1、Designation: F2931 13F2931 14Standard Guide forAnalytical Testing of Substances of Very High Concern inMaterials and Products1This standard is issued under the fixed designation F2931; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision
2、, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This guide contains a list of potential test methods for the analysis of Substances of Very High Concern
3、 (SVHC) asdesignated by ECHA, the European Chemicals Agency. Information on the test methods cited is publicly available and is drawnfrom a variety of sources. The guide is intended to assist in the selection of test methods that are applicable for the SVHCsidentified.1.2 The specific SVHCs covered
4、within this guide are compiled from the ECHA Candidate List of Substances of Very HighConcern. This list is also referred to as the REACH Candidate List.1.3 This guide specifically addresses methods for the analysis of SVHCs in products. It is not intended to cover the many andvaried analysis challe
5、nges associated in the manufacturing environment.1.4 Limitations:1.4.1 This guide is intended to provide a compilation of available test methods for the SVHCs listed on the ECHA Candidatelist and is not intended to be exhaustive. The test methods within this guide are not the only ones available for
6、 any specificsubstances and this guide does not recommend any specific test method.1.4.2 Test methods for specific substances at the detection limits required for REACH reporting are not always available. Insome cases, it is necessary to deduce the quantity of substance present through the analysis
7、and quantification of its elements.Although this approach is routinely used some degree of uncertainty exists in the final result due to the reduced specificity of thetest method.1.4.3 Although this guide is intended to be updated on a periodic basis to capture new developments in the field, there i
8、s noassurance that the information provided is the most current.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It
9、is the responsibilityof the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatorylimitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D1257 Specification for High-Gravity GlycerinD1385 Test Method for Hydrazine in Wate
10、rD1971 Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite FurnaceAtomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass SpectrometryD3335 Test Method for Low Concentrations of Lead, Cadmium, and Cobalt in Paint by Atomic Absorption Spec
11、troscopyD3545 Test Method for Alcohol Content and Purity of Acetate Esters by Gas ChromatographyD4309 Practice for Sample Digestion Using Closed Vessel Microwave Heating Technique for the Determination of Total Metalsin WaterD5831 Test Method for Screening Fuels in Soils1 This guide is under the jur
12、isdiction of ASTM Committee F40 on Declarable Substances in Materials and is the direct responsibility of Subcommittee F40.02.02 on TaskGroup on SVHCs.Current edition approved May 15, 2013April 1, 2014. Published July 2013May 2014. Originally approved in 2011. Last previous edition approved in 20112
13、013 asD3984 11.D3984 13. DOI: 10.1520/F2931-13.10.1520/F2931-14.2 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the ASTM websi
14、te.This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior
15、editions as appropriate. In all cases only the current versionof the standard as published by ASTM is to be considered the official document.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1D7065 Test Method for Determination of Nonylp
16、henol, Bisphenol A, p-tert -Octylphenol, Nonylphenol Monoethoxylate andNonylphenol Diethoxylate in Environmental Waters by Gas Chromatography Mass SpectrometryD7485 Test Method for Determination of Nonylphenol, p-tert-Octylphenol, Nonylphenol Monoethoxylate and NonylphenolDiethoxylate in Environment
17、al Waters by Liquid Chromatography/Tandem Mass SpectrometryE1621 Guide for Elemental Analysis by Wavelength Dispersive X-Ray Fluorescence SpectrometryF2576 Terminology Relating to Declarable Substances in Materials2.2 European Commission:3Article 57 of the European Union Regulation #1907/20062.3 Int
18、ernational Electrotechnical Commission TCTC111:111:4IEC 62321 Electrotechnical Products Determination of Levels of Six Regulated Substances (Lead, Mercury, Cadmium,Hexavalent Chromium, Polybrominated Biphenyls, Polybrominated Diphenyl Ethers)2.4 Joint Industry Guide (JIG):5JIG-101 Material Compositi
19、on Declaration for Electrotechnical Products. Ed 4.0, 20113. Terminology3.1 Definitions:3.1.1 Terms and definitions related to declarable substances in materials may be found in Terminology F2576.3.1.2 Terms and definitions in the guide not found in Terminology F2576 are found in a common dictionary
20、 or other referencedocuments such as the ASTM Dictionary of Engineering Science arsenic oxide; brominated flame retardants; candidate list; cobalt dichloride; hexabromocyclododecane; leadhydrogen arsenate; MDA; musk xylene; phthalates; REACH; short chain chlorinated paraffins; sodium dichromate; Sub
21、stances ofVery High Concern; tributyltin oxide; triethyl arsenateF2931 144TABLE 1 SVHC Substances and Their Common UsesSubstance Name Synonym CAS Number EU Number Chemical Formula Common Uses4,4-Diaminodiphenylmethane4,4-Methylene-dianiline, MDA101-77-9 202-974-4 C13H14N2 Converted to methylenediphe
22、ny diisocyanate (MDI). MDI used forpolyurethane production. Other uses include: (1) hardener for epoxy resinsand adhesives, (2) basic ingredient of colorant, and (3) intermediate for high-performance polymer.5-tert-Butyl-2.4.6-Trinitro-m-XyleneMusk Xylene (2,4,6-Trinitro-1,3-dimethyl-5-t-butylbenzen
23、e)81-15-2 201-329-4 C12H15N3O6 Used as a fragrant particularly for consumer cosmetic products.Alkanes, C10-13, chloro Short ChainChlorinated Paraffins(SCCP)85535-84-8 287-476-5 CxH(2X-y+2)Clywhere x=10-13and y=1-13May act as a secondary plasticizer or flame retardant in PVC. Other usesinclude: (1) m
24、etal working lubricant, (2) rubber parts, (3) paints, (4) sealant,(5) leather work, and (6) fiber.Anthracene Paranaphthalene 120-12-7 204-371-1 C14H10 An intermediate in the production of dyes; used in the manufacturer ofpyrotechnic products.Benzyl butyl phthalate Phthalic acid, benzylbutyl ester85-
25、68-7 201-622-7 C19H20O4 Plasticizer in flooring material such as PVC foam. Other uses are as aplasticizer in traffic cones, food conveyor belts, artificial leather, etc.Bis(2-ethylhexyl)phthalate Dioctylphthalate 117-81-7 204-211-0 C24H38O4 Commonly used as a platicizer in manufacturing of articles
26、made of PVC,resins, rubbers, packaging materials, some paper products, and variousmedical devices, including the blood bags. It can also be found in somehydraulic fluids or dielectric fluids in capacitors. It is often found in coatings,pigments, textiles, or used as a solvent in light sticks.Bis (tr
27、ibutyltin) oxide Distannoxane,hexabutyl-56-35-9 200-268-0 C24H54OSn2 Primarily used as a biocide for boats, mildew proofing for leather work.Cobalt dichloride Cobaltous Chloride 7646-79-9 231-589-4 CoCl2 This substance can be used for (1) humidity indicator, (2) absorbent ofammonia gas, (3) gas mask
28、, (4) production for vitamin B12, (5) trace amountof nutrient factor for food, (6) trace amount of element for nitric-acidpesticides, (7) solvent in purifying magnesium. Additionally, it may be usedfor packaging.Diarsenic pentaoxide Diarsenic Pentoxide 1303-28-2 215-116-9 As2O5 This substance can be
29、 used for (1) colorants, (2) metal refining, (3) specialglass production, and (4) antiseptic agent for wood.Diarsenic trioxide Arsenic Trioxide 1327-53-3 215-481-4 As2O3 This substance can be used for (1) decolorants for glasses and enamel, (2)purifying and oxidizing agent in production of special g
30、lasses and leadcrystal, (3) antiseptic agent for wood, and (4) medicine for leukemia.Dibutyl phthalate 1,2-Benzenedicarboxylicacid di-n-butyl ester84-74-2 201-557-4 C16H22O4 Common plasticizer used in various polymers to keep crystals from forming.It is also used in paints, pigments, or printing ink
31、s as an adhesive agent. It issoluble in various organic solvents. This property allows it to be used asfixatives in perfumes or as an ectoparasiticide.Hexabromocyclododecane Cyclododecane,hexabromo-isomers25637-99-4 247-148-4 C12H18Br6 Used as a brominated flame retardant for polystyrene materials,
32、forexample, HIPS case material and packaging.Lead hydrogen arsenate Lead Acid Arsenate 7784-40-9 232-064-2 (AsO4H)Pb Insecticide or pesticideSodium dichromate dihydrate Sodium Bichromate 7789-12-0 234-190-3 Na2Cr2O7.2H2O Used for: (1) production of other chromium compounds, (2) production ofinorgani
33、c chromate pigments, (3) preservative supplement, finishing of metalplating, (4) production of vitamin K.Triethyl arsenate Arsenic acid TriethylEster15606-95-8 427-700-2 (C2H5O)3AsO Used for integrated circuit manufacturing as an intermediate for n-typedoping of semiconductors.2,4-Dinitrotoluene 1-m
34、ethyl-2,4-dinitrobenzene 121-14-2 204-450-0 C7H6N2O4 2,4-dinitrotoluene is used in the production of toluene diisocyanate, which isused for the manufacture of flexible polyurethane foams. The substance isalso used as gelatinizing-plasticizing agent for the manufacture of explosivemixtures (for examp
35、le, for airbags in cars).Aluminosilicate RefractoryCeramic FibresVITREOUS 142844-00-6 Refractory ceramic fibres are used for high-temperature insulation, almostexclusively in industrial applications (insulation of industrial furnaces andequipment, equipment for the automotive and aircraft/aerospace
36、industry)and in fire protection (buildings and industrial process equipment).Anthracene oil Anthracene PhenanthreneCarbazole90640-80-5 292-602-7 C14H10C12H9NThe substances are mainly used in the manufacture of other substancessuch as anthracene and carbon black. They may also be used as reducingagen
37、ts in blast furnances, as components in bunker fuel, for impregnating,sealing and corrosion protection.F2931145Anthracene oil, anthracenepasteAnthracene PhenanthreneCarbazole90640-81-6 292-603-2 C14H10C12H9NThe substances are mainly used in the manufacture of other substancessuch as anthracene and c
38、arbon black. They may also be used as reducingagents in blast furnances, as components in bunker fuel, for impregnating,sealing and corrosion protection.Anthracene oil, anthracenepaste, anthracene fractionAnthracene PhenanthreneCarbazole91995-15-2 295-275-9 C14H10C12H9NThe substances are mainly used
39、 in the manufacture of other substancessuch as anthracene and carbon black. They may also be used as reducingagents in blast furnances, as components in bunker fuel, for impregnating,sealing and corrosion protection.Anthracene oil, anthracenepaste,distn. lightsAnthracene PhenanthreneCarbazole91995-1
40、7-4 295-278-5 C14H10C12H9NThe substances are mainly used in the manufacture of other substancessuch as anthracene and carbon black. They may also be used as reducingagents in blast furnances, as components in bunker fuel, for impregnating,sealing and corrosion protection.Anthracene oil, anthracene-l
41、ow Anthracene PhenanthreneCarbazole90640-82-7 292-604-8 C14H10C12H9NThe substances are mainly used in the manufacture of other substancessuch as anthracene and carbon black. They may also be used as reducingagents in blast furnances, as components in bunker fuel, for impregnating,sealing and corrosi
42、on protection.Diisobutyl phthalate Bis(2-methylpropyl) benzene-1,2-dicarboxylate84-69-5 201-553-2 C16H22O4 Diisobutyl phthalate is used as plasticiser for nitrocellulose, cellulose ether,polyacrylate and polyacetate dispersions, and as a gelling aid in combinationwith other plasticisers, which are w
43、idely used for plastics, lacquers,adhesives, explosive material and nail polish.Lead chromate Lead(2+) chromate 7758-97-6 231-846-0 CrH2O4.Pb Lead chromate is used for manufacturing pigments and dyes, as a pigmentor coating agent in industrial and maritime paint products or for embalming/restoring o
44、f art products. Further potential uses include as detergents andbleaches, photosensitive materials and for the manufacture of pyrotechnicpowder.Lead chromate molybdatesulphate red (C.I. Pigment Red104)Lead(2+) chromate lead(2+)sulfate lead(2+) molybdate12656-85-8 235-759-9 CrH2O4.PbH2O4S.PbPbMoO4Lea
45、d chromate molybdate sulphate red (C.I. Pigment Red 104) is used as acolouring, painting and coating agent in sectors such as the rubber, plasticand paints, coatings and varnishes industries. Applications comprise theproduction of agricultural equipment, vehicles and aircraft as well as roadand airs
46、trip painting.Lead sulfochromate yellow (C.I.Pigment Yellow 34)Lead(2+) chromate lead(2+)sulfate1344-37-2 215-693-7 CrH2O4.PbH2O4S.PbLead sulfochromate yellow (C.I. Pigment Yellow 34) is used as a colouring,painting and coating agent in sectors such as the rubber, plastic and paints,coatings and var
47、nishes industries. Applications comprise the production ofagricultural equipment, vehicles and aircraft as well as road and airstrippainting. The substance is further used for camouflage or ammunitionmarking in the defence area.Pitch, coal tar, high temperature anode pitch, binder pitch, claypigeon
48、binder, electrode pitch,hard pitch, impregnating pitch,soft pitch, vacuum pitch65996-93-2 266-028-2 not applicable Pitch, coal tar, high temperature is mainly used in the production ofelectrodes for industrial applications. Smaller volumes are dedicated tospecific uses such as heavy duty corrosion p
49、rotection, special purposepaving, manufacture of other substances and the production of clay targets.Tris(2-chloroethyl)phosphate 115-96-8 204-118-5 C6H12Cl3O4P Tris(2-chloroethyl)phosphate is mainly used as an additive plasticiser andviscosity regulator with flame-retarding properties for acrylic resins,polyurethane, polyvinyl chloride and other polymers. Other fields ofapplication are adhesives, coatings, flame-resistant paints and varnishes.The main industrial branches to use TCEP are the furniture, the textile andthe building industry.Zirconia AluminosilicateRefractory
