BS EN 15605-2010 Copper and copper alloys Inductively coupled plasma optical emission spectrometry《铜和铜合金 电感耦合等离子体发射光谱法》.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 15605:2010Copper and copper alloys Inductively coupled plasmaoptical emission spectrometryBS EN 15605:2010 BRITISH STANDARDNational forewordThis British Standard is the UK

2、implementation of EN 15605:2010.The UK participation in its preparation was entrusted to TechnicalCommittee NFE/34, Copper and copper alloys.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessary

3、provisions of a contract. Users are responsible for its correctapplication. BSI 2010ISBN 978 0 580 66406 9ICS 77.120.30Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee

4、 on 31 August 2010Amendments issued since publicationDate Text affectedBS EN 15605:2010EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15605 July 2010 ICS 77.120.30 Supersedes CEN/TS 15605:2007English Version Copper and copper alloys - Inductively coupled plasma optical emission spectrometry Cu

5、ivre et alliages de cuivre - Analyse par spectromtrie dmission optique avec source plasma induit par haute frquence Kupfer und Kupferlegierungen - Optische Emissionsspektrometrie mit induktiv gekoppelter Plasmaanregung This European Standard was approved by CEN on 12 June 2010. CEN members are bound

6、 to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN

7、 Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same statu

8、s as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,

9、 Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means rese

10、rved worldwide for CEN national Members. Ref. No. EN 15605:2010: EBS EN 15605:2010EN 15605:2010 (E) 2 Contents Page Foreword 31 Scope 42 Normative references 63 Principle 64 Reagents .65 Apparatus 116 Sampling 117 Procedure 117.1 Method A: Coppers . 117.2 Method B: Copper-zinc alloys . 157.3 Method

11、C: Copper-tin alloys 197.4 Method D: Copper-aluminium alloys 237.5 Method E: Copper-beryllium alloys 277.6 Method F: Copper-nickel alloys 318 Expression of results . 359 Precision 359.1 Method A Coppers . 359.2 Method B Copper-zinc alloys 369.3 Method C Copper-tin alloys 379.4 Method D Copper-alumin

12、ium alloys . 389.5 Method E Copper-beryllium alloys . 399.6 Method F Copper-nickel alloys . 4010 Test report . 40Annex A (informative) Optical emission spectrometer (OES) Suggested performance criteria to be checked 41Annex B (informative) Inductively coupled plasma emission spectrometry method for

13、the analysis of Copper-tin-lead alloys 43Bibliography . 49BS EN 15605:2010EN 15605:2010 (E) 3 Foreword This document (EN 15605:2010) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretariat of which is held by DIN. This European Standard shall be given the stat

14、us of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2011, and conflicting national standards shall be withdrawn at the latest by January 2011. Attention is drawn to the possibility that some of the elements of this document may be the sub

15、ject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TS 15605:2007. Within its programme of work, Technical Committee CEN/TC 133 requested CEN/TC 133/WG 10 “Methods of Analysis“ to revise the following Tec

16、hnical Specification: CEN/TS 15605, Copper and copper alloys Inductively coupled plasma optical emission spectrometry In comparison with the first edition of CEN/TS 15605:2007, the following significant technical changes were made: Revision from a Technical Specification to a European Standard; Meth

17、od G (specifying the analysis of Copper-tin-lead alloys) is edited under an informative basis (see An-nex B), taking into account the mediocrity of the precision criteria related to this method; Precision criteria for methods A and E were added; Precision criteria for methods B, C, D and F were impr

18、oved and up-dated. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungar

19、y, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. BS EN 15605:2010EN 15605:2010 (E) 4 1 Scope This European Standard specifies six inductively coupled plasma emission sp

20、ectrometry methods (A to F) for the determination of alloying elements and impurities in copper and copper alloys in the form of unwrought, wrought and cast products. A complementary method, for the analysis of Copper-tin-lead alloys, is described in Annex B (informative). The precision criteria con

21、cerning this method do not reach the suitable level, for all the elements specified (zinc and phosphorus, namely). These methods are applicable to the elements listed in Tables 1 to 6 within the composition ranges shown: Table 1 Coppers Element Mass fraction % min. max. Sn 0,02 0,60Pb 0,02 0,60Zn 0,

22、02 0,60 Fe 0,01 0,60Ni 0,01 0,60Mn 0,01 0,60 Al 0,02 0,60P 0,01 0,40Be 0,01 0,60 Co 0,01 0,60Cd 0,01 0,60Table 2 Copper-zinc alloys Element Mass fraction % min. max. Sn 0,05 2,00 Pb 0,03 4,00 Zn 10,00 42,00 Fe 0,01 5,00 Ni 0,02 4,00 Mn 0,01 6,00 P 0,01 0,40 Al 0,02 9,00 As 0,01 0,20 BS EN 15605:2010

23、EN 15605:2010 (E) 5 Table 3 Copper-tin alloys Element Mass fraction % min. max. Sn 3,00 16,00Pb 0,01 9,00 Zn 0,03 6,00 Fe 0,01 1,00 Ni 0,05 7,00 Mn 0,01 0,40 P 0,01 0,60 Al 0,01 0,50 Sb 0,02 1,60 As 0,02 0,25 Table 4 Copper-aluminium alloys Element Mass fraction % min. max. Sn 0,02 0,50Pb 0,03 0,50Z

24、n 0,03 1,00 Fe 0,05 7,00 Ni 0,10 8,00 Mn 0,01 5,00 Al 6,00 14,00Cd 0,01 0,50 Mg 0,002 0,15 Table 5 Copper-beryllium alloys Element Mass fraction % min. max. Sn 0,02 0,20Pb 0,01 0,20 Zn 0,03 0,20Fe 0,03 0,30 Ni 0,04 2,50Mn 0,006 0,15 Al 0,03 0,20Be 0,08 4,00 Co 0,03 4,00BS EN 15605:2010EN 15605:2010

25、(E) 6 Table 6 Copper-nickel alloys Element Mass fraction % min. max. Sn 0,10 0,50 Pb 0,03 0,50 Zn 0,04 2,00 Fe 0,10 4,00 Ni 7,00 35,00Mn 0,02 3,00 Al 0,02 0,50 NOTE 1 The ranges specified for each method can be extended or adapted, for the determination of lower mass frac-tions. NOTE 2 Other element

26、s may be included. However such elements and their mass fractions should be carefully checked, taking into account interference, sensitivity, resolution and linearity criteria for each instrument and each wave-length. 2 Normative references The following referenced documents are indispensable for th

27、e application of this document. For dated refer-ences, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 1811-1, Copper and copper alloys Selection and preparation of samples for chemical analysis Part 1: Sam

28、pling of cast unwrought products ISO 1811-2, Copper and copper alloys Selection and preparation of samples for chemical analysis Part 2: Sampling of wrought products and castings 3 Principle Dissolution of a test portion with hydrochloric and nitric acids. After suitable dilution and addition of an

29、internal reference element, nebulization of the solution into an inductively coupled plasma emission spectrometer and measurement of the intensity of the emitted light, including that of the internal reference element. 4 Reagents During the analysis, use only reagents of recognised analytical grade

30、and only distilled water or water of equivalent purity. The same reagents should be used for the preparation of calibration solutions and of sample solutions. 4.1 Hydrochloric acid, HCl ( = 1,19 g/ml) BS EN 15605:2010EN 15605:2010 (E) 7 4.2 Hydrochloric acid, solution 1 + 1 Add 500 ml of hydrochlori

31、c acid (4.1) to 500 ml of water. 4.3 Nitric acid, HNO3( = 1,40 g/ml) 4.4 Nitric acid, solution 1 + 1 Add 500 ml of nitric acid (4.3) to 500 ml of water. 4.5 Hydrofluoric acid, HF (= 1,13 g/ml) 4.6 Sulphuric acid, H2SO4(4,5 mol/l) 4.7 Electrolytic copper 4.8 Zinc granules of 99,999 % purity 4.9 Alumi

32、nium stock solution, 10 g/l Al Weigh (5 0,001) g of aluminium (Al 99,99 %) and transfer into a 600 ml beaker. Add 250 ml of hydrochloric acid solution (4.2) and cover with a watch glass. After cooling to room temperature, transfer the solution quan-titatively into a 500 ml one-mark volumetric flask,

33、 dilute to the mark with water and mix well. 1 ml of this solution contains 10 mg of Al. 4.10 Aluminium stock solution, 1 g/l Al Weigh (1 0,001) g of aluminium (Al 99,99 %) and transfer into a 400 ml beaker. Add 50 ml of hydrochloric acid solution (4.2) and cover with a watch glass. After cooling to

34、 room temperature, transfer the solution quan-titatively into a 1 000 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of Al. 4.11 Antimony stock solution, 1 g/l Sb Weigh (0,5 0,001) g of antimony (Sb 99,99 %) and transfer into a 250 ml be

35、aker. Add 50 ml of hydrochlo-ric acid (4.1) and 25 ml of nitric acid solution (4.4) and cover with a watch glass. Heat gently until the metal is dissolved. After cooling to room temperature, transfer the solution quantitatively into a 500 ml one-mark volu-metric flask, containing 100 ml of hydrochlo

36、ric acid (4.1), dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of Sb. 4.12 Arsenic stock solution, 1 g/l As Weigh (0,5 0,001) g of arsenic (As 99,99 %) and transfer into a 250 ml beaker. Add 20 ml of nitric acid solution (4.4) and cover with a watch glass. Heat gentl

37、y until the metal is dissolved. After cooling to room temperature, transfer the solution quantitatively into a 500 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of As. BS EN 15605:2010EN 15605:2010 (E) 8 4.13 Beryllium stock solution, 5

38、 g/l Be Weigh (1 0,001) g of beryllium (Be 99,99 %) and transfer into a 250 ml beaker. Add 40 ml of hydrochloric acid (4.1) and cover with a watch glass. Heat gently until the metal is dissolved. After cooling to room temperature, transfer the solution quantitatively into a 200 ml one-mark volumetri

39、c flask, dilute to the mark with water and mix well. 1 ml of this solution contains 5 mg of Be. 4.14 Beryllium stock solution, 1 g/l Be Weigh (0,5 0,001) g of beryllium (Be 99,99 %) and transfer into a 250 ml beaker. Add 20 ml of hydrochloric acid (4.1) and cover with a watch glass. Heat gently unti

40、l the metal is dissolved. After cooling to room tem-perature, transfer the solution quantitatively into a 500 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of Be. 4.15 Cadmium stock solution, 1 g/l Cd Weigh (1 0,001) g of cadmium (Cd 99

41、,99 %) and transfer into a 400 ml beaker. Add 10 ml of nitric acid (4.3) and cover with a watch glass. Heat gently until the metal is dissolved, then boil until nitrous fumes have been expelled. After cooling to room temperature, transfer the solution quantitatively into a 1 000 ml one-mark volumetr

42、ic flask, dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of Cd. 4.16 Cobalt stock solution, 5 g/l Co Weigh (1 0,001) g of cobalt (Co 99,99 %) and transfer into a 250 ml beaker. Add 10 ml of hydrochloric acid (4.1) and 10 ml of nitric acid (4.3) and cover with a watch

43、 glass. Heat gently until the metal is dissolved, then boil until nitrous fumes have been expelled. After cooling to room temperature, transfer the solution quantita-tively into a 200 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 5 mg of Co.

44、 4.17 Cobalt stock solution, 1 g/l Co Weigh (0,5 0,001) g of cobalt (Co 99,99 %) and transfer into a 250 ml beaker. Add 5 ml of hydrochloric acid (4.1) and 5 ml of nitric acid (4.3) and cover with a watch glass. Heat gently until the metal is dissolved, then boil until nitrous fumes have been expell

45、ed. After cooling to room temperature, transfer the solution quan-titatively into a 500 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 1 mg of Co. 4.18 Iron stock solution, 5 g/l Fe Weigh (5 0,001) g of iron (Fe 99,99 %) and transfer into a 4

46、00 ml beaker. Add 100 ml of hydrochloric acid (4.1) and 50 ml of nitric acid solution (4.4) and cover with a watch glass. Heat gently until the metal is dis-solved, then boil until nitrous fumes have been expelled. After cooling to room temperature, transfer the solu-tion quantitatively into a 1 000

47、 ml one-mark volumetric flask, dilute to the mark with water and mix well. 1 ml of this solution contains 5 mg of Fe. BS EN 15605:2010EN 15605:2010 (E) 9 4.19 Iron stock solution, 1 g/l Fe Weigh (1 0,001) g of iron (Fe 99,99 %) and transfer into a 250 ml beaker. Add 20 ml of hydrochloric acid (4.1)

48、and 10 ml of nitric acid solution (4.4) and cover with a watch glass. Heat gently until the metal is dis-solved, then boil until nitrous fumes have been expelled. After cooling to room temperature, transfer the solu-tion quantitatively into a 1 000 ml one-mark volumetric flask, dilute to the mark wi

49、th water and mix well. 1 ml of this solution contains 1 mg of Fe. 4.20 Lead stock solution, 5 g/l Pb Weigh (2,5 0,001) g of lead (Pb 99,99 %) and transfer into a 400 ml beaker. Add 50 ml of nitric acid solu-tion (4.4) and cover with a watch glass. Heat gently until the metal is dissolved, then boil until nitrous fumes have been expelled. After cooling