ASTM D1357-1995(2005) Standard Practice for Planning the Sampling of the Ambient Atmosphere《制定外围大气的取样计划的标准操作规程》.pdf

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1、Designation: D 1357 95 (Reapproved 2005)Standard Practice forPlanning the Sampling of the Ambient Atmosphere1This standard is issued under the fixed designation D 1357; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of la

2、st revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 The purpose of this practice is to present the broadconcepts of sampling the ambient air for the concentrations ofconta

3、minants. Detailed procedures are not discussed. Generalprinciples in planning a sampling program are given includingguidelines for the selection of sites and the location of the airsampling inlet.1.2 Investigations of atmospheric contaminants involve thestudy of a heterogeneous mass under uncontroll

4、ed conditions.Interpretation of the data derived from the air samplingprogram must often be based on the statistical theory ofprobability. Extreme care must be observed to obtain measure-ments over a sufficient length of time to obtain results that maybe considered representative.1.3 The variables t

5、hat may affect the contaminant concen-trations are the atmospheric stability (temperature-height pro-file), turbulence, wind speed and direction, solar radiation,precipitation, topography, emission rates, chemical reactionrates for their formation and decomposition, and the physicaland chemical prop

6、erties of the contaminant. To obtain concen-trations of gaseous contaminants in terms of weight per unitvolume, the ambient temperature and atmospheric pressure atthe location sampled must be known.1.4 This standard does not purport to address all of thesafety concerns, if any, associated with its u

7、se. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D 1356 Terminology Relating to Sampling and Analysis ofAtmospheresD 3249 P

8、ractice for General Ambient Air Analyzer Proce-duresD 3614 Guide for Laboratories Engaged in Sampling andAnalysis of Atmospheres and EmissionsNOTE 1A list of references are appended to this practice whichprovide greater details including background information, air qualitymodeling techniques, and sp

9、ecial purposes air sampling programs (1).33. Terminology3.1 DefinitionsFor definitions of terms used in this prac-tice, refer to Terminology D 1356.4. Summary of Practice4.1 This practice describes the general guidelines in plan-ning for sampling the ambient air for the concentrations ofcontaminants

10、.5. Significance and Use5.1 Since the analysis of the atmosphere is influenced byphenomena in which all factors except the method of samplingand analytical procedure are beyond the control of the inves-tigator, statistical consideration must be given to determine theadequacy of the number of samples

11、 obtained, the length of timethat the sampling program is carried out, and the number ofsites sampled. The purpose of the sampling and the character-istics of the contaminant to be measured will have an influencein determining this adequacy. Regular, or if possible, continu-ous measurements of the c

12、ontaminant with simultaneous per-tinent meteorological observations should be obtained duringall seasons of the year. Statistical techniques may then beapplied to determine the influence of the meteorologicalvariables on the concentrations measured (2).5.2 Statistical methods may be used for the int

13、erpretation ofall of the data available (2). Trends of patterns and relation-ships between variables of statistical significance may bedetected. Much of the validity of the results will depend,however, on the comprehensiveness of the analysis and thelocation and contaminant measured. For example, if

14、 24-hsamples of suspended particulate matter are obtained onlyperiodically (for example, every 6 or 8 days throughout theyear), the geometric mean of the measured concentrations isrepresentative of the median value assuming the data are lognormally distributed. The geometric mean level may be used t

15、o1This practice is under the jurisdiction of ASTM Committee D22 on Samplingand Analysis of Atmospheres and is the direct responsibility of SubcommitteeD22.03 on Ambient Atmospheres and Source Emissions.Current edition approved March 1, 2005. Published May 2005. Originallyapproved in 1955. Last previ

16、ous edition approved in 2000 as D 1357 - 95 (2000).2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The boldf

17、ace numbers in parentheses refer to the list of references at the end ofthis practice.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United Spare the air quality at different locations at which suchregular but intermittent observations of suspend

18、ed particulatematter are made.6. Basic Principles6.1 The choice of sampling techniques and measurementmethodology, the characteristics of the sites, the number ofsampling stations, and the amount of data collected all dependon the objectives of the monitoring program. These objectivesmay be one or m

19、ore of the following:6.1.1 Air quality assessment including determining maxi-mum concentration,6.1.2 Health and vegetation effects studies,6.1.3 Trend analysis,6.1.4 Evaluation of pollution abatement programs,6.1.5 Establishment of air quality criteria and standards byrelating to effects,6.1.6 Enfor

20、cement of control regulations,6.1.7 Development of air pollution control strategies,6.1.8 Activation of alert or emergency procedures,6.1.9 Land use, transportation, and energy systems plan-ning,6.1.10 Background evaluations, and6.1.11 Atmospheric chemistry studies.6.2 In order to cover all the vari

21、able meteorological condi-tions that may greatly affect the air quality in an area, airmonitoring for lengthy periods of time may be necessary tomeet most of the above objectives.6.3 The topography, demography, and micrometeorology ofthe area as well as the contaminant measured, must beconsidered in

22、 determining the number of monitoring stationsrequired in the area. Photographs and a map of the locations ofthe sampling stations is desirable in describing the samplingstation.6.4 Unless the purpose of the sampling programs is sitespecific, the sites monitored should, in general, be selected soas

23、to avoid undue influence by any local source that may causelocal elevated concentrations that are not representative of theregion to be characterized by the data.6.5 Monitoring sites for determining the impact on airquality by individual sources should be selected, if possible, soas to isolate the e

24、ffect of the source being considered. Whenthere are many sources of the contaminant in the area, the sitessampled should be strategically located so that with winddirection data obtained simultaneously near the sites, themonitoring results will provide evidence of the contributions ofthe individual

25、sources. Multiple samplers or monitors operat-ing simultaneously upwind and downwind from the source areoften very valuable and efficient.7. Meteorological Factors7.1 The meteorological parameters that are most importantin an atmospheric sampling program are:7.1.1 Wind direction and speed, the degre

26、e of persistence indirection, and gustiness;7.1.2 Temperature and its changes with height aboveground; the mixing height, that is, the height above ground thatthe pollutants will diffuse to during the afternoon; and7.1.3 Solar radiation and hours of sunshine, humidity, pre-cipitation, and barometric

27、 pressure. These parameters areimportant in assessing the pollution potential of an area andshould be considered in the planning of a monitoring programand in the interpretation of the data. Pertinent meteorologicaland climatological information may be obtained from the localweather department. In m

28、any localities, however, the microme-teorology may be unique and meteorological investigations toprovide data specific to the area may be needed.7.2 The influences of each of the meteorological parametersimportant to air quality are discussed in detail. The methods ofcarrying out the related meteoro

29、logical investigations are alsodiscussed (3, 4, 5).8. Topographical Factors8.1 Topography can influence the contaminant concentra-tions in the atmosphere. For example, a valley will causepersistence in wind directions and intensify low-level nocturnalinversions that will limit the dispersion of poll

30、utants emittedinto it. Mountains or plateaus may act as barriers affecting theflow of air as well as the contaminant concentrations in theirvicinity. Consideration should be given to the influence ofthese features as well as that of large lakes, the sea, and oceans(2, 3).9. Apparatus9.1 Details of t

31、he apparatus or instruments employed insampling the air or carrying out associated meteorologicalinvestigations are discussed in other ASTM methods andrecommendations.10. Sampling Procedure and Siting Concepts10.1 The choice of procedure for the air sampling isdependent on the contaminant to be meas

32、ured. See PracticeD 3249 for recommendations for general ambient air analyzerprocedures. ASTM recommended methods have been pub-lished for most of the common contaminants that are sampled.Automatic instruments providing a continuous record of theconcentrations of the contaminant should be utilized w

33、heneverpossible to save manpower and increase efficiency. Very oftenfactors such as temperature, humidity, and vibrations, as wellas the power line voltage can influence the output of the airmonitoring instrument and these should be controlled.10.2 The monitors must be supplied with sample air thatr

34、epresents the ambient air under investigation. Careful consid-eration should be given to the sample conveying system.Aductsystem is often utilized for this purpose. There should be as fewabrupt enlargements and elbows as possible, as these mayaffect the uniformity and hence the concentration of thec

35、ontaminants measured. The material for the duct should besuch that there will be little or no interaction between it and thecontaminants in the air sampled. Employ temperature controlto limit the condensation forming in the sampling lines. Takethe samples from straight sections of the duct with the

36、inletlead to the monitoring instrument as short as possible.10.3 The following guidelines are recommended for sam-pling locations unless site specific measurements are desired.The height of the inlet to the sampling duct should be normallyD 1357 95 (2005)2from 2.5 to 5 m above ground whenever possib

37、le. The heightof the inlet above the sampling station structure or vegetationadjacent to the station should be greater than 1 m. Samplingshould preferably be through a vertical inlet with an invertedcone over the opening. For a horizontal inlet, there should bea minimum of 2 m from the face of the s

38、tructure. For access torepresentative ambient air in the area sampled, the elevationangle from the inlet to the top of nearby buildings should beless than 30. To be representative of the area in which a largesegment of the population is exposed to contaminants emittedby automobiles, the inlet should

39、 be at a distance greater than 15m from the nearest high-volume traffic artery. Photochemicaloxidants or ozone samplers should be located at distancesgreater than 50 m from high traffic locations. Particulate mattersamplers should be sited at locations that are greater than 200m from unpaved streets

40、 or roads (6, 7, 8).11. Plan of Sampling Procedure11.1 The procedure for sampling should be undertaken inthe following steps:11.1.1 A general exploratory survey of the area includingthe topography, an inventory of sources for the contaminants,the height of their emissions, traffic, and land use data

41、.11.1.2 A preliminary meteorology analysis to identify winddirection frequencies, wind velocity, and temperature-heightprofiles.11.1.3 Exploratory short-term temporary sampling requiresa number of temporary sampling stations, to determine theneed and the best sites for extensive long term monitoring

42、.Using air quality models, and the input of emission inventoryand meteorological information for the area obtained in 11.1.1and 11.1.2, an estimate for the levels of air quality over the areamay be calculated. The model results will provide guidance indetermining the locations for monitors that will

43、 measure themaximum levels and the number of monitors required tocharacterize the air quality in the area of concern (9, 10).12. Quality Assurance12.1 Quality assurance programs include all of the activitiesnecessary to provide measurement data at a requisite precisionand accuracy. An air quality as

44、surance program should bedeveloped and implemented for every air monitoring programto ensure compatibility of data both externally and betweenstations in the monitoring network.12.2 Guidelines for quality assurance programs are given inPractice D 3614. The quality assurance program should includeall

45、 the following elements to the extent to which they areapplicable:12.2.1 Sampling and analytical procedures should be speci-fied, using standard methods such as ASTM methods whereapplicable and appropriate to the objectives to be achieved.12.2.2 Calibration procedures should be specified in thestand

46、ard methods. For a continuing program, frequency ofcalibration re-checks should be specified.12.2.3 Data collection and recording procedures should bespecified, to identify responsibility for record keeping, analysisof recorder chart records, conversion to computer format, andmethod and frequency of

47、 reporting. Specifications should alsobe included for safeguarding equipment, samples, and recordsto maintain the chain of evidence if data are required for legalpurposes.12.2.4 Sample shipping and storage procedures should bedocumented, especially if the methods used impose any limitson time delay

48、prior to analysis, refrigeration, or other storageconditions, or any other precautions in sample handling.12.2.5 Methods of computation after analysis or automaticdata recording should be specified, including data validationprocedures used to minimize errors in computation or recordkeeping.12.2.6 In

49、dependent audits of the entire measurement pro-gram by an outside agency are helpful, in which parallelsampling and analysis is conducted independently to verify theprecision and accuracy of the final results. Simultaneousanalysis of ambient atmospheres can be used, as well asindependent measurements using cylinder gases or other cali-bration standards.12.2.7 Interlaboratory tests (also called “round-robin” tests)are useful as a means of confirming the precision and accuracyof the methods used, and also make it possible for eachorganization to check its own performance agai