ASTM D1763-2000(2013) Standard Specification for Epoxy Resins《环氧树脂的标准规格》.pdf

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1、Designation: D1763 00 (Reapproved 2013)Standard Specification forEpoxy Resins1This standard is issued under the fixed designation D1763; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parenth

2、eses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This specification covers totally reactive epoxy resinssupplied as liqu

3、ids or solids which can be used for castings,coatings, tooling, potting, adhesives, or reinforced applica-tions. The addition of hardeners in the proper proportionscauses these resins to polymerize into infusible products. Theproperties of these products can be modified by the addition ofvarious fil

4、lers, reinforcements, extenders, plasticizers, thixo-tropic agents, etc. The epoxy resins described also can be usedas stabilizers and cross-linking agents; and they can becombined with other reactive products.1.2 It is not the function of this specification to provideengineering data or to guide th

5、e purchaser in the selection of amaterial for a specific end use. Ordinarily the properties listedin Table 1 and Table 2 are sufficient to characterize a materialunder this specification, and it is recommended that routineinspection be limited to testing for such properties.1.3 This standard does no

6、t purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.1.4 The values stated in SI units are to

7、 be regarded asstandard.NOTE 1ISO 36731:1980(E) is similar but not equivalent to thisspecification. Product classification and characterization are not the same.2. Referenced Documents2.1 ASTM Standards:2D445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids (and Calculation of Dy

8、namic Viscos-ity)D883 Terminology Relating to PlasticsD1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)D1544 Test Method for Color of Transparent Liquids (Gard-ner Color Scale)D1652 Test Method for Epoxy Content of Epoxy ResinsD3104 Test Method for Softening Point of Pitches (Mett

9、lerSoftening Point Method)D3892 Practice for Packaging/Packing of Plastics2.2 ISO Standard:3ISO 36731:1980(E) PlasticsEpoxy ResinsPart 13. Terminology3.1 Definitions:3.1.1 GeneralDefinitions of terms used in this specifica-tion are in accordance with Terminology D883.4. Classification4.1 The resins

10、covered contain no hardeners. Resin typescovered are divided into specific groups by their chemicalnature:4.1.1 Type IBisphenol A and epichlorohydrin.4.1.2 Type IIReaction product of phenol and formalde-hyde (novolac resin) and epichlorohydrin.4.1.3 Type IIICycloaliphatic and peracid epoxies.4.1.4 T

11、ype IVGlycidyl esters.4.1.5 Type VReaction product of epichlorohydrin andp-aminophenol.4.1.6 Type VIReaction product of epichlorohydrin andglyoxal tetraphenol.4.2 These types may be further subdivided by grades:4.2.1 Grade 1Resins containing no diluent.4.2.2 Grade 2Resins modified with a reactive di

12、luent.Each class of Grade 2 resin can be made from any class ofGrade 1 resin.4.2.3 Each grade may include as many classes as are shownin the tables.1This specification is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.16 on ThermosettingM

13、aterials.Current edition approved Nov. 1, 2013. Published November 2013. Originallyapproved in 1960. Last previous edition approved in 2005 as D1763 - 00(2005).DOI: 10.1520/D1763-00R13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceast

14、m.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036, http:/www.ansi.org.*A Summary of Changes section appears at the end

15、of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States15. Requirements5.1 The resin shall be of uniform quality and as free ofcontamination as can be achieved by good manufacturingpractice.5.2 The resin shall conform to the r

16、equirements prescribedin Tables 1-7 for the type, grade, and class of materialspecified.6. Sampling6.1 Take a representative sample sufficient for the testspecified either from a well-blended bulk lot prior to packagingor by withdrawing samples with a thief from no less than 5 %of the containers com

17、prising the lot or shipment.6.2 Unless the samples taken from the containers showevidence of variability, blend them into a single compositesample on which to conduct the specified tests. Instead of theforegoing, adequate statistical sampling acceptable to thepurchaser and the seller may be substitu

18、ted.7. Test Methods7.1 Determine compliance with the requirements specifiedin Table 1 in accordance with the following methods:7.1.1 ViscosityTest Method D445.7.1.2 Weight per Epoxy Equivalent(WPE)Test MethodD1652.7.1.3 ColorTest Method D1544, except for Classes IVthrough VII, where a 40 % solids so

19、lution in butyl carbitolshall be used.7.1.4 ColorTest Method D1209 is used to characterize thelow color Type I and Type III resins.7.1.5 Softening PointTest Method D3104.8. Packaging and Package Marking8.1 PackagingThe material shall be packaged in a stan-dard commercial container so constructed as

20、to protect theproduct from contamination and ensure acceptance by commonor other carriers for safe transportation at the lowest rate to thepoint of delivery, unless otherwise specified in the contract ororder.8.2 Package MarkingShipping containers shall be markedwith the name of the product and its

21、manufacturer, its type andgrade, lot or control number, and the quantity contained asdefined by the contract or order under which shipment is made.8.3 All packing, packaging, and marking provisions ofPractice D3892 shall apply to this specification.9. Keywords9.1 epoxy; resinsTABLE 1 Requirements fo

22、r Type I, Grade 1, Epoxy ResinClassEpoxy ContentViscosity, cP at 25CMettler Softening Point,CColorAGardner-Holdt,maxEquivalents/100 g WPEBAC0.500 to 0.588 170 to 200 3000 to 20 000 3B 0.443 to 0.527 190 to 226 15 000 to 40 000 5C 0.357 to 0.443 226 to 280 semi-solid 5D 0.125 to 0.357 280 to 800 40 t

23、o 90 5E 0.067 to 0.125 800 to 1500 90 to 110 5F 0.040 to 0.067 1500 to 2500 110 to 140 5G 0.017 to 0.040 2500 to 6000 134 to 180 6H 0.010 to 0.020 5000 to 10 000 160 to 200 7ATest Method D1209 with a maximum color of 100 defines low color Type I resins.BWPE = weight per epoxy equivalent.CCan exist a

24、s a supercooled liquid.TABLE 2 Requirements for Type I, Grade 2, Epoxy ResinClass Epoxy Content Viscosity, cP at 25CAA100 to 500BA500 to 900CA900 to 4000DA4000 to 10 000AThe WPE of these diluted resins shall be agreed upon between the purchaserand the seller.TABLE 3 Requirements for Type II, Grade 1

25、, Epoxy Novolac ResinsClassEpoxy ContentViscosity, cP at 25CMettler SofteningPoint, CColorA,Gardner-Holdt,maxEquivalents/100 g WPEBA 0.500 to 0.588 170 to 200 35 000 to 100 000 3B 0.537 to 0.575 174 to 186 12 000 to 19 000 7C 0.476 to 0.555 180 to 210 16 to 30C.D 0.455 to 0.525 190 to 220 4000 to 10

26、 000 at 55C 48 to 60 4E 0.333 to 0.370 270 to 300 70 to 80 9F 0.294 to 0.345 290 to 340 BDA90 to 100 10AATest Method D1209 with a maximum color of 300 defines low color Type III resins.BFifty percent solution in acetone.CForty percent in diethylene glycol mono n-butyl ether.D1763 00 (2013)2ASTM Inte

27、rnational takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely

28、 their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand sho

29、uld be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Sta

30、ndards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610

31、-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).TABLE 4 Requirements for Type III, Grade 1, Cycloaliphatic ResinsClassEpoxy C

32、ontentViscosity, cP at 25CColor, Gardner-Holdt, maxEquivalents/100 g WPEA 1.35to1.43 70to74 13max 1B 1.250 to 1.350 74 to 80 7 1C 0.98 to 1.09 91 to 102 100 at 45C 2D 0.625 to 1.000 100 to 160 80 to 500 3E 0.833 to 0.909 110 to 120 80 to 150 .F 0.699 to 0.763 131 to 143 350 to 450 1G 0.649 to 0.751

33、133 to 154 7000 to 17 000 at 38C 2H 0.465 to 0.488 205 to 216 500 to 1500 2I 0.462 to 0.487 210 to 221 500 to 1000 1J 0.238 to 0.270 370 to 420 50A.K 0.233 to 0.256 309 to 430 300 to 600 at 40C 2BL 0.232 to 0.256 390 to 430 450 at 40C 2AForty percent solution in acetone.BAt 40C.TABLE 5 Requirements

34、for Type IV, Grade 1, Glycidyl EstersClassEpoxy ContentViscosity, cP at 25CColor, Gardner-Holdt, maxEquivalents/100 g WPEAA0.790 to 0.835 120 to 130 300 to 500 6BA0.625 to 0.668 150 to 160 200 to 400 3CB0.625 to 0.668 150 to 160 1000 to 1300 5DC0.391 to 0.438 244 to 256 5 to 10 1ACycloaliphatic.BAro

35、matic.CSaturated monocarboxylic acid.TABLE 6 Requirements for Type V, Grade 1, Reaction Product of Epichlorohydrin and of p-AminophenolClassEpoxy ContentViscosity, cP at 25CColor, Gardner-Holdt, maxEquivalents/100 g WPEAB0.990 to 1.030.869 to 0.95295 to 107105 to 115550 to 8501500 to 5000.TABLE 7 Requirements for Type VI, Grade 1, Reaction Product of Epichlorohydrin and Glyoxal TetraphenolClassEpoxy ContentViscosity, cP at 25CColor, Gardner-Holdt, maxEquivalents/100 g WPEA 0.416 to 0.526 190 to 240 10A.AFifty percent solution in acetone.D1763 00 (2013)3