1、Designation: D4614 11Standard Specification forEthyl Acetate (All Grades)1This standard is issued under the fixed designation D4614; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses
2、 indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This specification covers the various grades of ethylacetate suitable for use as solvents in paint and relatedcoatings.1.2 The values stated in SI units ar
3、e to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 The following applies to all specified limits in thisstandard; for purposes of determining conformance with thisstandard, and observed value or a calculated value shall berounded off “to the nearest unit in t
4、he last right-hand digit usedin expressing the specification limit, in accordance with therounding-off method of Practice E29.1.4 For specific hazard information and guidance, see thesuppliers Material Safety Data Sheet for material listed in thisspecification.2. Referenced Documents2.1 ASTM Standar
5、ds:2D268 Guide for Sampling and Testing Volatile Solvents andChemical Intermediates for Use in Paint and RelatedCoatings and MaterialD891 Test Methods for Specific Gravity, Apparent, ofLiquid Industrial ChemicalsD1078 Test Method for Distillation Range of Volatile Or-ganic LiquidsD1209 Test Method f
6、or Color of Clear Liquids (Platinum-Cobalt Scale)D1296 Test Method for Odor of Volatile Solvents andDiluentsD1353 Test Method for Nonvolatile Matter in VolatileSolvents for Use in Paint, Varnish, Lacquer, and RelatedProductsD1364 Test Method for Water in Volatile Solvents (KarlFischer Reagent Titrat
7、ion Method)D1613 Test Method for Acidity in Volatile Solvents andChemical Intermediates Used in Paint, Varnish, Lacquer,and Related ProductsD3545 Test Method for Alcohol Content and Purity ofAcetate Esters by Gas ChromatographyD4052 Test Method for Density, Relative Density, and APIGravity of Liquid
8、s by Digital Density MeterD5386 Test Method for Color of Liquids Using TristimulusColorimetryE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE300 Practice for Sampling Industrial Chemicals2.2 U.S. Federal Specification:PPP-C-2020 Chemicals, Liquid, D
9、ry, and Paste: Packagingof33. Properties3.1 Ethyl acetate shall conform to the requirements of oneof the grades in Table 1.4. Sampling4.1 The material shall be sampled in accordance withPractice E300.5. Test Methods5.1 The properties enumerated in this specification shall bedetermined in accordance
10、with the following ASTM methods:5.1.1 Purity and Alcohol ContentTest Method D3545.5.1.2 Apparent Specific GravityDetermine the apparentspecific gravity by any convenient method that is accurate tothe third decimal place, the temperature of both sample andwater being 20 or 25C (see Guide D268, or Tes
11、t MethodsD891 or D4052).5.1.3 Distillation RangeTest Method D1078 using a tem-perature measuring device having a range of 48 to 102C anda resolution of 0.1C.5.1.4 AcidityTest Method D1613.5.1.5 WaterTest Method D1364.5.1.6 ColorTest Method D1209.5.1.7 Nonvolatile MatterTest Method D1353.1This specif
12、ication is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.Current edition approved Nov. 1, 2011. Published November 2011. Originallyapp
13、roved in 1986. Last previous edition approved in 2005 as D4614 05. DOI:10.1520/D4614-11.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summa
14、ry page onthe ASTM website.3Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http:/dodssp.daps.dla.mil.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive,
15、 PO Box C700, West Conshohocken, PA 19428-2959, United States.5.1.8 OdorTest Method D1296.6. Packaging and Package Marking6.1 Package size to be agreed upon between the purchaserand the supplier.6.2 Packaging shall conform to applicable carrier rules andregulations or when specified shall conform to
16、 Fed. Spec.PPP-C-2020.7. Keywords7.1 ester; ethyl acetate; solventSUMMARY OF CHANGESCommittee D01 has identified the location of selected changes to this standard since the last issue (D4614 - 05)that may impact the use of this standard. (Approved November 1, 2011.)(1) Revised 5.1.3. (2) Removed Spe
17、cification E1 from 2.1.ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringem
18、ent of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or
19、 for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views kn
20、own to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting AS
21、TM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).TABLE 1 Requirements for Ethyl AcetatePropert
22、yGrades8588 99 99.5 99.5UAPurity, wt %, min 85.088.0 99.0 99.5 99.5Alcohol, wt %, max . 0.5 0.2 0.2Color, Pt-Co units, maxB10 10 10 10Distillation range, C 71.079.0 75.078.0 75.578.0 75.578.0Nonvolatile matter, mg/100 mL, max 5 5 5 5OdorCNon-residual Non-residual Non-residual Non-residualWater, wt %
23、, max 0.2 0.1 0.1 0.05DAcidity, wt %, max 0.01 0.01 0.01 0.01Apparent Specific Gravity:E20/20C 0.8820.887 0.9000.903 0.9000.903 0.9000.903or25/25C 0.8770.882 0.8950.898 0.8950.898 0.8959.898AUrethane grade material.BInstrumental Pt-Co color determined by Test Method D5386 have been shown to have no
24、statistically significant difference from Pt-Co color determined by Test MethodD1209. However, it is not known whether ethyl acetate was part of the sample set included in the interlaboratory study.CTest for odor is optional and should be agreed upon between the buyer and the seller.DTest method used to determine this value should be agreed on between the buyer and the seller.EApparent specific gravity should be determined either at 20C or 25C, and not both. Results obtained at one temperature are valid. Test result at another temperatureis redundant.D4614 112
