.4.2 Extractable heavy metals . 17 4.4.3 Total heavy metal 17 4.4.4 Antimony -Sb . 17 4.4.5 Arsenic As 18 4.4.6 Barium Ba . 19 4.4.7 Cadmium Cd . 20 4.4.8 Chromium Cr 21 4.4.9 Cobalt Co 22 4.4.10 Copper Cu . 23 4.4.11 Lead Pb

13、 . 24 4.4.12 Mercury Hg . 26 4.4.13 Nickel Ni 27 4.4.14 Selenium Se 30 4.5 Flame retardants . 30 4.5.1 General . 30 4.5.2 Why is it a critical substance? 30 4.5.3 Regulation/Specific test methods . 31 4.6 Carcinogenic dyes, suspected dyes and derived substances 31 4.6.1 General . 31 4.6.2 Carcinogen

14、ic amines derived from azo colorants 32 4.6.3 Carcinogenic colorants and colorants suspected to be carcinogenic, mutagenic or toxic to reproduction . 32 4.6.4 Sensitizing colorants 33 4.7 Sensitizing substances (others than colorants) 34 4.8 Pesticides, herbicides and fungicides . 34 4.8.1 General .

15、 34 PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 3 4.8.2 Why is it a critical substance? . 35 4.8.3 Regulation/Specific test methods 35 4.9 Chloroorganics including carriers (chlorinated benzenes, chlorinated toluenes and chlorinated naphtalenes) 37 4.9.1 General . 37 4.9.2 Why is it a critical substa

16、nce? . 37 4.9.3 Regulation/Specific tests method 37 4.10 Phthalates. 38 4.10.1 General . 38 4.10.2 Why is it critical? . 38 4.10.3 Regulations / Specific test method 38 4.11 Organotin compounds 39 4.11.1 General . 39 4.11.2 Why is it critical? . 39 4.11.3 Regulations / Specific test method 39 4.12 P

17、erfluorooctanesulfonates (PFOS) and perfluorooctanoic acid (PFOA) . 40 4.12.1 General . 40 4.12.2 Why is it a critical substance? . 40 4.12.3 Regulations/Test method 41 4.13 Dimethylfumarate (DMFu) . 41 4.13.1 General . 41 4.13.2 Why is it a critical substance? . 41 4.13.3 Regulation/Specific test m

18、ethods 42 4.14 Alkyl phenol ethoxylates (APEO) . 42 4.14.1 General . 42 4.14.2 Why are APEO critical substances? 43 4.14.3 Regulations/Test methods 43 4.15 Residual solvents 43 4.15.1 General . 43 4.15.2 Why is it critical? . 43 4.15.3 Regulations / Specific test method 44 5 Others . 44 5.1 pH 44 5.

19、1.1 General . 44 5.1.2 Why is it critical? . 44 5.1.3 Regulation/Specific tests method 44 5.2 Colour fastness in relation to acidic and alkaline perspiration (recommendation for screening). 44 5.3 Polycyclic aromatic hydrocarbons (PAH) (screening when strong odour) 44 5.3.1 General . 44 5.3.2 Why is

20、 it critical? . 45 5.3.3 Regulations / Specific test method 45 Annex A (informative) Risk phrases 46 Annex B (informative) Criteria for the identification of persistent, bioaccumulative and toxic substances, and very persistent and very bioaccumulative substances . 47 B.1 General . 47 B.2 PBT substa

21、nces . 47 B.3 vPvB substances . 48 Bibliography 49 PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 4 European foreword This document (CEN/TR 16741:2015) has been prepared by Technical Committee CEN/TC 248 “Textiles and textile products”, the secretariat of which is held by BSI. Attention is drawn to the

22、possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 5 Introduction In 2003, the company CREM (Consultancy and Research fo

23、r Environmental Management, Amsterdam, The Netherlands) started reviewing a selected number of European standards to identify relevant environmental concerns which should be addressed. Horizontal requirements were drafted during the continuing work on draft standards. These horizontal requirements c

24、omprise, among others, CMR chemicals (carcinogenic, mutagenic and toxic to reproduction), PBTs and vPvB substances (persistent, bioaccumulative and toxic and very persistent and very bioaccumulative substances) and substances identified as causing serious and irreversible effects to humans or the en

25、vironment equivalent to the effects mentioned on a case-by-case basis, such as endocrine disrupters. CEN/TC248 has decided to adopt the proposal included in the study as a technical report with general requirements for textile products with direct skin contact. The working group extended the scope o

26、f the technical report to textile products in the proximity of the human body . In this technical report, the wording textile product is used, as defined in the Textile Fibre Regulation (EU) No 1007/2011. In the parts where REACH is described, the wording textile article is used in the same meaning.

27、 Thus, in the context of this technical report textile product and textile article are the same. PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 6 1 Scope This Technical Report specifies environmental and health recommendations for textile products (including accessories) with direct skin contact and in

28、the proximity of the human body. This Technical Report facilitates the understanding of chemicals with intended uses in the manufacturing of goods in the fields of textile products intended to clothing, interior textiles and upholstery, to comply with the European chemical regulations and recommenda

29、tions in force in EU. WARNING This Technical Report is not intended to substitute the existing regulations. The reader is requested to check the current existing regulation. By suggesting that the textile market follows the ethos of this Technical Report, and thereby avoiding the use of unwanted sub

30、stances in the manufacture of textile products, the level of protection of human health and of environment will be increased. The distinguishing properties of the chemicals and the processes in which they are used (intended use substances) or they occur (unintended release substances) are described

31、in this technical report. This Technical Report mentions, when relevant, the existing standardized test methods commonly in use, as well as, the related limit values which are generally accepted. Only the standard identification number is given in the main text and the related title is listed in Bib

32、liography. NOTE 1 When limit values are given, possible contamination by the external environment and inaccuracy in the measurement of very low concentration may be taken into consideration. The listed substances of this Technical Report can be categorised in two: one related to intended use, anothe

33、r one related to unintended release. NOTE 2 Inclusion in the candidate list of EU REACH Regulation (EC) n1907/2006 has been mentioned in this Technical Report for some substances. This does not necessarily mean that a substance, for which such a note is not made, would not be included in the candida

34、te list in the future (new substances are regularly included in the list). NOTE 3 For filling material such as “feather wall and floor coverings are excluded SOURCE: EU fibre composition Regulation (EC) n1007/2011 2.3 fibres, yarn and fabric intended for use in textile clothing and accessories or in

35、terior textiles PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 7 Note 1 to entry: For textile clothing and accessories and for interior textiles: down, feathers, membranes and coatings need not be taken into account in the calculation of the percentage of textile fibres. 2.4 CMR chemical chemical (subst

36、ance or substance mixtures) belonging to at least one of three different categories: Carcinogenic, Mutagenic and Reprotoxic (toxic to reproduction) Note 1 to entry: CMR chemicals are classified according to EU Classification Labelling Packaging Regulation (EC) n1272/2008 and are covered by the follo

37、wing R-phrases: R40, R45, R46 R49, R60, R61, R62, R63 and R68 (see Annex A). 2.5 PBT and vPvB substances Persistent, Bio accumulative and Toxic substances and very Persistent and very Bio accumulative substances Note 1 to entry: The terms of PBT and vPvB substances are defined in EU REACH Regulation

38、 (EC) n1907/2006 2.6 Substances of Very High Concern (SVHC) substances which should be treated with equivalent concern as CMR chemical and PBT and vPvB substances. Note 1 to entry: These substances for which there is scientific evidence of probable serious effect to human health or the environment w

39、hich give rise to an equivalent level of concern to CMR and/or PBT and/or vPvB substances. 3 General recommendations 3.1 CMR chemicals The product should not contain or release any carcinogenic, mutagenic or reprotoxic chemicals (CMR chemicals) in amounts exceeding 0,1 % by weight of the whole produ

40、ct. 3.2 PBT and vPvB substances The product should not contain any PBT and vPvB substances which meet the criteria in Annex XIII of EU REACH Regulation (EC) n1907/2006, in amounts exceeding 0,1 % by weight of the whole product. 3.3 SVHC (“Substances of Very High Concern”) SVHC are defined in Article

41、 57 of EU REACH Regulation (EC) n1907/2006 and include substances which are: Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC. This directive was recently replaced by the new EU Classification L

42、abelling Packaging Regulation (EC) n1272/2008 on classification, labelling and packaging of chemical substances and mixtures, the so-called CLP Regulation. According to the new CLP Regulation these substances shall be classified as 1a or 1b. Persistent, Bioaccumulative and Toxic (PBT) or very Persis

43、tent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of EU REACH Regulation (EC) n1907/2006, Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (

44、e.g. endocrine disrupters, allergenic substances and sensitizing substances) NOTE The list of identified substances of very high concern is updated regularly. The current listing can be found at http:/echa.europa.eu/candidate-list-table. The obligations relating to placing on the market articles con

45、taining SVHC PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 8 substances can be reviewed on ECHA webpages. Uses of some SVHCs in the EU require authorization. More information on this can also be found at http:/echa.europa.eu/ . 4 Specific criteria for textile products The criteria are listed in Table 1

46、 in relation to the type of fibres and in Table 2 in relation to the type of finishing and accessories. PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 9 Table 1 Criteria in relation to the type of fibres Type of fibres a)natural fibres man-made fibres Criteria Animal fibres Cellulose fibres Polyester Po

47、lyamide Acetate; Triacetate Acrylic Viscose Elastane Elastodiene Formaldehyde X X X Azo dyes X X X X X X X Extractable heavy metals Cd X X X X X X As X Hg X Ni X Cu X X Pb X X Cr X X Co X X X Sb X Chromium (VI) X X Chlorinated Phenols PCP, TeCP, TriCP X X X X X X X OPP X X X X X X X Carcinogenic dye

48、s X X X X X X X Allergenic Disperse dyes X X X X Chlorinated benzenes and toluenes X X X X PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 10 Organotin compounds X X X X X X X X Flame retardants X X X X X X X Acrylonitrile X Pesticides X X Herbicides X Dimethylformamide (DMF) X Dimethylfumarate (DMFu) X

49、x X X X X X APEO X X X X X X X DMA X X X PFOS b)X X X X X X X PAH X X X X X X X a)In case of fibre blends, all criteria related to the fibre of the blends have to be considered. b)only for water-, oil- and dirt- repellent finish or coated PD CEN/TR 16741:2015 CEN/TR 16741:2015 (E) 11 Table 2 Criteria in relation to the type of finishing and components used on textile products (buttons, slide fasteners, buckles, etc.) Criteria Type of finishing or accessories Pr