1、MILITARY SPECIFICATION PASSIVATOR COMPOUND, NAVY BOILER This specification is approved for use within the Naval Sea Systems Command, Department of the Navy, and is available for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers a uniform
2、mixture containing essentially dust free, granular sodium nitrite, monosodium phosphate and disodium phosphate. No other materials shall be incorporated into the pass ivator . 2, APPLICABLE DOCUMENTS 2.1 Government documents. 2.1.1 Specification and standards. The following specification and standar
3、ds form a part of this specification to the extent specified herein. Unless otherwise specified, the issues of these documents shall be those listed in the issue of the Department of Defense Index of Specifications and Standards (DoDISS) and the supplement thereto, cited in the solicitation. SPECIFI
4、CATION FEDERAL PPP-D-723 - Drums, Fiber. STANDARDS FEDERAL FED-STD-313 - Material Safety Data Sheets Preparation and the Submission of. r I Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be addressed to: Comman
5、der, Naval Sea Systems Command, SEA 5523, Department of the Navy, Washington, DC 20362-5101 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. AMSC N/A FSC 6850 DISTRIBUTION STATEMENT A Approved for public rele
6、ase; distribution unlimited THIS DOCUMENT CONTAINS q- - PAGES. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,- I IfIL-P-24138A (SH) NILITARY NIL-STD-105 - Sampling Procedures and Tables for Inspection by NIL-STD-129 - Narking for Shipment and Storag
7、e. MIL-STD-147 - Palletized Unit Loads. Attributes. 2.1.2 Other Government documents. The following other Government documents Unless other- forms a part of this specification to the extent specified herein. wise specified, the issue shall be those in effect on the date of the solici- tation. DEPART
8、MENT OF LABOR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) Code of Federal Regulations (CFR) 29 CFR, Part 1910.1200 - Hazard Communication Standard. DEPARTMENT OF TRANSPORTATION (DOT) Code of Federal Regulations (CFR) 49 CFR, Parts 170-179 - Hazardous Material Regulations. NAVAL SEA SYSTEMS
9、COMElAND (NAVSEA) S9086-T8-STM-000 - Naval Ships Technical Manual, Chapter 593, Pollution Control. (The Code of Federal Regulations (CFR) and the Federal Register (FR) are for sale on a subscription basis by the Superintendent of Documents, U.S. Government Printing Office, Washington, DC 20402. When
10、 indicated, reprints of certain regulations may be obtained from the Federal agency responsible for issuance thereof.) (Copies of specifications, standards, and other Government documents required by contractors in connection with specific acquisition functions should bo.obtained from the contractin
11、g activity or as directed by the contracting activity. ) 2.2 Other publication. The following document forms a part of this specification to the extent specified herein. issues of the documents which are DoD adopted shall be those listed in the issue of the DoDISS specified in the solicitation. Unle
12、ss otherwise specified, tho issues of documents not listed in the DoDISS shall be the issue of the non- government documents which is current on the date of the solicitation. Unless otherwise specified, the AEIERICAN CHEMICAL SOCIETY (ACS) Specifications, Reagent Chemicals. (Application for copies s
13、hould be addressed to the American Chemical Society, 1155 16th Street NW, Washington, DC 20036.) (Nongovernment standards and other publications are normally available from the organizations which prepare or which distribute the documents. These documents also may be available in or through librarie
14、s or other informational cervices, ) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-fl.IL-P-24L38A 68 m 7799706 OLL8473 2 m 2.3 Order of precedence. In the event of a conflict between the text of this specification and the references cited herein (e
15、xcept for associated detail specifications, specification sheets or MS standards), the text of this specification shall take precedence. Nothing in this specification, however, shall supersede applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 Composit
16、ion. The nominal composition of the passivator is 50 percent sodium nitrite (NaN02), 25 percent monosodium phosphate (NaH2P04.H20) and 25 percent disodium phosphate (Na2H?Ok), 3.1.1 Sodium nitrite. The sodium nitrite used in the passivator shall have an assay of not less than 97 percent. The passiva
17、tor shall contain not less than 44.0 percent nor more than 54.0 percent sodium nitrite when tested as specified in 4.3.1. 3.1.2 pH. The pH shall be 6.6 k 0.3 when tested as specified in 4.3.2. 3.1.3 Total phosphoric anhydride (P205). The total phosphoric anhydride (P206) shall be not less than 24.7
18、percent nor more than 25.7 percent when tested as specified in 4.3.3. 3.1.4 Insoluble matter. The insoluble matter shall be not more than 0.25 percent when tested as specified in 4.3.4. 3.2 Material safety data sheet. The contracting activity shall be provided a material safety data sheet (MSDS) at
19、the time of contract award. The MSDS shall be provided in accordance with the requirements of FED-STD-313 and 29 CFR 1910.1200, Hazard Communication. When FED-STD-313 is at variance with the CFR, 29 CFR 1910.1200 shall take precedence, modify and supplement FED-STD-313. The MSDS shall be included wi
20、th each shipment of the material covered by this specification (see 6.3). 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the contractor is responsible for the performance of all inspection requirements as specified her
21、ein. Except as otherwise speci- fied in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by the Government. The Government reserves the right to perform any of the i
22、nspections set forth in the specification where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. 4.1.1 Responsibility for compliance. All items must meet all requirements of sections 3 and 5. a part of the contractors overall inspection system
23、 or quality program. The absence of any inspection requirements in the specification shall not relieve the contractor of the responsibility of assuring that all products or supplies submitted to the Government for acceptance comply with all requirements of the The inspection set forth in this specif
24、ication shall become 3 7. I Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-WIL-P-24138A( SH) contract. Sampling in quality conformance does not authorize submission of known defective material, either indicated or actual, nor does it commit the Gove
25、rnment to acceptance of defective material. 4.2 Quality conformance inspection. 4.2.1 E. A lot shall consist of not more than 20,000 pounds of passi- vator, or 1 days production, whichever is smaller, 4.2.2 Examination of filled containers. A random sample of filled containers, taken from each lot i
26、n accordance with MIL-STD-105 at inspection level I and acceptable quality level of 2.5 percent defective, shall be examined to verify compliance with all stipulations of this specification regarding fill, closure, marking and any other requirements not involving tests. for evidence of leakage and f
27、or unsatisfactory markings. Each sample-filled container shall be weighed to determine the amount of contents. in the sample having one or more defects or under required fill shall not be offered for delivery. exceeds the acceptance number for the appropriate sampling plan of MIL-STD-105, this shall
28、 be cause for rejection of the lot represented by the sample. Samples shall be examined for defects of the container and closure, Any container If the number of defective containers in any sample 4.2.3 Sampling procedure for tests. Two filled containers shall be ran- domly selected from each lot and
29、 a 1-pound sample shall be taken from each container, The samples shall not be mixed. Samples shall be marked with the lot number sind date of sampling, and shall be subjected individually to the tests specified in 4.3. In addition, representative samples of the ingredients used in fulfilling each c
30、ontract or order shall be taken as follows: each of sodium nitrite (NaN2), monosodium phosphate (NaH2P04.H20) and disodium phosphate (Na2HP04) placed in individual containers and marked with a lot number and date sampled. These ingredients shall be used in the eve.nt that additional testing for Conf
31、irmation of composition or quality becomes necessary. 1-pound 4.2.4 Tests. The two samples from each lot selected (see 4.2.3) shall Where be subjected individually to the tests specified. Analytical reagent grade chemicals and reagent grade water shall be used throughout the tests. applicable, the r
32、eagents shall meet the requirements of the American Chemical Society specifications. 4.3 Test proceduxes. 4.3.1 Sodium nitrite. Sodium nitrite shall be tested as follows. 4.3.1.1 Reagents, (a) Sulfamic acid, purified - The sulfamic acid shall be purified as follows: Dissolve 125 grams of sulfamic ac
33、id in 300 grams of water previously heated to 70 degrees Celsius (OC). Filter three times. With consequent lowering of the temperature, discard the material which crystalllzes from the solution. Cool the filtrate rapidly in an ice-salt mixture and let stand for 20 minutes. Remove the crystals thus f
34、ormed by suction filtration. Wash the crystals with a small portion of ice 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-24L38A 68 7979906 Oll8475 b MIL-P-24138A (SH) water, then twice with cold ethanol, and finally with ether. Air dry for
35、1 hour, grind in an agate mortar and store in a desiccator . (b) Sulfuric acid - 50 percent by volume. (c) Potassium bromide - Saturated solution. 4.3.1.2 Apparatus. pH meter, laboratory type with millivolt and polarizing current Silver billet electrode. Platinum electrode. Buret, 50-milliliter (mL)
36、 capacity graduated in 0.1-mL capability. divisions, with delivery error no greater than plus or minus 0.05 mL. Volumetric flask, 1000-mL capacity. Magnetic stirrer. Magnetic stirring bar. Beaker, 400-mL capacity. Ice-water bath. 4.3.1.3 Procedure. Dissolve to a 20-gram sample of the passivator (wei
37、ghed to the nearest milligram) in 700 to 800 mL of distilled water (pH of 6.6 to 7.2) in a 1000-mL volumetric flask. mix. Transfer the sulfamic acid to a 400-mL beaker and dissolve in 100 mL of cool water (25OC or less). Add 15 mL of the potassium bromide solution. Cool to 15OC in an ice water bath.
38、 Cool the sulfuric acid solution in the ice water bath. Connect the silver billet electrode with a polarizing jumper to the input jack of the pH meter. Connect the platinum electrode to the reference jack. Set the pH meter to read millivolts. of the sulfuric acid solution to the sulfamic acid soluti
39、on. solution by means of the magnetic stirrer and stirring bar. active surfaces of the electrodes in the acid solution. Titrate the sulfamic acid solution with the passivator sample solution, with the buret delivery tip just below the surface of the sulfamic acid solution. shall be taken as the poin
40、t at which further additions of the titrant (passivator sample solution) will not cause any additional surge in the millivolt reading. Calculate as follows: Dilute to the mark and Accurately weigh a 0,500-gram portion of the purified sulfamic acid. Connect meter to power supply. Add 25 mL Agitate th
41、e acid Immerse the The equivalence point Percent sodium nitrite = 71130 W2 - w1 v Where: WL = Weight in grams of passivator sample. W2 = Weight in grams of sulfamic acid. V = Volume of titrant (passivator sample solution), mL. 4.3.2 pH. pH shall be tested as follows. 4.3.2.1 Reagents. (a) Distilled
42、water, pH of 6.6 to 7.2. (b) Standard buffer solution, pH of 7.0 at 25OC. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-_ _ - - MIL-P-IIJA b iLq77770b OLL8476 8 llIL-P-2413A(SH) (a) pH meter, laboratory type. (b) Glass electrode. (c) Calomel electr
43、ude. (d) Pipet, 25-mL delivery. (e) Volumetric flask, 200-mE capacity. (f) Thermometer. (8) Beaker, 15-mL capacity. 4.3.2.3 Procedure, Transfer a 25-mL aliquot of the passivator sample solution prepared as specified in 4.3.1.3 to a 200-mL volumetric flask. Diliite to the mark with distilled water an
44、d mix. mL of the solution to a 1S-mL beaker, 7.0 standard buffer solution. at 2OC with the pH meter. Transfer approximately 100 Standardize the pH meter with the pH Measure the pH of the diluted sample solution 4.3,3 Total phosphoric anyhydride (P205). 4.3.3.1 Reagents. (a) Magnesia mixture. Dissolv
45、e 55 grams of MgC12.6H20 and 110 grams of NH4C1 in 500 mL of water. with “,+OH and let stand overnight. Filter off any precipitate. Acidify with HCl and dilute to 1 liter in a glass-stoppered bottle. Make distinctly ammoniacal (b) Ammonium hydroxide (l:l), SO percent by volume. (c) Ammonium hydroxid
46、e (1:19), 5 percent by volume. (d) Hydrochloric acid (l:l)j 50 percent by volume. (e) Hydrochloric acid (1:19), 5 percent by volume. 4.3.3.2 Apparatus. (a) Pipet, 25-mL delivery. (b) Beaker, 400-mL capacity. (c) Gooch crucible, porcelain, Coors, No. 3, or equal. 4.3.3.3 Procedure. Transfer a 25-mL a
47、liquot of the passivator sample solution as prepared in 4.3.1.3 to a 400-mL beaker. acid (1:l). Cool and add 40 mL of magnesia mixture. Add ammonium hydroxide (1:l) dropwisa with constant stirring until precipitation starts. Let stand 16, minutes. Add 10 mL of ammonium hydroxide (1:l) per 100 mL of
48、solution, while stirring gently. Allow to stand overnight. Filter through a No. 42 Whatman filter paper, or equal, without attempting to transfer the precipitate to the paper, Wash the residue by decaptation and the filter paper a few times with ammonium hydroxide (1:19). paper with 30 mL of hydroch
49、loric acid (l:l), catching the solution in the original beaker. Wach the filter paper thoroughly with hydrochloric acid (1:19). Dilute the solution to 100 mL and add 2 to 4 mL of magnesia mixture. Add ammonium hydroxide (1:l) dropwise, stirring until precipitation starts. Lot stand 15 minutes. Add ammonium hydroxide (1:l) to 10 percent of excess. Allow the precipitate to settle. Filter on a pre-ignited and weighed Gooch crucible with a glass fiber filter disc, em
