EN 62321-8-2017 en Determination of certain substances in electrotechnical products - Part 8 Phthalates in polymers by gas chromatography-mass spectrometry (GC-MS) gas chromatograp.pdf

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1、Determination of certain substances in electrotechnical productsPart 8: Phthalates in polymers by gas chromatography-mass spectrometry (GC-MS), gas chromatography-mass spectrometry using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS) (IEC 62321-8:2017)BS EN 62321-8:2017BSI Standards Publicat

2、ionWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 62321-8June 2017ICS 31.020; 71.040.50English VersionDetermination of certain substances in electrotechnical products- Part 8: Phthalates in polymers by gas chromatography-mass spectrometry (G

3、C-MS), gas chromatography-mass spectrometryusing a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS)(IEC 62321-8:2017)Dtermination de certaines substances dans les produitslectrotechniques - Partie 8: Analyse des phtalates dans lespolymres par chromatographie en phase gazeuse-spectromtrie de mass

4、e (GC-MS), chromatographie en phase gazeuse-spectromtrie de masse parpyrolyse/thermodsorption (Py/TD-GC-MS)(IEC 62321-8:2017)Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik - Teil 8: Phthalate inPolymeren mit Pyrolyse-Gaschromatographie-Massenspektrometrie (Py-GC-M

5、S), Ionen-Anlagerungs-Massenspektrometrie (IAMS), Gaschromatographie-Massenspektrometrie (GC-MS) und Flssigchromatographie-Massenspektrometrie (LC-MS)(IEC 62321-8:2017)This European Standard was approved by CENELEC on 2017-05-02. CENELEC members are bound to comply with the CEN/CENELECInternal Regul

6、ations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CENELEC me

7、mber.This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versio

8、ns.CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic,Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Ne

9、therlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,Switzerland, Turkey and the United Kingdom.European Committee for Electrotechnical StandardizationComit Europen de Normalisation ElectrotechniqueEuropisches Komitee fr Elektrotechnische NormungCEN-CENELEC Managem

10、ent Centre: Avenue Marnix 17, B-1000 Brussels 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members.Ref. No. EN 62321-8:2017 ENational forewordThis British Standard is the UK implementation of EN 62321-8:2017. It is identical to IEC 62321-8:2017.

11、 Together with BS EN 62321-1:2013, BS EN 62321-2:2014, BS EN 62321-3-1:2014, BS EN 62321-3-2:2014, BS EN 62321-4:2014, BS EN 62321-5:2014, BS EN 62321-6:2015, BS EN 62321-7-1:2015 and BS EN 62321-7-2, it supersedes BS EN 62321:2009, which will be withdrawn upon publication of all parts of the BS EN

12、62321 series.The UK participation in its preparation was entrusted to Technical Committee GEL/111, Electrotechnical environment committee.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary p

13、rovisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017 Published by BSI Standards Limited 2017ISBN 978 0 580 84323 5ICS 31.020; 71.040.50Compliance with a British Standard cannot confer immunity from legal obligations. This British Standard

14、 was published under the authority of the Standards Policy and Strategy Committee on 31 July 2017.Amendments/corrigenda issued since publicationDate Text affectedBRITISH STANDARDBS EN 623218:2017EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 62321-8 June 2017 ICS 31.020; 71.040.50 English Vers

15、ion Determination of certain substances in electrotechnical products - Part 8: Phthalates in polymers by gas chromatography-mass spectrometry (GC-MS), gas chromatography-mass spectrometry using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS) (IEC 62321-8:2017) Dtermination de certaines substa

16、nces dans les produits lectrotechniques - Partie 8: Analyse des phtalates dans les polymres par chromatographie en phase gazeuse-spectromtrie de masse (GC-MS), chromatographie en phase gazeuse-spectromtrie de masse par pyrolyse/thermodsorption (Py/TD-GC-MS) (IEC 62321-8:2017) Verfahren zur Bestimmun

17、g von bestimmten Substanzen in Produkten der Elektrotechnik - Teil 8: Phthalate in Polymeren mit Pyrolyse-Gaschromatographie-Massenspektrometrie (Py-GC-MS), Ionen-Anlagerungs-Massenspektrometrie (IAMS), Gaschromatographie-Massenspektrometrie (GC-MS) und Flssigchromatographie-Massenspektrometrie (LC-

18、MS) (IEC 62321-8:2017) This European Standard was approved by CENELEC on 2017-05-02. CENELEC members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lis

19、ts and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CENELEC member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation u

20、nder the responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic, Denmark,

21、Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Europea

22、n Committee for Electrotechnical Standardization Comit Europen de Normalisation Electrotechnique Europisches Komitee fr Elektrotechnische Normung CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide f

23、or CENELEC Members. Ref. No. EN 62321-8:2017 E BS EN 623218:2017EN 62321-8:2017 2 European foreword The text of document 111/416/CDV, future edition 1 of IEC 62321-8, prepared by IEC/TC 111 “Environmental standardization for electrical and electronic products and systems“ was submitted to the IEC-CE

24、NELEC parallel vote and approved by CENELEC as EN 62321-8:2017. The following dates are fixed: latest date by which the document has to be implemented at national level by publication of an identical national standard or by endorsement (dop) 2018-02-02 latest date by which the national standards con

25、flicting with the document have to be withdrawn (dow) 2020-05-02 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CENELEC shall not be held responsible for identifying any or all such patent rights. Endorsement notice The text of t

26、he International Standard IEC 62321-8.2017 was approved by CENELEC as a European Standard without any modification. In the official version, for Bibliography, the following notes have to be added for the standards indicated: ISO 3696 NOTE Harmonized as EN ISO 3696. ISO/IEC 17025 NOTE Harmonized as E

27、N ISO/IEC 17025. IEC 62321-2:2013 NOTE Harmonized as EN 62321-2:2014. IEC 62321-6:2015 NOTE Harmonized as EN62321-6:2016 BS EN 623218:2017EN 62321-8:2017 2 European foreword The text of document 111/416/CDV, future edition 1 of IEC 62321-8, prepared by IEC/TC 111 “Environmental standardization for e

28、lectrical and electronic products and systems“ was submitted to the IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-8:2017. The following dates are fixed: latest date by which the document has to be implemented at national level by publication of an identical national standard or by en

29、dorsement (dop) 2018-02-02 latest date by which the national standards conflicting with the document have to be withdrawn (dow) 2020-05-02 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CENELEC shall not be held responsible for i

30、dentifying any or all such patent rights. Endorsement notice The text of the International Standard IEC 62321-8.2017 was approved by CENELEC as a European Standard without any modification. In the official version, for Bibliography, the following notes have to be added for the standards indicated: I

31、SO 3696 NOTE Harmonized as EN ISO 3696. ISO/IEC 17025 NOTE Harmonized as EN ISO/IEC 17025. IEC 62321-2:2013 NOTE Harmonized as EN 62321-2:2014. IEC 62321-6:2015 NOTE Harmonized as EN62321-6:2016 EN 62321-8:2017 3 Annex ZA (normative) Normative references to international publications with their corr

32、esponding European publications The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including

33、any amendments) applies. NOTE 1 When an International Publication has been modified by common modifications, indicated by (mod), the relevant EN/HD applies. NOTE 2 Up-to-date information on the latest versions of the European Standards listed in this annex is available here: www.cenelec.eu. Publicat

34、ion Year Title EN/HD Year IEC 62321-1 2013 Determination of certain substances in electrotechnical products - Part 1: Introduction and overview EN 62321-1 2013 BS EN 623218:2017This page deliberately left blank 2 IEC 62321-8:2017 IEC 2017 CONTENTS FOREWORD . 6 INTRODUCTION . 8 1 Scope 9 2 Normative

35、references 9 3 Terms, definitions and abbreviated terms 10 3.1 Terms and definitions 10 3.2 Abbreviated terms . 10 4 Principle 11 5 Reagents and materials . 11 5.1 GC-MS method . 11 5.2 Py/TD-GC-MS method 12 6 Apparatus 12 6.1 GC-MS method . 12 6.2 Py/TD-GC-MS method 13 7 Sampling . 14 7.1 General .

36、 14 7.2 GC-MS method . 14 7.3 Py/TD-GC-MS method 14 8 Procedure 14 8.1 General instructions for the analysis . 14 8.1.1 Overview . 14 8.1.2 GC-MS method 14 8.1.3 Py/TD-GC-MS method . 14 8.2 Sample preparation . 15 8.2.1 GC-MS method 15 8.2.2 Py/TD-GC-MS method . 16 8.3 Instrumental parameters . 16 8

37、.3.1 GC-MS method 16 8.3.2 Py/TD-GC-MS method . 18 8.4 Calibrants . 18 8.5 Calibration 19 8.5.1 GC-MS method 19 8.5.2 Py/TD-GC-MS method . 20 9 Calculation of phthalate concentration . 21 9.1 GC-MS method . 21 9.2 Py/TD-GC-MS method 22 10 Precision . 23 10.1 GC-MS method . 23 10.1.1 Threshold judgem

38、ent . 23 10.1.2 Repeatability and reproducibility 24 10.2 Py/TD-GC-MS method 25 10.2.1 Screening judgement . 25 10.2.2 Repeatability and reproducibility 26 11 Quality assurance and control . 27 11.1 General . 27 2 IEC 62321-8:2017 IEC 2017 CONTENTS FOREWORD . 6 INTRODUCTION . 8 1 Scope 9 2 Normative

39、 references 9 3 Terms, definitions and abbreviated terms 10 3.1 Terms and definitions 10 3.2 Abbreviated terms . 10 4 Principle 11 5 Reagents and materials . 11 5.1 GC-MS method . 11 5.2 Py/TD-GC-MS method 12 6 Apparatus 12 6.1 GC-MS method . 12 6.2 Py/TD-GC-MS method 13 7 Sampling . 14 7.1 General

40、. 14 7.2 GC-MS method . 14 7.3 Py/TD-GC-MS method 14 8 Procedure 14 8.1 General instructions for the analysis . 14 8.1.1 Overview . 14 8.1.2 GC-MS method 14 8.1.3 Py/TD-GC-MS method . 14 8.2 Sample preparation . 15 8.2.1 GC-MS method 15 8.2.2 Py/TD-GC-MS method . 16 8.3 Instrumental parameters . 16

41、8.3.1 GC-MS method 16 8.3.2 Py/TD-GC-MS method . 18 8.4 Calibrants . 18 8.5 Calibration 19 8.5.1 GC-MS method 19 8.5.2 Py/TD-GC-MS method . 20 9 Calculation of phthalate concentration . 21 9.1 GC-MS method . 21 9.2 Py/TD-GC-MS method 22 10 Precision . 23 10.1 GC-MS method . 23 10.1.1 Threshold judge

42、ment . 23 10.1.2 Repeatability and reproducibility 24 10.2 Py/TD-GC-MS method 25 10.2.1 Screening judgement . 25 10.2.2 Repeatability and reproducibility 26 11 Quality assurance and control . 27 11.1 General . 27 BS EN 623218:2017IEC 62321-8:2017 IEC 2017 3 11.2 GC-MS method . 27 11.2.1 Performance

43、27 11.2.2 Limit of detection (LOD) or method detection limit (MDL) and limit of quantification (LOQ) 28 11.3 Py/TD-GC-MS method 29 11.3.1 Sensitivity 29 11.3.2 Blank test 29 11.3.3 Limit of detection (LOD) or method detection limit (MDL) and limit of quantification (LOQ) 29 12 Test report . 30 Annex

44、 A (informative) Determination of phthalates in polymers by ion attachment mass spectrometry (IAMS) 31 A.1 Principle . 31 A.2 Reagents and materials 31 A.3 Apparatus . 31 A.4 Sampling. 32 A.5 Procedure . 32 A.5.1 General instructions for the analysis 32 A.5.2 Sample preparation . 32 A.5.3 Instrument

45、al parameters 33 A.5.4 Calibrants 34 A.5.5 Calibration . 34 A.6 Calculation of phthalates concentration . 35 A.7 Quality assurance and control . 35 A.7.1 General . 35 A.7.2 Sensitivity 35 A.7.3 Recovery . 35 A.7.4 Blank test 36 A.7.5 Limit of detection (LOD) or method detection limit (MDL) and limit

46、 of quantification (LOQ) 37 A.8 Test report 37 Annex B (informative) Determination of phthalates in polymers by liquid chromatography-mass spectrometry(LC-MS) 38 B.1 Principle . 38 B.2 Reagents and materials 38 B.3 Apparatus . 38 B.4 Sampling. 39 B.5 Procedure . 39 B.5.1 General instructions for the

47、 analysis 39 B.5.2 Sample preparation . 39 B.5.3 Instrumental parameters 40 B.5.4 Calibrants 42 B.5.5 Calibration . 42 B.6 Calculation of phthalates concentration . 43 B.7 Quality assurance and control . 44 B.7.1 General . 44 B.7.2 Performance 44 B.7.3 Limit of detection (LOD) or method detection li

48、mit (MDL) and limit of quantification (LOQ) 44 B.8 Test report 45 BS EN 623218:2017IEC 62321-8:2017 IEC 2017 3 11.2 GC-MS method . 27 11.2.1 Performance 27 11.2.2 Limit of detection (LOD) or method detection limit (MDL) and limit of quantification (LOQ) 28 11.3 Py/TD-GC-MS method 29 11.3.1 Sensitivi

49、ty 29 11.3.2 Blank test 29 11.3.3 Limit of detection (LOD) or method detection limit (MDL) and limit of quantification (LOQ) 29 12 Test report . 30 Annex A (informative) Determination of phthalates in polymers by ion attachment mass spectrometry (IAMS) 31 A.1 Principle . 31 A.2 Reagents and materials 31 A.3 Apparatus . 31 A.4 Sampling. 32 A.5 Procedure . 32 A.5.1 General instructions for the analysis 32 A.5.2 Sample preparation . 32 A.5.3 Instrumental parameters 33 A.5.4 Calibrants 34 A.5.5 Calibration . 34 A.6 Calculation