EN 71-10-2005 en Safety of toys - Part 10 Organic chemical compounds - Sample preparation and extraction《玩具安全 第10部分 有机化合物 样品制备和抽取》.pdf

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1、BRITISH STANDARDBS EN 71-10:2005Safety of toys Part 10: Organic chemical compounds Sample preparation and extractionThe European Standard EN 71-10:2005 has the status of a British StandardICS 97.200.50g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g4

2、0g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN 71-10:2005This British Standard was published under the authority of the Standards Policy and Strategy Committee on 12 January 2006 BSI 12 January 2006ISBN 0 580 46782 1National forewordThis Br

3、itish Standard is the official English language version of EN 71-10:2005.The UK participation in its preparation was entrusted by Technical Committee CW/15, Safety of toys, to Subcommittee CW/15/-/4, Chemical requirements, which has the responsibility to: A list of organizations represented on this

4、subcommittee can be obtained on request to its secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using

5、the “Search” facility of the BSI Electronic Catalogue or of British Standards Online.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from

6、legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK.Sum

7、mary of pagesThis document comprises a front cover, an inside front cover, the EN title page, pages 2 to 25 and a back cover.The BSI copyright notice displayed in this document indicates when the document was last issued.Amendments issued since publicationAmd. No. Date CommentsEUROPEAN STANDARDNORME

8、 EUROPENNEEUROPISCHE NORMEN 71-10December 2005ICS 97.200.50English VersionSafety of toys - Part 10: Organic chemical compounds - Samplepreparation and extractionScurit des jouets - Partie 10: Composs chimiquesorganiques - Procdures de prparation dchantillon etdextractionSicherheit von Spielzeug - Te

9、il 10: Organisch-chemischeVerbindungen - Probenvorbereitung und ExtraktionThis European Standard was approved by CEN on 6 October 2005.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national st

10、andard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other l

11、anguage made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,G

12、ermany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement

13、 Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 71-10:2005: EEN 71-10:2005 (E) 2 Contents page Foreword 3 Introduction4 1 Scope .5 2 Normative references .5 3 Terms and definitions.5

14、4 Requirements (see B.6) 6 5 Sample preparation.9 6 Migration Sampling and extraction.9 6.1 Simulant (see B.7).9 6.2 Apparatus 9 6.3 Sampling9 6.4 Extraction (see B.8).10 7 Inhalation Sampling, extraction and analysis10 7.1 First-action method for solvents10 7.2 Final-action method for solvents.10 8

15、 Specific sampling and extraction procedures 10 8.1 Textiles Flame retardants, colourants and primary aromatic amines10 8.2 Leather Colourants, primary aromatic amines and preservatives .11 8.3 Wood Colourants, primary aromatic amines and wood preservatives13 8.4 Paper Colourants and primary aromati

16、c amines.14 8.5 Aqueous liquids - Colourants, primary aromatic amines and preservatives .14 8.6 Solid toy materials intended to leave a trace - Colourants and primary aromatic amines16 8.7 Modelling clay, play clay and similar - Colourants, primary aromatic amines and preservatives.16 8.8 Balloon-ma

17、king compounds Colourants and primary aromatic amines .17 8.9 Imitation tattoos with adhesive - Colourants, primary aromatic amines and preservatives.18 Annex A (normative) First-action method for colourants and primary aromatic amines20 Annex B (informative) Rationale22 Annex ZA (informative) Relat

18、ionship between this European Standard and the Essential Requirements of EU Directive 88/378/EEC24 Bibliography.25 EN 71-10:2005 (E) 3 Foreword This European Standard (EN 71-10:2005) has been prepared by Technical Committee CEN/TC 52 “Safety of Toys”, the secretariat of which is held by DS. This Eur

19、opean Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2006, and conflicting national standards shall be withdrawn at the latest by June 2006. This European Standard has been prepared under a mandate given

20、to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this European Standard. This European Standard constitutes part 10 of the E

21、uropean Standard on Safety of Toys. This part should be read in conjunction with parts 9 and 11. This European Standard defines the sample preparation and extraction procedures used to address potential exposure to organic compounds from ingestion, mouthing, inhalation, skin contact with solids and

22、skin and eye contact with liquids. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,

23、Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 71-10:2005 (E) 4 Introduction The European Standard EN 71 for safety of toys consists of the following parts: Part 1: Mechanical

24、 and physical properties Part 2: Flammability Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test

25、 methods Part 8: Swings, slides and similar activity toys for indoor and outdoor family domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The standards EN 71-9, EN

26、 71-10 and EN 71-11 were mandated by the European Commission (M/229) to address the risks presented by organic compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This European Standard speci

27、fies the procedures for preparing and extracting samples of toy materials prior to analysis by the methods described in EN 71-11. This part should be read in conjunction with EN 71-9, which contains requirements for certain organic compounds in toys, and EN 71-11, which specifies methods of analysis

28、. This European Standard takes into account the opinion of the Toxicology Section of the Scientific Advisory Committee published in 1992 (EUR 13976), which recommended that certain groups of chemical compounds used in toys and toy materials need to be given special attention. In drafting this Europe

29、an Standard CEN/TC 52 has considered organic chemicals that can be classified within the following groups: Solvents Preservatives Plasticisers (excluding phthalate plasticisers)1 Flame retardants Monomers Biocides (wood preservatives) Processing aids Colouring agents During the development of this E

30、uropean Standard, CEN/TC 52 has considered the requirements set out in Council Directive 82/711/EEC as amended and its supporting standards. 1Phthalate plasticisers were specifically excluded from the scope of mandate M/229. EN 71-10:2005 (E) 5 1 Scope This Part 10 of the European Standard EN 71 for

31、 safety of toys specifies sample preparation and extraction procedures for establishing the release or content of organic compounds from those toys for which requirements exist in EN 71-9. 2 Normative references The following referenced documents are indispensable for the application of this Europea

32、n Standard. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 71-1, Safety of toys Part 1: Mechanical and physical properties EN 71-9, Safety of toys Part 9: Organic chemical compounds Re

33、quirements EN 71-11:2005, Safety of toys Part 11: Organic chemical compounds Methods of analysis EN 20105-A03, Textiles Tests for colour fastness Part A03: Grey scale for assessing staining ISO 105-F10, Textiles Tests for colour fastness Part F10: Specification for adjacent fabric: Multifibre 3 Term

34、s and definitions For the purposes of this European Standard, the following terms and definitions apply. 3.1 (see B.2) accessible contact with the articulated probe when tested in accordance with the accessibility-of-a-part-or-component test in EN 71-1 3.2 accessible liquid liquid in or on a toy or

35、accompanying a toy to which the child is likely to become exposed during normal or foreseeable use of the toy NOTE Liquid paints, bubble liquids, ink in pens, liquids provided with toys for squirting are examples of accessible liquids 3.3 (see B.3) first-action method method of analysis designed to

36、show the compliance of a toy or toy material with the requirements of EN 71-9 for a particular compound or group of compounds 3.4 final-action method method of analysis for use when compliance cannot be demonstrated by a first-action method 3.5 (see B.4) laboratory sample single toy in the form in w

37、hich it is marketed or intended to be marketed EN 71-10:2005 (E) 6 3.6 mouth-actuated toy toy which relies on an action of the mouth to operate and which therefore is designed to come into contact with the mouth during play. Inflatable toys are not considered mouth-actuated toys unless they rely on

38、an action of the mouth after inflation NOTE Toy whistles, toy imitation novelty teeth are examples of mouth-actuated toys 3.7 (see B.5) mouthed licked, sucked and chewed 3.8 paper material, marketed as either paper or card, with a maximum mass per unit area of 400 g/m23.9 polymeric consisting of pla

39、stic, synthetic rubber, natural rubber, silicone polymer but not other natural polymers 3.10 resin-bonded wood wood-based material NOTE Plywood, particle board, chipboard and medium-density fibreboard (MDF) are examples of resin-bonded wood 3.11 test portion portion of the laboratory sample prepared

40、 for analysis 3.12 textile woven or knitted fabrics, non-woven fibrous material NOTE Felt is an example of non-woven fibrous material 3.13 toy material material from which toys and toy components are made 4 Requirements (see B.6) Toys, toy components and toy materials specified in columns 1 and 2 of

41、 Table 1 shall be sampled and analysed in accordance with Clause 5 and the clauses of this European Standard specified in columns 3 to 12 of Table 1. If a clause number relating to a first-action method is given in Table 1 for a particular toy / toy component and toy material, compliance with EN 71-

42、9 may be shown by the analysis of the toy material by that method alone for the relevant group of organic compounds. A first-action method shall not be used to show non-compliance with the requirements of EN 71-9. EN 71-10:2005 (E) 7 Table 1 Applicable sampling and preparation clauses Requirements F

43、lameretardants Colourantsand Primary aromaticaminesMonomers-migration Solvents -migration Solvents -inhalationWood preservatives Preservatives PlasticisersSPECIFIC TOY/TOY COMPONENT Toy material ProcedureFirst actionFinal actionProcedureProcedureFirst actionFinal actionProcedureProcedureProcedure1 T

44、oys intended to be mouthed by children under 3 years of age POLYMERICa6 6 6 2 POLYMERICa6 6 6 3 WOOD 8.3.1 a paper clip is often appropriate. 6.4 Extraction (see B.8) Place the test portion into the extraction bottle using tweezers. Add 100 mlsimulant (6.1) at (20 2) C. Close the extraction bottle a

45、nd secure it in the rotator. Rotate the bottle at (60 5) r/min for (60 5) min. Filter the aqueous migrate in the bottle through a plug of glass wool. Analyse the aqueous migrate using the appropriate method(s) specified in EN 71-11. 7 Inhalation Sampling, extraction and analysis 7.1 First-action met

46、hod for solvents See A.2 of EN 71-11:2005 7.2 Final-action method for solvents See A.3 of EN 71-11:2005 8 Specific sampling and extraction procedures 8.1 Textiles Flame retardants, colourants and primary aromatic amines 8.1.1 Flame retardants Examine the laboratory sample and determine which textile

47、 components are present and accessible, and have an accessible area of 10 cm2or more. Remove test portions from the textile components having an accessible area greater than 10 cm2 on the toy. The test portions may be cut from the laboratory sample with a suitable blade. Cut each test portion such t

48、hat no dimension exceeds 3 mm. Store each test portion separately in a suitable container. Weigh, to the nearest 1 mg, approximately 0,5 g of the test portion into a 20-ml amber glass vial with a PTFE-liner screw cap. Add 5 ml acetonitrile and place the vial in an ultrasonic bath for 60 min at 40 C.

49、 Filter the extract, transfer to a vial and crimp. Analyse the extract in accordance with 5.2 of EN 71-11:2005. 8.1.2 First-action method for colourants and primary aromatic amines This test, specified in Annex A and based on EN ISO 105-E04, is an assessment of whether any colourants can be transferred from textile toy materials to the mouth, mucous membranes or skin. If textiles are found not to be colourfast when tested in accordance with the test procedure described in Annex A, they shall be t