EN 71-9-2005 en Safety of toys - Part 9 Organic chemical compounds - Requirements (Incorporates Amendment A1 2007)《玩具安全 第9部分 有机化合物 要求》.pdf

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1、BRITISH STANDARDBS EN 71-9:2005 +A1:2007Safety of toys Part 9: Organic chemical compounds RequirementsThe European Standard EN 71-9:2005, incorporating amendment A1:2007, has the status of a British StandardICS 97.200.50g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44

2、g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN 71-9:2005+A1:2007This British Standard was published under the authority of the Standards Policy and Strategy Committee on 25 February 2005 BSI 2007ISBN 978 0 580 59840 1Nati

3、onal forewordThis British Standard is the UK implementation of EN 71-9:2005+A1:2007. The start and finish of text introduced or altered by amendment is indicated in the text by tags. Tags indicating changes to CEN text carry the number of the CEN amendment. For example, text altered by CEN amendment

4、 A1 is indicated by !“.The UK participation in its preparation was entrusted by Technical Committee CW/15, Safety of toys, to Subcommittee CW/15/-/4, Chemical requirements.A list of organizations represented on this subcommittee can be obtained on request to its secretary.This publication does not p

5、urport to include all the necessary provisions of a contract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations.Amendments issued since publicationAmd. No. Date Comments17278 31 August 2007 Implementation of CEN amendme

6、nt A1:2007EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-9:2005+A1 July 2007 ICS 97.200.50 Supersedes EN 71-9:2005English Version Safety of toys - Part 9: Organic chemical compounds - Requirements Scurit des jouets - Partie 9: Composs organiques chimiques - Exigences Sicherheit von Spielzeu

7、g - Teil 9: Organisch-chemische Verbindungen - Anforderungen This European Standard was approved by CEN on 15 November 2004 and includes Amendment 1 approved by CEN on 26 May 2007. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving thi

8、s European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions

9、(English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bul

10、garia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDAR

11、DIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-9:2005+A1:2007: EEN 71-9:2005+A1:2007 (E) 2 Conte

12、nts Page Foreword3 Introduction .4 1 Scope 6 2 Normative references 6 3 Terms and definitions .6 4 Requirements.7 4.1 Limits (see A.4) 7 4.2 Liquids in toys (see A.5) .8 4.3 Formaldehyde (see A.6) 8 4.4 Methods of analysis (see A.7) 8 Annex A (informative) Rationale 13 A.1 General13 A.2 Accessible l

13、iquid (see 3.2)13 A.3 Polymeric (see 3.6) 13 A.4 Limits (see 4.1).13 A.5 Liquids in toys (see 4.2) 14 A.6 Formaldehyde (see 4.3).14 A.7 Methods of analysis (see 4.4).14 A.8 Colourants and primary aromatic amines (see Table 1, Table 2 B and Table 2 C).14 A.9 Applicable limit tables (see Table 1)15 A.

14、10 Limit tables (see Tables 2 A to 2 I).15 A.11 Toys containing cosmetic components 16 Annex B (informative) Conformity assessment .17 Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives18 Bibliography 19 Tables of 4.4 Table

15、 1 Applicable limit tables Table 2 A Flame retardants Table 2 B Colourants Table 2 C Primary aromatic amines Table 2 D Monomers (migration) Table 2 E Solvents (migration) Table 2 F Solvents (inhalation) Table 2 G a) and b) Wood preservatives Table 2 H Preservatives (other than wood preservatives) Ta

16、ble 2 I Plasticisers (migration) EN 71-9:2005+A1:2007 (E) 3 Foreword This document (EN 71-9:2005+A1:2007) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This document shall be given the status of a national standard, either by publication

17、 of an identical text or by endorsement, at the latest by January 2008 and conflicting national standards shall be withdrawn at the latest by January 2008. This document includes Amendment 1 approved by CEN on 2007-05-26. This document supersedes EN 71-9:2005. The start and finish of text introduced

18、 or altered by amendment is indicated in the text by tags ! “. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informati

19、ve Annex ZA, which is an integral part of this document. This standard constitutes part 9 of the European Standard on Safety of Toys. This part should be read in conjunction with parts 10 and 11. This !standard“ defines contact routes and specifies limits for the migration or content of certain chem

20、ical compounds in toys. This !standard“ contains three annexes: - Annex A (informative) Rationale - Annex B (informative) Conformity assessment - Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives. According to the CEN/CENE

21、LEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxemb

22、ourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 71-9:2005+A1:2007 (E) 4 Introduction The !standard“ EN 71 for safety of toys consists of the following parts. Part 1: Mechanical and physical properties Part 2: Flammabi

23、lity Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test methods Part 8: Swings, slides and simil

24、ar activity toys for indoor and outdoor family domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The !standards“ EN 71-9, !EN 71-10“ and !EN 71-11“ were mandated b

25、y the European Commission (M/229) to address the risks presented by organic compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This !standard“ gives requirements for organic compounds in cer

26、tain toys and toy materials. In drafting the !standard“, CEN/TC 52 considered the risks associated with more than 650 organic compounds. It was recognized that not all potentially hazardous organic compounds could be addressed. The Commission further restricted the Mandate to substances classified a

27、s dangerous under Council Directive 67/548/EEC. This !standard“, therefore, supports but does not reduce the responsibility of toy manufacturers, importers and suppliers for ensuring that the use of other substances will not endanger the health whilst playing with toys as intended or in a reasonably

28、 foreseeable way. In addition, there should be no exposure to children from toys, in amounts which may harm their health, of organic chemical substances which are classified by other relevant statutes as carcinogenic, mutagenic or toxic for reproduction and for which no requirements are specified in

29、 this !standard“. !Future editions of this standard may address additional organic compounds. Users of this standard are reminded that compliance with the standard can only provide presumption of conformity with the essential safety requirements of the Toys Safety Directive in respect of the substan

30、ces addressed.“ This part should be read in conjunction with !EN 71-10“, which describes sample preparation and extraction procedures, and !EN 71-11“, which specifies methods of analysis. At the date of publication, the standard does not specify requirements for chemical compounds which are prohibit

31、ed in toys by Council Directive 76/769/EEC of 27thJuly 1976, as amended, on restrictions on the marketing and use of certain dangerous substances and preparations. This !standard“ takes into account the opinion of the Toxicology Section of the Scientific Advisory Committee published in 1992 (EUR 139

32、76) which recommended that certain groups of chemical compounds used in toys and toy materials need to be given special attention. In drafting this !standard“ CEN/TC 52 has considered organic chemicals that can be classified within the following groups: Solvents Preservatives Plasticisers (excluding

33、 phthalate plasticisers)1 Flame retardants Monomers Biocides (wood preservatives) 1Phthalate plasticisers were specifically excluded from the scope of mandate M/229. EN 71-9:2005+A1:2007 (E) 5 Processing aids Colouring agents During the development of this !standard“, CEN/TC 52 has considered the re

34、quirements set out in Council Directive 82/711/EEC as amended and its supporting standards. EN 71-9:2005+A1:2007 (E) 6 1 Scope This Part 9 of the !standard“ EN 71 for safety of toys specifies requirements for the migration or content of certain hazardous organic chemical compounds from/in certain to

35、ys and toy materials (see Table 1) by the following exposure routes: - mouthing - ingestion - skin contact - eye contact - inhalation when used as intended or in a foreseeable way, bearing in mind the normal behaviour of children and the function and design of the toy. This !standard“ does not conta

36、in requirements for chemical toys, experimental sets or finger-paints, which are addressed by other parts of EN 71. Packaging materials used with toys are not within the scope of the !standard“ unless they form part of the toy or have intended play value. 2 Normative references The following referen

37、ced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. !EN 71-1:2005+A4:2007“, Safety of toys - Part 1: Mechanical and physic

38、al properties EN 71-5, Safety of toys Part 5: Chemical toys (sets) other than experimental sets !EN 71-10, Safety of toys - Part 10: Organic chemical compounds - Sample preparation and extraction“ !EN 71-11, Safety of toys - Part 11: Organic chemical compounds - Methods of analysis“ EN 645, Paper an

39、d board intended to come into contact with foodstuffs Preparation of a cold water extract EN 717-3, Wood-based panels Determination of formaldehyde release Part 3: Formaldehyde release by the flask method EN 1541, Paper and board intended to come into contact with foodstuffs - Determination of forma

40、ldehyde in an aqueous extract EN ISO 787-9, General methods of test for pigments and extenders Part 9: Determination of pH value of aqueous suspension (ISO 787-9:1981) EN ISO 14184-1, Textiles Determination of formaldehyde Part 1: Free and hydrolysed formaldehyde (water extraction method) (ISO 14184

41、-1:1998) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. EN 71-9:2005+A1:2007 (E) 7 3.1 accessible contact with the articulated probe when tested in accordance with the accessibility-of-a-part-or-component test in !EN 71-1:2005+A4:2007“ 3.2 (see

42、A.2) accessible liquid liquid in or on a toy or accompanying a toy to which the child is likely to become exposed during normal or foreseeable use of the toy (e.g. liquid paints, bubble liquids, ink in pens, liquids provided with toys for squirting) 3.3 mouth-actuated toy toy which relies on an acti

43、on of the mouth to operate and which therefore is designed to come into contact with the mouth during play (e.g. toy whistles, toy imitation novelty teeth). Inflatable toys are not considered mouth-actuated toys unless they rely on an action of the mouth after inflation 3.4 mouthed licked, sucked an

44、d chewed 3.5 paper material, marketed as either paper or paperboard, with a maximum mass per unit area of 400 g/m2!EN 71-1:2005+A4:2007“ 3.6 (see A.3) polymeric consisting of plastic, synthetic rubber, natural rubber, silicone polymer but not other natural polymers 3.7 resin-bonded wood wood-based m

45、aterial, for example, plywood, particle board, chipboard and medium-density fibreboard (MDF) 3.8 textile woven or knitted fabrics, non-woven fibrous material (e.g. felt) 3.9 toy material material from which toys and toy components are made 3.10 toy which a child can enter any toy, having a door, lid

46、 or similar device, which encloses a continuous volume greater than 0,03 m3and in which all internal dimensions are 150 mm or more. 4 Requirements 4.1 Limits (see A.4) 4.1.1 Table 1 specifies toys, toy components and toy materials for which this !standard“ contains requirements. An “X” is indicated

47、in columns 2A 2I when requirements are given in the limit Tables 2 A 2 I for certain groups of organic chemicals. The toys and accessible toy components specified in Table 1 shall not contain or release the organic compounds in the relevant limit tables in amounts which exceed the limits specified.

48、EN 71-9:2005+A1:2007 (E) 8 4.1.2 If a limit specified in a limit table is expressed as “Action limit”, the relevant limit shall be the limit of the applicable method as specified in !EN 71-11“. NOTE See also 4.4 relating to methods of analysis. 4.1.3 If a particular toy or toy component fits more th

49、an one of the descriptions given in Table 1, then the limit tables indicated for each of the descriptions shall apply to that toy or accessible toy component. 4.2 Liquids in toys (see A.5) 4.2.1 Toys shall not contain accessible liquids classified in accordance with Directive 1999/45/EC as very toxic, toxic, harmful, corrosive, irritant or sensitising; and the accessible liquids shall not contain substances that are classified as carcinogenic, mutagenic or toxic to reproduction, category 1 or 2. However, as a der