1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions 2006 08 31 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.3, 3.26 & 4 1995 02 28 Released L. Gullen Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 1 of 6 HOSE, NON-REINFORCED RUBBER, FUEL/ALCOHOL RESISTANT WSL-M
2、96D33-A4 CONDUCTIVE, LOW PERMEATING 1. SCOPE This specification defines a non-reinforced barrier layer hose with good resistance to fuel/alcohol blends and low permeation. 2. APPLICATION This specification was released originally for fuel tank filler and vent hoses. 3. REQUIREMENTS 3.0 STANDARD REQU
3、IREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.4 HOSE CONSTRUCTION The hose shall consist of a smooth bore THV tube, acting as a fuel barrier layer and a epichlorohydrin cover. 3.
4、5 PHYSICAL PROPERTIES The following tests, where possible, shall be performed on finished hoses and/or test specimens cut from them in accordance with ASTM D 3183 (cutting knife procedure preferred). Greater variation in test values can be anticipated when evaluating materials that are thinner than
5、recommended by an applicable Industry Standard/Test Method. 3.6 ORIGINAL PROPERTIES Barrier Cover 3.6.1 Hardness, International 85 95 65 - 75 (ISO 48/ASTM D 1415, micro) 3.6.2 Hardness, Durometer A 85 95 65 - 75 (ISO 868/ASTM D 2240, instantaneous, plied-up specimen. Hand held durometers shall not b
6、e used) 3.6.3 Tensile Strength, MPa, min 12.0 10.0 (ISO 37/ASTM D 412, Die C) 3.6.4 Elongation at Break, %, min 400 250 (ISO 37/ASTM D 412, Die C) ENGINEERING MATERIAL SPECIFICATION WSL-M96D33-A4 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 2 of 6 Barrier Cover
7、3.6.5 Modulus at 100% Elongation, MPa, min 6.0 2.5 (ISO 37/ASTM D 412, Die C) 3.7 HEAT AGED (ISO 188/ASTM D 573, 150 +/- 50 air changes/h, 168 h at 125 C) Hardness Change, max +10 +15 Tensile Strength Change, %, max -35 -10 Elongation Change, %, max -15 -60 3.8 HEAT AGED (ISO 188/ASTM D 573, 150 +/-
8、 50 air changes/h, 1000 h at 100 C) Hardness Change, max +10 +20 Tensile Strength Change, %, max -40 +15 Elongation Change, %, max -20 -60 3.9 IMMERSION IN FUEL C (ISO 1817/ASTM D 471, 70 h at 23 +/- 2 C) Hardness Change, max -10 -25 Tensile Strength Change, %, max -25 -30 Elongation Change, %, max
9、-15 -40 Volume Change, %, max +10 +30 3.9.1 Dry Out (24 h at 70 +/- 2 C) Hardness Change, max +10 +25 Volume Change, %, max -5 -15 (Use specimens from para 3.7) 3.10 IMMERSION IN 75% FUEL C + 25% METHANOL (ISO 1817/ASTM D 471, 70 h at +/- 2 C) Hardness Change, max -10 -25 Tensile Strength Change, %,
10、 max -30 -40 Elongation Change, %, max -15 -50 Volume Change, %, max +10 +75 ENGINEERING MATERIAL SPECIFICATION WSL-M96D33-A4 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 3 of 6 3.10.1 Dry Out (24 h at 70 +/- 2 C) Hardness Change, max +10 +25 Volume Change, %, m
11、ax -10 -20 (Use specimens from 3.8) 3.11 BURST PRESSURE, min (ASTM D 380) Hose Size, mm Burst Pressure (Approximate I.D.) MPa Below 9.53 1.02 9.53 - 15.87 0.68 15.87 and larger 0.34 3.12 STATIC ELECTRICAL RESISTANCE, max 5 megaohms (Test method tbd, measured over the length of the part) 3.13 VACUUM
12、COLLAPSE, max 20% Test Method: The hose shall be subjected to a vacuum of 68 kPa while bent over a mandrel having a diameter of 10 times the nominal O.D. of the hose for a duration of 24 h at 100 +/- 2 C. The outside diameter shall not be less than 90% of the original. This requirement shall not app
13、ly to sizes larger than 15.87 nominal I.D. 3.14 COLD FLEXIBILITY, Hose No cracks or breaks Test Method: A 450 mm length of hose filled with Fuel C shall be aged for 70 h at 23 C. After aging, the hose shall be drained. Then, hose together with a mandrel having a diameter 10 times the nominal O.D. wi
14、ll be conditioned for 70 h at -40 C. The conditioned hose shall show no signs of cracking or disintegration when bent 180 over the mandrel. This flexing shall be accomplished within four seconds. For straight hose over 17.28 mm I.D. and all preformed hoses, prepare strips from the Fuel C aged hose 1
15、3 mm wide with length to be equal to the developed length of the part. Condition the strips and a 130 +/- 3 mm mandrel for 70 h at -40 C. Bend the strips over the mandrel and examine for cracking. 3.15 HIGH TEMPERATURE RESISTANCE No cracks Test Method: Prepare for oven aging a piece of hose bent int
16、o a free loop (approx 250 mm diameter) until the ends meet. For straight hose over 19.05 mm I.D. and all preformed hoses prepare strips of hose 13 mm wide with length to be equal to the developed length of the part. Age hose or test specimens in an air circulating oven for 70 h at 124 +/- 2 C. At th
17、e end of the aging period examine for cracks, restraighten and/or re-loop and examine again noting all conditions. No signs of cracking are permitted when examined with a 7X power glass. 3.16 OZONE RESISTANCE, Cover Rating 0 Test Method: FLTM BP 101-01, Procedure B, after the following sequence: . I
18、mmerse in Fuel C for 48 h at 23 +/- 2 C . Air dry for 70 h at 23 +/- 2 C . Elongate 20% ENGINEERING MATERIAL SPECIFICATION WSL-M96D33-A4 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 4 of 6 3.17 OVALITY, min 75% (Not applicable to hoses with I.D. greater than 16.
19、28 mm, unless otherwise specified on engineering drawing) I.D. minimum Ovality = _ x 100 I.D. maximum 3.18 FLAMMABILITY, Cover Self extinguishing (ISO 3795) in 1 minute 3.19 FUEL PERMEABILITY RESISTANCE, 75% FUEL C/25% METHANOL (FLTM BP 114-02, fuel permeation by recirculation, 13.8 kPa pressure) .
20、at 40 C 40 g/m2/24 h . at 60 C 60 g/m2/24 h 3.20 COMPRESSION SET, max 75% (FLTM BP 108-06, 70 h at 100 C, 25% compression) 3.21 ADHESION, min (ASTM D 413, Strip Method, Type A) Adhesion greater than the Barrier to Cover strength of the material 3.22 RESISTANCE TO KINKING (Not applicable to hoses wit
21、h I.D. greater than 16.28 mm, unless specified on engineering drawing) Test Method: Insert required length of hose on test fixture securing each end with metal clamps. When installing hose, it shall be bent within 5 s in the same plane and direction as its free state curvature. Place fixture in an o
22、ven at 120 +/- 2 C for 1 h. Remove fixture from oven and within 5 minutes pass a steel ball of specified diameter through hose installed on fixture. Ball must pass freely. Nominal I.D., I.D. Limits Test Sample Ball Diameter Mm mm Length, mm, min mm 4.8 3.58/4.34 200 1.68 +/- 0.05 6.4 4.88/6.76 250 2
23、.40 +/- 0.05 7.9 6.91/8.33 300 3.20 +/- 0.05 9.5 8.51/9.91 400 3.95 +/- 0.05 12.7 11.55/13.08 475 5.08 +/- 0.05 15.9 14.60/16.28 690 7.87 +/- 0/05 ENGINEERING MATERIAL SPECIFICATION WSL-M96D33-A4 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 5 of 6 Sample Selecti
24、on: Production hose selected for the kink test should represent, as nearly as possible, minimum wall thickness. When recording results include wall thickness, ovality, and dimension “A“ (see above). This dimension is measured while sample is on the test fixture. 3.23 INSTALLATION EFFORT, max 89 N Te
25、st must be completed satisfactorily with initial production parts for ISIR approval. Parts must be retested whenever any change is made which may affect part installation effort. Test Method: Cut hose to 41 +/- 2.5 mm length and immerse one end in 20W oil to approximately 6.4 mm depth. Immediately i
26、nstall hose on the test fixture with lubricated end inserted over SAE J962 Style A formed tube to an engagement of 19 mm. Test load application shall not exceed 1 minute. Nominal Diameter A Diameter B Diameter C (Reference) mm +/- 0.05 mm +/- 0.08 mm +/- 0.08 mm 4.8 Ref SAE 3.58 9.55 6.4 Ref SAE 5.3
27、3 11.81 7.9 Ref SAE 6.91 14.68 9.5 Ref SAE 8.51 15.67 19.1 22.5 18.30 26.20 31.8 35.5 32.00 40.90 38.1 42.2 38.00 47.10 44.5 48.9 44.00 53.30 ENGINEERING MATERIAL SPECIFICATION WSL-M96D33-A4 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 6 of 6 3.24 HOSE ELONGATIO
28、N, min 135% Test Method: Elongate a minimum 150 mm length of hose marked with 25 mm gage length to 135% (59 mm between gage marks) at a rate of 500 mm/minute. Remove from fixture and examine for cracks or breaks. None are allowed. Proof pressure test at 35 kPa of water or air under water may alterna
29、tively be used after 135% elongation to indicate pass or fail. Use production hose clamps and mandrels simulating production tube end form. 3.25 HOSE IDENTIFICATION The colored tracer cord in the reinforcement of the hose may be used for source identification. The color shall be determined between P
30、urchasing and the supplier. The word gas/fuel and the coding described below shall appear on the outer cover of the hose in contrasting color and repeated at intervals of 60 mm or less. Mandrel cured hose may be coded once per part. The following format is recommended: a) Supplier identification cod
31、e. b) Date of manufacture (week, year) and plant designation if supplier has more then one plant producing hoses to this specification. No space between letters. Mandatory on hoses longer then 80 mm only. c) Ford trademark on hoses longer then 150 mm. d) All of the above printing shall be clearly and legibly printed letters of 4.5 - 6 mm in height and width. When hose is less then 80 mm long, width of letters may be reduced to 3 mm. The following code format is recommended, but not mandatory: G 2 01 Where: G = Plant Designation 2 = Year (single digit) 01 = Week (2-digit number)
