EN 14069-2017 en Liming materials - Denominations specifications and labelling.pdf

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1、Liming materials - Denominations, specifications and labellingBS EN 14069:2017BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14069 November 2017 ICS 65.080 Supersedes EN 14069:2003English Version Liming materials

2、- Denominations, specifications and labelling Amendements minraux basiques - Dnominations, spcifications et tiquetage Kalkdnger - Beschreibung, Spezifizierung und Kennzeichnung This European Standard was approved by CEN on 2 July 2017. CEN members are bound to comply with the CEN/CENELEC Internal Re

3、gulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN me

4、mber. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.

5、 CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Polan

6、d, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploi

7、tation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14069:2017 ENational forewordThis British Standard is the UK implementation of EN 14069:2017. It supersedes BS EN 14069:2003, which is withdrawn.The UK participation in its preparation was entrusted to Techn

8、ical Committee CII/37, Fertilisers and related chemicals.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The B

9、ritish Standards Institution 2017 Published by BSI Standards Limited 2017ISBN 978 0 580 91789 9ICS 65.080Compliance with a British Standard cannot confer immunity from legal obligations. This British Standard was published under the authority of the Standards Policy and Strategy Committee on 30 Nove

10、mber 2017.Amendments/corrigenda issued since publicationDate Text affectedBRITISH STANDARDBS EN 14069:2017EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14069 November 2017 ICS 65.080 Supersedes EN 14069:2003English Version Liming materials - Denominations, specifications and labelling Amendem

11、ents minraux basiques - Dnominations, spcifications et tiquetage Kalkdnger - Beschreibung, Spezifizierung und Kennzeichnung This European Standard was approved by CEN on 2 July 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving t

12、his European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official

13、 versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Aus

14、tria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spa

15、in, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwid

16、e for CEN national Members. Ref. No. EN 14069:2017 EBS EN 14069:2017EN 14069:2017 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scope 5 2 Normative references 5 3 Terms and definitions . 6 4 Denominations and specifications for liming materials . 6 5 Analytical methods 23 6 Tolerances 2

17、3 6.1 General . 23 6.2 Material passing a specific sieve . 23 7 Use of terms 23 8 Declaration . 24 Bibliography . 26 BS EN 14069:2017EN 14069:2017 (E) 3 European foreword This document (EN 14069:2017) has been prepared by Technical Committee CEN/TC 260 “Fertilizers and liming materials”, the secreta

18、riat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2018, and conflicting national standards shall be withdrawn at the latest by May 2018. Attention is drawn to the p

19、ossibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14069:2003. In comparison with the previous edition, the following changes have been made: a) the mi

20、nimum requirements laid down in Regulation (EC) No 463/2013 2 amending Regulation (EC) No 2003/2003 1 concerning liming materials have been taken into account; b) references to analytical methods extended; c) the requirements are specified for products of standard quality and for fine quality produc

21、ts (see Table 1 to Table 6); d) requirements concerning oxide and hydroxide limes of natural origin added (see Table 2); e) requirements concerning silicate limes added (see Table 4); f) requirements concerning mixed limes added (see Table 5); g) requirements concerning mixtures of liming materials

22、with other EC fertilizer types added (see Table 6); h) requirements for declaration and labelling extended according to Regulation (EC) No 463/2013 2; i) editorially revised. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound

23、to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,

24、Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 14069:2017EN 14069:2017 (E) 4 Introduction Throughout the member countries of CEN, regular liming to regulate the soil pH level and to neutralize the effect of soil acidification is a well-establish

25、ed and essential agricultural operation on all soils in humid climates and under all systems of agricultural cultivation. Liming improves soil fertility and supplies essential plant nutrients. Liming materials are also used in forest liming, lake liming and the liming of water catchment areas. A wid

26、e range of natural geological deposits of liming materials is found in all member countries of CEN. Some industrial processes produce materials acceptable as liming products. This very wide range of material differs substantially in both chemical and physical properties. The use of these various mat

27、erials will vary according to the type of material. Still, this standard specifies the main properties of the liming materials used in Europe. However, for the purpose of comparison of these products, it is necessary to describe and specify the minimum requirements of a liming material. In the frame

28、 of the 1st revision of this European Standard the minimum requirements laid down in Regulation (EC) No 463/2013 2 amending Regulation (EC) No 2003/2003 1 concerning liming materials have been taken into account. Liming materials in Europe show a large diversity due to factors as climate and type of

29、 crops, production, transport, storing and spreading of lime adapted to regional conditions. Standard quality covers these varying liming materials, whilst Fine quality credits rapidly dissolving materials needed for certain specialized agricultural productions or to allow the dissolution of the lim

30、ing material in some soil types having a higher pH value in a rapid and controlled way. BS EN 14069:2017EN 14069:2017 (E) 5 1 Scope This European Standard describes and specifies the requirements of products of natural origin and products from industrial processes of basic and fine quality to be use

31、d as liming materials in agriculture for raising the pH of soil (and water). 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated r

32、eferences, the latest edition of the referenced document (including any amendments) applies. EN 12048, Solid fertilizers and liming materials - Determination of moisture content - Gravimetric method by drying at (105 +/- 2)C (ISO 8190:1992, modified) EN 12944-1, Fertilizers and liming materials and

33、soil improvers - Vocabulary - Part 1: General terms EN 12944-3, Fertilizers and liming materials - Vocabulary - Part 3: Terms relating to liming materials EN 12945, Liming materials - Determination of neutralizing value - Titrimetric methods EN 12946, Liming materials - Determination of calcium cont

34、ent and magnesium content - Complexometric method EN 12947, Liming materials - Determination of magnesium content - Atomic absorption spectrometric method EN 12948, Liming materials - Determination of size distribution by dry and wet sieving EN 13475, Liming materials - Determination of calcium cont

35、ent - Oxalate method EN 13971, Carbonate and silicate liming materials - Determination of reactivity - Potentiometric titration method with hydrochloric acid EN 14397-2, Fertilizers and liming materials - Determination of carbon dioxide - Part 2: Method for liming materials EN 14984, Liming material

36、s - Determination of product effect on soil pH - Soil incubation method EN 15704, Liming materials - Determination of the breakdown of granulated calcium and calcium/magnesium carbonates under the influence of water EN 16357, Carbonate liming materials - Determination of reactivity - Automatic titra

37、tion method with citric acid ISO 6598, Fertilizers Determination of phosphorus content Quinoline phosphomolybdate gravimetric method ISO 7497, Fertilizers Extraction of phosphates soluble in mineral acids BS EN 14069:2017EN 14069:2017 (E) 6 3 Terms and definitions For the purposes of this document,

38、the terms and definitions given in EN 12944-1 and EN 12944-3 apply. 4 Denominations and specifications for liming materials The denominations (type designations), specifications and elements to be declared are specified in Table 1 to Table 6 as follows: Table 1: Natural limes Table 2: Oxide and hydr

39、oxide limes of natural origin Table 3: Limes from industrial processes Table 4: Silicate limes Table 5: Mixed limes Table 6: Mixtures of liming materials with other EC fertilizer types Granulated liming materials which are produced by aggregating smaller primary particles shall break down when stirr

40、ed in water into particles with fineness distributions as specified in the type descriptions, and as measured using the method specified in EN 15704. All the properties mentioned in the Table 1 to Table 6 refer to the product as supplied unless otherwise specified. All the neutralizing requirements

41、are expressed as CaO-equivalent and as HO-equivalent in brackets. For mixed limes other than specified in Table 5, users of these products shall check the compliance of these products with the national regulations for agricultural liming materials. For products obtained by mixing, the type designati

42、on shall be completed by the list of the components with the maximum of three types. In case of mixtures of raw materials containing dolomite for common grinding, the final mixed product shall be finer than 97 % at 1,5 mm. BS EN 14069:2017EN14069:2017(E)7Table1NaturallimesType designationDataonmetho

43、dofproductionand essentialingredientsMinimum contentofnutrientsassupplied (percentagebymass)DataontheexpressionofnutrientsOtherrequirementsOtherdataonthe type designationNutrientcontenttobedeclaredassuppliedFormsandsolubilityofthenutrientsindrymatterOthercriteriatobe declaredMethodsofdeterminationLi

44、mestonestandard qualityProductormixtureofproductsofTable1containingas its essentialingredientcalcium carbonate,obtainedby grindingofnaturaldepositsoflimestoneMinimum NeutralizingValue:42asCaO(25,5asHO-)Finenessdeterminedby sieving:atleast97% topassthrougha 3,15mmsieve andat least70%to passthrough a1

45、mmsieve andatleast50% topassthrougha 0,5mm sieve.Usual trade names oralternative namesmaybe added.NeutralizingValue (EN12945)Totalcalcium (EN12946or EN13475)Totalmagnesium (optional)(EN12946orEN12947)Wet product (ifmoisturecontent2%(EN12048)Finenessdeterminedby sieving(EN12948)Reactivityandmethodof

46、determination(optional)(EN13971, EN16357, EN14984)LimestonefinequalityMinimum NeutralizingValue:50asCaO(30,3asHO-)Finenessdeterminedby sieving:atleast97%to passthrough a2mmsieve andatleast80%to passthrough a1mmsieve andatleast50% topassthrougha 0,315mmsieve andatleast30% topassthrougha 0,1mm sieve.U

47、sualtradenames oralternative namesmaybe added.BS EN 14069:2017EN14069:2017(E)8Type designationDataonmethodofproductionand essentialingredientsMinimum contentofnutrientsassupplied (percentagebymass)DataontheexpressionofnutrientsOtherrequirementsOtherdataonthe type designationNutrientcontenttobedeclar

48、edassuppliedFormsandsolubilityofthenutrientsindrymatterOthercriteriatobe declaredMethodsofdeterminationMagnesianlimestone standard qualityProductormixtureofproductsofTable1containingas its essential ingredientscalciumcarbonate andmagnesiumcarbonate, obtainedby grindingofnaturaldepositsofmagnesianlim

49、estoneMinimum NeutralizingValue:45asCaO(27,3asHO-)Totalmagnesium:3%MgOto12%MgOFinenessdeterminedby sieving:atleast97% topassthrougha 3,15mmsieve andatleast70%to passthrough a1mmsieve andatleast50% topassthrougha 0,5mm sieve.Usual trade names oralternative namesmay beadded.NeutralizingValue (EN12945)Totalcalcium (EN12946orEN13475)Totalmagnesium (EN12946or EN12947)Wet product (ifmoisturecontent2%(EN12048)Finenessdeterminedby sieving(EN12948)Reactivityandmethodof determination(optional)(EN13971, EN16357, EN14984)Magnesia