EN 15513-2014 en Chemicals used for treatment of swimming pool water - Carbon dioxide《用于游泳池水质处理的化学品 二氧化碳》.pdf

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1、BSI Standards PublicationBS EN 15513:2014Chemicals used for treatmentof swimming pool water Carbon dioxideBS EN 15513:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 15513:2014. Itsupersedes BS EN 15513:2007 which is withdrawn.The UK participation in its pr

2、eparation was entrusted to TechnicalCommittee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible

3、for its correctapplication. The British Standards Institution 2014. Published by BSI StandardsLimited 2014ISBN 978 0 580 82881 2ICS 71.100.80Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy

4、and Strategy Committee on 31 March 2014.Amendments issued since publicationDate Text affectedBS EN 15513:2014EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15513 March 2014 ICS 71.100.80 Supersedes EN 15513:2007English Version Chemicals used for treatment of swimming pool water - Carbon dioxid

5、e Produits chimiques utiliss pour le traitement de leau des piscines - Dioxyde de carbone Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser - Kohlenstoffdioxid This European Standard was approved by CEN on 5 January 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regula

6、tions which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member

7、. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN

8、 members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, P

9、ortugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in an

10、y form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15513:2014 EBS EN 15513:2014EN 15513:2014 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 5 2 Normative references 5 3 Description .5 3.1 Identification .5 3.2 Commercial form .6 3.3 Physical properties 6 3.4 Che

11、mical properties 7 4 Purity criteria 7 4.1 General 7 4.2 Composition of commercial product .7 4.3 Impurities and main by-products .7 4.4 Chemical parameters 8 5 Test methods 8 6 Labelling Transportation Storage 8 6.1 Means of delivery .8 6.2 Labelling according to the EU legislation ).9 6.3 Transpor

12、tation regulations and labelling 9 6.4 Marking .9 6.5 Storage 9 Annex A (informative) General information on carbon dioxide 10 A.1 Origin . 10 A.2 Use . 10 A.3 General rules relating to safety . 11 Bibliography . 12 BS EN 15513:2014EN 15513:2014 (E) 3 Foreword This document (EN 15513:2014) has been

13、prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2014 and conflicting national standa

14、rds shall be withdrawn at the latest by September 2014. This document supersedes EN 15513:2007. The significant technical difference between this edition and EN 15513:2007 is as follows: Updating of 6.2 in line with current legislation. According to the CEN-CENELEC Internal Regulations, the national

15、 standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuan

16、ia, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. WARNING The use of this standard may involve hazardous materials, operations and equipment. This standard does not purport to address all the safety p

17、roblems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. BS EN 15513:2014EN 15513:2014 (E) 4 Introduction With respect for potential adverse effe

18、cts on the quality of swimming pool water, caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting th

19、e adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or

20、 EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. BS EN 15513:2014EN 15513:2014 (E) 5 1 Scope This European Standard is applicable to carbon dioxide used for treatment of swimming pool water. It describes the characteristics

21、of carbon dioxide and specifies the requirements and the corresponding test methods for carbon dioxide. It gives information on its use in swimming pool water treatment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispens

22、able for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 936, Chemicals used for treatment of water intended for human consumption - Carbon dioxide 3 Description 3.1 Id

23、entification 3.1.1 Chemical name Carbon dioxide. 3.1.2 Synonym or common name Carbonic acid gas (carbonic anhydride). 3.1.3 Relative molecular mass 44,011. 3.1.4 Empirical formula CO2. 3.1.5 Chemical formula CO2. 3.1.6 CAS Registry Number 1)124-38-9. 3.1.7 EINECS reference 2)204-696-9. 1) Chemical A

24、bstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. BS EN 15513:2014EN 15513:2014 (E) 6 3.2 Commercial form The carbon dioxide is supplied as a liquefied gas. 3.3 Physical properties 3.3.1 Appearance The carbon dioxide is a colourless gas or liquid. 3.

25、3.2 Density The density of the gas at 0 C and 101,3 kPa 3)is 1,9 768 kg/m3, while the density of the liquid at 0 C and 4 000 kPa is 933,318 kg/m3. 3.3.3 Solubility in water The solubility of the gas in water is 1,72 g/l at 20 C and 101,3 kPa. 3.3.4 Vapour pressure The vapour pressure of the liquid i

26、s 5 733,0 kPa at 20 C. 3.3.5 Boiling point at 100 kPa3(See 3.3.6). 3.3.6 Melting point The sublimation point of solid CO2is 78,9 C and 101,3 kPa. 3.3.7 Specific heat The specific heat of carbon dioxide is 0,827 kJ/kg x K at 0 C and 100 kPa. 3.3.8 Viscosity (dynamic) The viscosity of the liquid is 14

27、7 107Pa x s at 20 C. 3.3.9 Critical temperature The critical temperature of the liquid is 31 C. 3.3.10 Critical pressure The critical pressure of the carbon dioxide is 7 383 kPa. 3.3.11 Physical hardness Not applicable. 3) 100 kPa = 1 barBS EN 15513:2014EN 15513:2014 (E) 7 3.4 Chemical properties Th

28、e carbon dioxide CO2forms a weak acid when dissolved in water. It reacts with alkalis to form carbonates and bicarbonates. 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for carbon dioxide used for the treatment of swimming pool water. Limits are given

29、 for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to the relevant authorities. Users of the product should check national regulations in order

30、to clarify whether it is of appropriate purity for treatment of swimming pool water, taking into account water quality, required dosage, and contents of other impurities and additives used in the product not stated in the product European Standard. Limits have been given for impurities and chemical

31、parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to significant quantities of other impurities, by-products or additives being present, this shall be notified to the user.

32、4.2 Composition of commercial product The products shall conform to the requirements specified in Table 1. Table 1 Composition of commercial product Carbon dioxide, CO2 99,9 % (V/V) NOTE The minimum requirements of the commercial product are defined in the EU Directive 2008/84/EC of August 27, 2008

33、(see2) and additional Changes RL 2010/67/EU from 20th October 2010. 4.3 Impurities and main by-products The product tested in liquid phase shall conform to the requirements specified in Table 2. BS EN 15513:2014EN 15513:2014 (E) 8 Table 2 - Requirements Moisture 50 ppm v/v (20 ppm w/w max.) Ammonia

34、2,5 ppm v/v Oxygen 30 ppm v/v Oxides of Nitrogen (NO/NO2) 2,5 ppm v/v each Non-volatile residue(particulates) 10 ppm w/w Non-volatile organic components (oil and fat) 5 ppm w/w Phosphine 1) 0,3 ppm v/v Total volatile hydrocarbons (calculated as methane) 50 ppm v/v of which 20 ppm v/v non-methane hyd

35、rocarbons. Acetaldehyde 0,2 ppm v/v Benzene 0,02 ppm v/v Carbon Monoxide 10 ppm v/v Methanol 10 ppm v/v Hydrogen Cyanide 2) 0,5 ppm v/v Total Sulfur (as S) 3) 0,1 ppm v/v Taste and Odour in Water Acceptable to consumers and no abnormal change 1)Analysis necessary only for carbon dioxide from phospha

36、te rock sources 2)Analysis necessary only for carbon dioxide from coal gasification sources 3)If the total sulfur content exceeds 0.1 ppm v/v as sulfur then the species should be determined separately and the following limits apply: Carbonyl Sulfide 0,1 ppm v/v Hydrogen Sulfide 0,1 ppm v/v Sulfur Di

37、oxide 1,0 ppm v/v 4.4 Chemical parameters NOTE Further chemical parameters and indicator parameters according to EU Directive 98/83/EC (see 3) are not found in the gaseous phase. Pesticides and polycyclic aromatic hydrocarbons are not by-products of the manufacturing process. 5 Test methods The meth

38、ods for sampling and analysis are those specified in EN 936. 6 Labelling Transportation Storage 6.1 Means of delivery The carbon dioxide shall be delivered in pressurised cylinders or by tankers. In order that the purity of the product is not affected, the means of delivery shall not have been used

39、previously for any different product or it shall have been specially cleaned and prepared before use. BS EN 15513:2014EN 15513:2014 (E) 9 6.2 Labelling according to the EU legislation 4)Carbon dioxide is not subject to labelling regulations at the date of publication of this European Standard. The l

40、egislation,1 and its amendments for the purposes of its adaptation to technical and scientific progress, contains a list of substances classified by the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to the criteria in the regul

41、ation by the person responsible for the marketing of the substance. 6.3 Transportation regulations and labelling Liquid carbon dioxide is listed as UN Number 5)1013. Refrigerated liquid carbon dioxide is listed as UN Number 2187. For liquid carbon dioxide: RID 6)ADR 7): class 2, classification code

42、2A. IMDG 8): class 2. For refrigerated carbon dioxide: RID 3)ADR 4): class 2, classification code 3A. IMDG 5): class 2. 6.4 Marking The marking shall include the following: name “carbon dioxide” and trade name; net mass; name and address of supplier and/or manufacturer; statement “this product confo

43、rms to EN 15513”. 6.5 Storage The product is stable during long term storage. Pressure cylinders containing, carbon dioxide shall be protected from direct heat and storage rooms shall be well-ventilated, especially if they are below ground level. Cylinders shall preferably be stored horizontally; if

44、 upright, they shall be secured to prevent them toppling over. For more details about use, see Annex A. 4) See 1. 5)United Nations Number. 6) Regulation concerning the International Carriage of Dangerous Goods by Rail (RID). 7) European Agreement concerning the International Carriage of Dangerous Go

45、ods by Road (ADR). 8) International Maritime Dangerous Goods Code (IMDG). BS EN 15513:2014EN 15513:2014 (E) 10 Annex A (informative) General information on carbon dioxide A.1 Origin A.1.1 Raw materials Natural carbon dioxide or as a product from chemical processes or from combustion, which differs f

46、rom natural carbon dioxide chiefly in the components of residual gases. A.1.2 Manufacturing process Carbon dioxide is condensed gradually in one or more steps up to the corresponding liquefy pressure, than cleaned, dried up, if needed filtered and subsequently liquefied in large scaled refrigerators

47、, after that stored in pressure vessels (tanks). A.2 Use A.2.1 Function The product is used for adjustment of pH value of pool water. A.2.2 Form in which it is used The product is used in gaseous form. A.2.3 Treatment dose The treatment dose is variable depending on the composition of swimming pool

48、water. For example, to increase the hydrogen carbonate content of the water, expressed as calcium carbonate, by 10 mg/l a dose of 4,4 mg CO2/l would be required. A.2.4 Means of application Carbon dioxide is dissolved under pressure through an injector into a circulating system of swimming pool. A.2.

49、5 Secondary effects In some conditions the product can increase the carbonated alkalinity. A.2.6 Removal of excess of product Excess carbon dioxide is removed by aeration, binding with alkaline reacting chemicals or by stripping with other inert gases. BS EN 15513:2014EN 15513:2014 (E) 11 A.3 General rules relating to safety A.3.1 Rules for safe handling and use The supplier will provide current safety instructions. A.3.2 Emergency procedures A.3.2.1 First aid In case of inhalation, the affected person