EN ISO 10062-2008 en Corrosion tests in artificial atmosphere at very low concentrations of polluting gas(es)《人工环境中特低浓度污染气体的腐蚀试验》.pdf

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1、BRITISH STANDARDBS EN ISO 10062:2008Corrosion tests in artificial atmosphere at very low concentrations of polluting gas(es)ICS 77.060g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g

2、50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 10062:2008This British Standard was published under the authority of the Standards Policy and Strategy Committee on 29 February 2008 BSI 2008ISBN 978 0 580 55060 7National forewordThis British Standard is the UK implementation of EN ISO 10062:2008. It is i

3、dentical to ISO 10062:2006. It supersedes BS EN ISO 10062:1995 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee ISE/NFE/8, Corrosion of metals and alloys.A list of organizations represented on this committee can be obtained on request to its secretary.T

4、his publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations.Amendments/corrigenda issued since publicationDate CommentsEUROPEAN STANDARDNORME

5、 EUROPENNEEUROPISCHE NORMEN ISO 10062January 2008ICS 77.060 Supersedes EN ISO 10062:1995 English VersionCorrosion tests in artificial atmosphere at very lowconcentrations of polluting gas(es) (ISO 10062:2006)Corrosion des mtaux et alliages - Essais de corrosion enatmosphre artificielle trs faible co

6、ncentration en gazpolluants (ISO 10062:2006)Korrosionsprfungen in knstlicher Atmosphre mit sehrniedrigen Konzentrationen von Schadgas(en) (ISO10062:2006)This European Standard was approved by CEN on 29 December 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stip

7、ulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard ex

8、ists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bo

9、dies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EURO

10、PEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2008 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 10062:2008: EForeword The t

11、ext of ISO 10062:2006 has been prepared by Technical Committee ISO/TC 156 “Corrosion of metals and alloys” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 10062:2008 by Technical Committee CEN/TC 262 “Metallic and other inorganic coatings“, the secretari

12、at of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2008, and conflicting national standards shall be withdrawn at the latest by July 2008. Attention is drawn to the p

13、ossibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 10062:1995. According to the CEN/CENELEC Internal Regulations, the national stand

14、ards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Po

15、rtugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 10062:2006 has been approved by CEN as EN ISO 10062:2008 without any modifications. BS EN ISO 10062:2008Reference numberISO 10062:2006(E)INTERNATIONAL STANDARD ISO10062Second ed

16、ition2006-01-15Corrosion tests in artificial atmosphere at very low concentrations of polluting gas(es) Corrosion des mtaux et alliages Essais de corrosion en atmosphre artificielle trs faible concentration en gaz polluants BS EN ISO 10062:2008ii iiiContents Page Foreword iv Introduction v 1 Scope .

17、 1 2 Normative references . 1 3 Terms and definitions. 2 4 Apparatus 2 5 Test methods. 2 6 Information to be given in the relevant specification . 6 7 Expression of results . 7 8 Test report . 7 Annex A (informative) Specifications for apparatus for corrosion tests in artificial atmospheres. 8 Annex

18、 B (informative) Typical apparatus for polluting gas corrosion tests 11 Bibliography . 12 BS EN ISO 10062:2008iv Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards

19、 is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take p

20、art in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to

21、 prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility t

22、hat some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 10062 was prepared by Technical Committee ISO/TC 156, Corrosion of metals and alloys. This second edition cancels and replaces the first

23、 edition (ISO 10062:1991), which has been technically revised. BS EN ISO 10062:2008vIntroduction Products with, for example, sensitive electrical functions, may, during storage or operation in indoor locations, be affected by atmospheric corrosion dependent on climatic factors such as temperature, r

24、elative humidity, air velocity and rate of change caused by temperature and humidity. Additionally, gaseous pollutants may seriously affect the rate of corrosion, as well as the occurrence of different corrosion mechanisms. Contaminants on the surface, such as salt, dust, oil and compounds liberated

25、 from plastics, may also affect the rate and mechanism of corrosion. Different corrosion-promoting gaseous pollutants dominate in different field environments: sulfur dioxide and nitrogen oxides in atmospheres influenced by combustion of fossil fuels and in traffic environments, hydrogen sulfide in

26、atmospheres in the vicinity of petrochemical and steel industry, decaying organic matter, stagnant waters and animal shelters, and hydrogen sulfide and chlorine compounds in the vicinity of pulp and paper industry; if chlorine is used for bleaching Those gaseous pollutants are known to act as single

27、 corrosion-promoting factors. However, in atmospheres where more than one gaseous pollutant is present, synergistic effects may be initiated. As a result, a considerable increase in the corrosion rate may occur, compared to the case when the different gaseous pollutants act as single corrosion-promo

28、ting factors. This International Standard is intended to a) define a general method using atmospheres polluted by one or more gases at very low volume fractions u106under specified conditions of temperature and relative humidity, so as to avoid condensation phenomena during the test, b) define the t

29、est apparatus and procedure required to achieve the best possible reproducibility, c) assess performance under test conditions which accelerate corrosion; as knowledge of operating conditions proceeds, more suitable pollutants or pollutant mixtures could be used. BS EN ISO 10062:2008blank1Corrosion

30、tests in artificial atmosphere at very low concentrations of polluting gas(es) WARNING Safety rules for personnel: Handling of the gases used for testing can be hazardous and must be left to skilled chemists or conducted under their control. The test equipment must be used and maintained by skilled

31、personnel, not only so that the tests can be performed correctly, but also because of the hazards to health and safety that are involved. 1 Scope This International Standard specifies tests which are intended to determine the influence of one or more flowing polluting gas(es) at volume fractions les

32、s than or equal to 10-6on test samples and/or articles of metals and alloys with or without corrosion protection under determined conditions of temperature and relative humidity. These tests apply to a) metals and their alloys, b) metallic coatings (anodic and cathodic), c) metals with conversion co

33、atings, d) metals with anodic oxide coatings, and e) metals with organic coatings. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the

34、 referenced document (including any amendments) applies. ISO 554, Standard atmospheres for conditioning and/or testing Specifications ISO 558, Conditioning and testing Standard atmospheres Definitions ISO 7384, Corrosion tests in artificial atmosphere General requirements ISO 8407, Corrosion of meta

35、ls and alloys Removal of corrosion products from corrosion test specimens BS EN ISO 10062:20082 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 exposure time interval of time elapsed between the moment when the specimens are introduced into t

36、he test chamber and the end of the test 3.2 test duration interval of time during which the specimens are exposed to polluting gases 4 Apparatus Special attention shall be paid to equipment design and the choice of construction materials, in order that the conditions (less than 1 C for temperature a

37、nd less than 3 % for relative humidity) are uniformly consistent throughout the working space, able to ensure no condensation in the test chamber, and are repeatable. The apparatus shall enable the use, singly or in mixtures, of polluting gas(es) such as SO2, H2S, Cl2and NO2up to at least the concen

38、tration required, for each gas, by the test method. The important parameters are a) the materials used for the test chamber and the gas handling system, b) the geometry of the test chamber, c) the rate and pattern of the gas flow, d) the homogeneity of gas mixing, e) the incident illumination (see A

39、.1.6) The apparatus shall be constructed according to Annex A and shall meet its requirements. A typical apparatus for polluting-gas corrosion tests is also shown in Annex B. 5 Test methods 5.1 Test severity 5.1.1 General The test severity, to be given in the relevant specification, is defined by th

40、e type, concentration and flow rate of polluting gas, the temperature, the relative humidity, and the test duration. BS EN ISO 10062:200835.1.2 Suggested test methods The method to be used depends upon the purposes of the test, the nature of the metals and alloys and the type of protection to be tes

41、ted. Method A Polluting gas SO2at a volume fraction of (0,5 0,1) 106Temperature and relative humidity (40 1) C and (80 5) % RH or (25 1) C and (75 3) % RH The condition of (40 1) C and (80 5) % is more aggressive than the condition of (25 1) C and (75 3) % RH. Either of them shall be optionally sele

42、cted and be stated in the test report. Method B Polluting gas H2S at a volume fraction of (0,10 0,02) 106Temperature and relative humidity (40 1) C and (80 5) % RH or (25 1) C and (75 3) % RH The condition of (40 1) C and (80 5) % RH is more aggressive than the condition of (25 1) C and (75 3) % RH.

43、 Either of them shall be optionally selected and be stated in the test report. Method C Polluting gas Cl2at a volume fraction of (0,02 0,005) 106Temperature and relative humidity (40 1) C and (80 5) % RH or (25 1) C and (75 3) % RH The condition of (40 1) C and (80 5) % RH is more aggressive than th

44、e condition of (25 1) C and (75 3) % RH. Either of them shall be optionally selected and be stated in the test report. Method D Mixture of polluting gases SO2at a volume fraction of (0,5 0,1) 106, and H2S at a volume fraction of (0,10 0,02) 106Temperature and relative humidity (40 1) C and (80 5) %

45、RH or (25 1) C and (75 3) % RH The condition of (40 1) C and (80 5) % RH is more aggressive than the condition of (25 1) C and (75 3) % RH. Either of them shall be optionally selected and be stated in the test report. BS EN ISO 10062:20084 Method E Mixture of polluting gases SO2at a volume fraction

46、of (0,20 0,05) 106, and NO2at a volume fraction of (0,5 0,1) 106Temperature and relative humidity (40 1) C and (80 5) % RH or (25 1) C and (75 3) % RH The condition of (40 1) C and (80 5) % RH is more aggressive than the condition of (25 1) C and (75 3) % RH. Either of them shall be optionally selec

47、ted and be stated in the test report. Method F Mixture of polluting gases SO2at a volume fraction of (0,5 0,1) 106, H2S at a volume fraction of (0,10 0,02) 106, and Cl2at a volume fraction of (0,02 0,005) 106Temperature and relative humidity (40 1) C and (80 5) % RH or (25 1) C and (75 3) % RH The c

48、ondition of (40 1) C and (80 5) % RH is more aggressive than the condition of (25 1) C and (75 3) % RH. Either of them shall be optionally selected and be stated in the test report. NOTE 1 Since the corrosivity is different for methods A, B, C, D, E and F the result obtained by these methods are not

49、 comparable. NOTE 2 Other methods may be added in the future if required (e.g. increase in the relative humidity). 5.1.3 Test duration The test duration for each test method depends upon the purposes of the test, the nature of the metals and alloys and the means of protection tested. 5.2 Treatment of the specimens prior to testing (see Clause 6) The relevant specif