1、Designation: D 6131 97 (Reapproved 2004)Standard Test Method forEvaluating the Relative Tint Undertone of Titanium DioxidePigments1This standard is issued under the fixed designation D 6131; the number immediately following the designation indicates the year oforiginal adoption or, in the case of re
2、vision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method is intended to be used to determine thetint undertone (blue or yellow) of titani
3、um dioxide pigments.This relates to the effective particle size of the pigment. It isbased upon tinting with a black iron oxide, but other blacksmay be used if found suitable.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.
4、1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced D
5、ocuments2.1 ASTM Standards:2D 16 Terminology for Paint, Coatings, Related Materials,and ApplicationsD 2745 Test Method for Relative Tinting Strength of WhitePigments by Reflectance MeasurementsE 313 Practice for Calculating Yellowness and WhitenessIndices from Instrumentally Measured Color Coordinat
6、esE 1331 Test Method for Reflectance Factor and Color bySpectrophotometry Using Hemispherical GeometryE 1347 Test Method for Color and Color-Difference Mea-surement by Tristimulus (Filter) ColorimetryE 1349 Test Method for Reflectance Factor and Color bySpectrophotometry Using Bidirectional Geometry
7、3. Terminology3.1 Any special terms used in this test method can be foundin Terminology D 16.4. Summary of Test Method4.1 Titanium dioxide pigments are dispersed in a black pastewith a mechanical muller. Test and reference pigments aretreated identically. The resultant grey pastes are applied toglas
8、s cover slips and read instrumentally. These readings arethen used to calculate the yellowness index.5. Significance and Use5.1 This test method allows the user to make a quickdetermination of the blueness or yellowness of the tint under-tone of titanium dioxide pigments, versus a reference pigmenta
9、greed upon by the parties to the test. This is an importantmeasure of tone, since it gives both a measure of effectiveparticle size, and quick approximation of the blue/yellowundertone that can be expected when a coating containing thetitanium dioxide is tinted.5.2 Such matters as the vehicle for pr
10、eparing the disper-sions, and the black for tinting have been suggested. However,changes in the components may be made by agreementbetween the buyer and the seller.5.3 The results obtained with a mechanical muller do notnecessarily correlate directly with a practice where differentdispersion conditi
11、ons exist. However, dispersion with a me-chanical muller is a quick and inexpensive way of evaluatingthe undertone of a titanium dioxide pigment.6. Apparatus6.1 Balances, meeting the requirements of Test MethodD 2745.6.2 Mechanical Muller, equipped with ground-glass platesto which a variable but kno
12、wn force may be added in 220Nincrements. The driven glass plate shall have a speed ofrotation of between 70 and 120 r/min and the apparatus shallhave an arrangement for presetting the number of revolutionsin multiples of 50.6.3 Rubbing Surfaces, meeting the requirements of TestMethod D 2745.6.4 Smal
13、l Glass Slab, meeting the requirements of TestMethod D 2745.6.5 Spatula, meeting the requirements of Test MethodD 2745.1This test method is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.26 on
14、 Optical Properties.Current edition approved Nov. 1, 2004. Published November 2004. Originallyapproved in 1997. Last previous edition approved in 1997 as D 6131 97.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Boo
15、k of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.6.6 Glass Cover Slips, No. 2 thickness, 45 by 50 mm.6.7 Color Measuring Instrument
16、, meeting the requirementsof Test Methods E 1331, E 1347, or E 1349, and having ameasuring port 25 mm or smaller in diameter.7. Materials7.1 Reference StandardA standard pigment as agreedupon between the buyer and the seller.7.2 Vehicle-Castor Oil, (Grade AA).7.3 Tinting PasteA Vehicle/Parts by Weig
17、ht paste such asone of the following:(1) Castor Oil 50Gypsum 47Thickener 6Iron Oxide Black 3(2) Petroleum Jelly 97Lampblack 38. Procedure8.1 Disperse pigment into paste as described in Test MethodD 2745. Luminance should be approximately 40 %.8.2 Apply the gray paste to the cover glass with a spatul
18、a.The area to which the paste is applied should be in the centerof the cover glass, should be approximately 30 mm in diameter,and should be at least 2mm thick.8.3 View the paste through the glass from the side oppositethat to which the paste was applied. Evaluate for evenness ofcoating, and any poss
19、ible flaws. An irregular coating from thisside mandates a repeat of the test.8.4 Center the uncoated side of the cover glass over the portof the color measuring instrument, and read CIE XYZ valueson the specimen, using the applicable method for the instru-ment. Make sure that the port is entirely co
20、vered.NOTE 1A daylight illuminant (for example, C, D65,D75) must be usedfor the readings.NOTE 2Because of inherent differences in the readings obtained withdifferent methods (that is Test Methods E 1331, E 1347, E 1349), thebuyer and the seller should agree on the method to be used.9. Calculation9.1
21、 Calculate the yellowness index in accordance withPractice E 313.10. Report10.1 Report the following information:10.1.1 The type and identification of the test pigment andreference standard pigment,10.1.2 The type and identification of the black and thedispersing vehicle,10.1.3 The mass ratio of pig
22、ment to vehicle, and of black totitanium dioxide,10.1.4 The manufacturer and model number of the mechani-cal muller used, and the color instrument used,10.1.5 The total force applied to the muller plates, and thetotal number of revolutions,10.1.6 The measuring method used,10.1.7 The instrument readi
23、ngs, and10.1.8 The yellowness index.11. Precision and Bias11.1 PrecisionThe precision will be written from RoundRobin results.11.2 BiasBias cannot be determined because there is nostandard reference material for this test method.12. Keywords12.1 mechanical muller; tint undertone; titanium dioxidepig
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25、 are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional sta
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27、mittee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D 6131 97 (2004)2
