REG NASA-LLIS-0439--1996 Lessons Learned - Avoid Use of PFPE-based Lubricant on Moving Surfaces of Titanium (or Other Highly Reactive Metal) Bearings (1993).pdf
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1、Lessons Learned Entry: 0439Lesson Info:a71 Lesson Number: 0439a71 Lesson Date: 1996-07-19a71 Submitting Organization: JPLa71 Submitted by: D. OberhettingerSubject: Avoid Use of PFPE-based Lubricant on Moving Surfaces of Titanium (or Other Highly Reactive Metal) Bearings (1993) Abstract: A rotating p
2、rism motor aboard the TOPEX spacecraft experienced a sudden in-flight failure due to the use of perfluoropolyalkyether (PFPE) based lubricant on titanium bearings. Pure titanium debris produced by spalling of the motor shaft chemically reacted with the fluorocarbon-based lubricant, causing polymeriz
3、ation of the lubricant. Avoid the use of PFPE-based lubricants on titanium or other highly reactive bearing surfaces.Description of Driving Event: Following an April 1993 in-flight failure of an Upper Atmosphere Research Satellite (UARS) Earth Sensor Assembly (ESA), the vulnerability of identical ES
4、As aboard the TOPEX spacecraft was investigated. UARS experienced a sudden in-flight failure of the ESA rotating prism motor attributed to the use of perfluoropolyalkyether (PFPE) based lubricant on titanium bearings. Pure titanium debris produced by spalling of the motor shaft chemically reacted wi
5、th the fluorocarbon-based lubricant, causing polymerization of the lubricant. In the presence of debris, bearing race-to-ball friction produces enough heat for the titanium to react with the lubricant, given that titanium is very reactive when exposed. The degradation mechanism consists of two steps
6、: (1) the reaction of PFPE molecules with freshly exposed titanium particles to form an acid followed by (2) the reaction of the acid with unreacted PFPE molecules, resulting in cleavage of their molecular bonds. This failure mechanism was confirmed in a life test performed by GSFC on a spare UARS E
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