UOP 930-2007 Chloride in LPG and Gaseous Hydrocarbons by Dry Colorimetry.pdf
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1、 IT IS THE USERS RESPONSIBILITY TO ESTABLISH APPROPRIATE PRECAUTIONARY PRACTICES AND TO DETERMINE THE APPLICABILITY OF REGULATORY LIMITATIONS PRIOR TO USE. EFFECTIVE HEALTH AND SAFETY PRACTICES ARE TO BE FOLLOWED WHEN UTILIZING THIS PROCEDURE. FAILURE TO UTILIZE THIS PROCEDURE IN THE MANNER PRESCRIB
2、ED HEREIN CAN BE HAZARDOUS. MATERIAL SAFETY DATA SHEETS (MSDS) OR EXPERIMENTAL MATERIAL SAFETY DATA SHEETS (EMSDS) FOR ALL OF THE MATERIALS USED IN THIS PROCEDURE SHOULD BE REVIEWED FOR SELECTION OF THE APPROPRIATE PERSONAL PROTECTION EQUIPMENT (PPE). COPYRIGHT 2006, 2007 UOP LLC. All rights reserve
3、d. Nonconfidential UOP Methods are available from ASTM International, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA 19428-2959, USA. The UOP Methods may be obtained through the ASTM website, www.astm.org, or by contacting Customer Service at serviceastm.org, 610.832.9555 FAX, or 610.83
4、2.9585 PHONE. Chloride in LPG and Gaseous Hydrocarbons by Dry Colorimetry UOP Method 930-07 Scope This method is for determining the sum of organic chloride and hydrogen chloride (HCl) in liquefied petroleum gas (LPG) and refinery gas streams at concentrations ranging from approximately 0.02 to 1000
5、 mass-ppm (mg/kg) for LPG samples or 0.02 to 1000 ng/mL for gas samples. Other halogens present are determined as chloride. References ASTM Practice D 1265, “Sampling Liquefied Petroleum (LP) Gases (Manual Method),” www.astm.org ASTM Method D 1657, “Density or Relative Density of Light Hydrocarbons
6、by Pressure Hydrometer,” www.astm.org ASTM Method D 2421, “Interconversion of Analysis of C5and Lighter Hydrocarbons to Gas-Volume, Liquid-Volume, or Mass Basis,” www.astm.org ASTM Method D 2598, “Calculation of Certain Physical Properties of Liquefied Petroleum (LP) Gases from Compositional Analysi
7、s,” www.astm.org ASTM Practice D 3700, “Obtaining LPG Samples Using a Floating Piston Cylinder,” www.astm.org ASTM Practice D 5287, “Automatic Sampling of Gaseous Fuels,” www.astm.org ASTM Method D 6849, “Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods,” w
8、ww.astm.org Instrument instruction manual, CI Analytics, PN 2010-Cl-man UOP Method 516, “Sampling of Gasolines, Distillate Fuels and C3- C4Fractions,” www.astm.org UOP Method 539, “Refinery Gas Analysis by Gas Chromatography,” www.astm.org UOP Method 999, “Precision Statements in UOP Methods,” www.a
9、stm.org 2 of 6 930-07 Outline of Method A commercial chloride analyzer utilizing dry colorimetric detection is set up according to the manufacturers specifications. The sample is subjected to pyrolysis during which the organic chlorides are converted to HCl. The pyrolysis product is then passed to a
10、 detector where the HCl produces a color change on sensitized paper. The measured color change is proportional to the quantity of chloride in the sample. Calibration is by blends for LPG samples and permeation tubes for gas samples. Apparatus References to catalog numbers and suppliers are included
11、as a convenience to the method user. Other suppliers may be used. Chloride analyzer, with Dry Colorimetric Detector (DCD), Gas/LPG Introduction Module, and AccuGas Blend Generator (PN 096) , C.I. Analytics, Model 2010L Cylinder, gas sampling, stainless steel, internally coated with Teflon, Siltek, S
12、ulfinert, or other similar inert coating, 500- or 1000-mL, Restek, Cat. No. 24133 or 24144, with valve Cat. No. 24100 and valve with rupture disk Cat. No. 21403, several required Cylinder, LPG sampling, stainless steel, internally coated with Teflon, Siltek, Sulfinert, or other similar inert coating
13、, 500- or 1000-mL, with outage tube, Restek, Cat. No. 24133 or 24144, with valve with outage tube Cat. No. 21402 (specify %-outage, e.g., 30%) and valve with rupture disk Cat. No. 21403, several required Fittings, tube, as needed for connecting gases and sample cylinders to instrument, local supply
14、or Swagelok Gauge, test, pressure, 0 to 2760 kPa gauge (0 to 400 psig), Matheson Tri-Gas, Cat. No. 63-5642 Regulator, air, two-stage, high purity, with stainless steel diaphragm, delivery pressure range 30-700 kPa (4-100 psi), Matheson Tri-Gas, Cat. No. 3122-590 Regulator, nitrogen, two-stage, high
15、purity, with stainless steel diaphragm, delivery pressure range 30-700 kPa (4-100 psi), Matheson Tri-Gas Cat. No. 3122-580 Regulator, nitrogen, two-stage, high purity, with stainless steel diaphragm, delivery pressure range 70-1700 kPa (10-250 psi), Matheson Tri-Gas Cat. No. 3126-580, if needed to p
16、ressurize an LPG sample Regulator, oxygen, two-stage, high purity, with stainless steel diaphragm, delivery pressure range 30-700 kPa (4-100 psi), Matheson Tri-Gas, Cat. No. 3122-540 Tubing, 316 stainless steel, 3.18-mm OD (1/8-inch) x 2.16-mm ID (0.085-inch), Alltech Associates, Cat. No. 30105 Reag
17、ents and Materials References to catalog numbers and suppliers are included as a convenience to the method user. Other suppliers may be used. Air, compressed gas, 99.99% minimum purity Nitrogen, compressed gas, 99.99% minimum purity 3 of 6 930-07 Oxygen, compressed gas, 99.99% minimum purity Calibra
18、tion blends, certified, LPG, 0.5- and 50-mass-ppm (as chloride) 2-chlorobutane in isobutane, Matheson Tri-Gas. Adjust concentrations and components to fit typical samples. Reference blank, gas or LPG, less than 10 ppb chloride Permeation devices, for gas-phase calibration; select one or more from: 1
19、,2-Dichloropropane, C.I. Analytics, Cat. No. PN-per-cl2-003a 1,1,1-Trichloroethane, C.I. Analytics, Cat. No. PN-per-cl2-002a 1,1,2-Trichloroethane, C.I. Analytics, Cat. No. PN-per-cl2-002b 1,1,2-Trichloroethylene, C.I. Analytics, Cat. No. PN-per-cl2-002aa 1,2,3-Trichloropropane, C.I. Analytics, Cat.
20、 No. PN-per-cl2-003c Purifiers, compressed gas, removes hydrocarbons and moisture, Alltech, Cat. No. 81350, three required Procedure The analyst is expected to be familiar with general laboratory practices and with the equipment being used. Preparation of Apparatus Install the analyzer as recommende
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