ASHRAE IJHVAC 15-5-2009 HVAC&R Research《《HVAC&R研究》》.pdf
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1、 VOLUME 15, NUMBER 5 HVAC they no longer need to rely solely on a self-appointed technical elite to provide policy advice on technical issues. So what is the role of American Society of Heating, Refrigerating and Air-Conditioning Engi-neers, Inc. (ASHRAE) in this brave new world? Like other professi
2、onal societies, ASHRAE develops consensus standards based on more detailed technical handbooks that are continuously updated and vetted by researchers and expert practitioners at semiannual meetings of the mem-bership. No matter what means are available for handling information in the future, this w
3、ill remain an important domain and function of professional societies. And, in the case of ASHRAE, there is a unique capability. ASHRAE is perhaps the only professional society that raises funds for and manages its own research projects that foster the understanding of science and technology support
4、ing HVAC.Established nearly a century ago, the ASHRAE research program has played a vital role in the development of materials incorporated in the ASHRAE Handbooks, design guidelines, and stan-dards. The societys $2.5 million/year investment is augmented by matching funds from others, and guided by
5、the Research Strategic Plan which is periodically updated by the members. The Clark Bullard is a professor emeritus in the Department of Mechanical Science and Engineering at the University of Illinois at Urbana-Champaign, Urbana, IL. Jelena Srebric is an associate professor in the Department of Arc
6、hitectural Engineering at Pennsylvania State University, University Park, PA. Reinhard Radermacher is a professor in the De-partment of Mechanical Engineering and director of the Center for Environmental Energy, University of Maryland, Col-lege Park, MD. 2009, American Society of Heating, Refrigerat
7、ing and Air-Conditioning Engineers, Inc. (www.ashrae.org). Published in HVAC accepted February 20, 2009This paper proposes a method for establishing improved guidelines regarding the use of refriger-ant blends that contain a flammable component. This approach was verified in a test chamber under rea
8、listic refrigerating equipment leak scenarios. First, the paper provides an overview of the safety classification described in ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants (ASHRAE 2007) and its international equivalent ISO Standard 817-2006, RefrigerantsDesigna
9、tion and Safety Classification (ISO 2006). The refrigerant blends examined were A1, as formulated, and A2, at the “worst-case fractionated formulation,” as defined by ASHRAE Standard 34-2007. The blend is prepared in a cylinder and is then slowly leaked inside a test chamber of 1 m3(35.31 ft3). At t
10、he beginning of the leak, the gas phase occu-pies 10% of the cylinder volume, corresponding to one of the leak scenarios featured in ISO Stan-dard 817-2006. The concentrations inside the test chamber are measured by gas chromatography. In addition, this paper provides the algorithm of calculation of
11、 a computer code named Room_leak, which simulates leaks of any refrigerant blends in realistic scenarios.BACKGROUNDNew hydrofluorocarbon (HFC) refrigerants have been developed to stop the production of ozone depleting refrigerants such as chlorofluorocarbons and hydrochlorofluorocarbons. The develop
12、ment of new low global warming potential (GWP) refrigerants are necessary to limit radiative forcing of most of the HFCs developed since 1990. The compromise among energy efficiency, GWP, and flammability is difficult to establish for many applications, and the use of mildly flammable refrigerant ha
13、s to be carefully analyzed to increase the number of choices when it comes to refrigerants. It may be possible to reduce the GWP of refrigerant blends by allowing the use of larger quantities of flammable, low GWP refrigerant ingredients, as long as this can be done without increasing the flammabili
14、ty risk associated with the refrigerant.ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants (ASHRAE 2007) and its Appendix B, as well as its international equivalent ISO Standard 817-2006, RefrigerantsDesignation and Safety Classification (ISO 2006), define safety cri
15、teria for toxicity and flammability limits of refrigerants. Several definitions that are essential to this discussion are provided in the Annex at the end of this paper. Because of the worst-case frac-tionated formulation (WCFF) some refrigerant blends are classified as mildly flammable only for the
16、 worst-case fractionation, while others are nonflammable as initially formulated, even when taking into account the worst case formulation (WCF). ISO Standard 817-2006 utilizes a dual classification system, which classifies the blends as 1/2, 1 (for the WCF), and 2 (for the Dennis Clodic is director
17、 of research and laboratory manager and Youssef Riachi is project leader at the Center for En-ergy and Processes, MINES Paris Tech, Paris, France. 2009, American Society of Heating, Refrigerating and Air-Conditioning Engineers, Inc. (www.ashrae.org). Published in HVAC 0.7812/0.2096/0.0092) at stan-d
18、ard conditions (101.325 kPa and 25C 14.69 psi and 77F), the air and refrigerant masses, mole numbers, and concentrations inside the test chamber are recalculated at each time-step along the leak process. These concentrations vary depending upon the remaining components in the cylinder. This step of
19、the program is the very different compared to step seven in the REFLEAK VERSION 3.1: NIST Leak/Recharge Simulation Program for Refrigerant Mix-tures Database (NIST 2005).8. The mass of refrigerants remaining in the cylinder is the difference between the initial mass of each component and the mass of
20、 each component that has leaked at a given time step. The remaining mass of refrigerants inside the cylinder are then taken as initial masses and calcu-lations continue until there is no liquid remaining in the cylinder. When the vapor volume quality ( ) is larger than 0.999 the calculation stops. F
21、igure 1 summarizes the algorithm to calculate concentration changes over time.Simulation ResultsConsidering a 10 105m3(0.006 ft3) cylinder that was evacuated (10 Pa abs 14.5 104psia) and then filled with 90 g (0.198 lb) of R-134a and 75 g (0.165 lb) of R-32, the mass concentration of R-134a was 54.5
22、% (45.5% of R-32). The refrigerant blend leaking from the cylinder in the vapor phase was released inside the 1 m3(35.31 ft3) test chamber initially filled with air at standard conditions.The test chamber was assumed to be air tight. A 1 g (2.2 103lb) leak sample was removed during the vapor phase a
23、t each sampling step. Calculations ended when the vapor volumetric quality in the cylinder were larger than 99.9%. The initial mass filled was 165 g (0.364 lb). At the end of the leak process, 7 g (0.016 lb) of the vapor phase remained in the cylinder. So, the entire mass leaked from the cylinder an
24、d released into the test chamber was 158 g (0.348 lb), which can be seen in Figure 2. The overall molar and mass concentrations inside the cylinder along the leak process are also shown in Figure 2. At the beginning of the leak, the vapor phase showed the highest concentration of R-32, which then co
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