1、Designation: D 926 08Standard Test Method forRubber PropertyPlasticity and Recovery (Parallel PlateMethod)1This standard is issued under the fixed designation D 926; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last
2、revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This test method covers the determination
3、of plasticityand recovery of unvulcanized rubber by means of the parallelplate plastometer. Uncompounded, compounded, and reclaimrubber may be tested.NOTE 1ISO 2007 and Test Method D 3194 use a principle similar tothis test method although the apparatus, test conditions, and procedure aredifferent.1
4、.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro
5、-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D 3194 Test Method for Rubber From Natural SourcesPlasticity Retention Index (PRI)D 3767 Practice for RubberMeasurement of DimensionsD 4483 Practice
6、for Evaluating Precision for Test MethodStandards in the Rubber and Carbon Black ManufacturingIndustriesE 145 Specification for Gravity-Convection and Forced-Ventilation Ovens2.2 ISO Standard:3ISO 2007 Rubber UnvulcanizedDetermination ofPlasticityRapid Plastimeter Method3. Summary of Test Method3.1
7、Plasticity:3.1.1 A specimen of specific volume and height is tested atroom temperature or heated to a specified test temperature for15 min and then subjected to a compressive force of 49 N fora specified time.3.1.2 At the end of this time, the height of the specimen ismeasured, and the plasticity nu
8、mber is calculated.3.2 RecoveryThere are two recovery procedures.3.2.1 Procedure AThe test specimen is removed from theplastometer immediately after the determination of plasticityand allowed to cool and recover some of its original height for1 min. The height is measured again and the recovery isca
9、lculated.3.2.2 Procedure BThe test specimen is compressed to aheight of 5 mm for 30 s and then allowed to recover at the testtemperature for 5 min. The height is measured again and therecovery is calculated.4. Significance and Use4.1 The plasticity number and the recovery of the testspecimen are rel
10、ated to the flow properties and the elasticproperties, respectively, and may be useful in predictingprocessing characteristics, such as ease of forming and extru-sion characteristics.4.1.1 In this test method, plasticity is measured in an inversemanner, as noted by the final height of the specimen.
11、Thus,high plasticity rubbers (high degree of flow during test) areindicated by a low plasticity number.5. Apparatus5.1 The essential features of the parallel plate plastometer,illustrated in Fig. 1, are as follows:1This test method is under the jurisdiction of ASTM committee D11 on Rubberand is the
12、direct responsibility of Subcommittee D11.12 in Processability Tests.Current edition approved Nov. 1, 2008. Published November 2008. Originallyapproved in 1956. Last previous edition approved in 2004 as D 926 04.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Cus
13、tomer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute, 25 West 43rd St., 4thFloor, New York, NY 10036.1Copyright ASTM International, 100 Barr Harbor
14、Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.1.1 Two metal plates, not less than 10 mm in thicknessand 40 mm in diameter, shall be mounted on a suitable frameso that one plate moves with respect to the other, and so that thetwo plates are parallel within 0.017 rad (1) at all
15、 times.5.1.2 The apparatus shall be so designed that a specimenbetween the parallel plates is subjected to a force of 49 6 0.5N, including the effect of the spring in the dial gauge duringtest.5.1.3 A digital or dial indicator gauge calibrated in hun-dredths of a millimetre (0.01 mm) shall be mounte
16、d on theapparatus in such a manner that the distance between the platescan be determined at all times.5.1.4 When required, the apparatus shall be operated in anyoven, as described in Specification E 145, that is capable ofcontaining the plastometer.5.1.5 A separate dimensional measurement gauge is r
17、e-quired for performing recovery measurements. The apparatusand methodology described in Practice D 3767, Procedure A,shall be employed when performing these measurements.5.2 Test SurfacesFilms or material with low coefficientsof friction shall be used to prevent sticking of the test specimento the
18、plates. The most commonly used test surface is polyesterfilm. Other films such as cellophane or nylon may be used. Thetest surface film shall have a thickness of 0.25 6 0.005 mm.NOTE 2The test surface used can affect the plasticity number. Evendifferent grades of the same type of film can cause diff
19、erent results. Whencomparing results, the same test surface must be used.6. Sampling6.1 Samples may be taken from raw rubber or unvulcanizedrubber compounds undergoing processing operations.7. Test Specimens7.1 The specimen shall be a right cylinder 2.00 6 0.02 cm3in volume and be free from air pock
20、ets. (A cylinder 16 mm indiameter and 10 mm in height is appropriate.) The specimenmay be prepared from either a solid piece or plied sheets ofunvulcanized rubber approximately 1.5 mm in thickness, carebeing taken to exclude air pockets in the sheet. The specimensmay be cut from the sheet either by
21、means of two mating diesconforming to Fig. 2, which produce cylinders of the correctvolume, or a rotating die having an internal diameter ofapproximately 16 mm. If a rotating die is used, the height of thecylinder shall be adjusted until the volume is 2.00 6 0.02 cm3.If the density is known, weighin
22、g may be used to adjust to thecorrect volume. If necessary, the specimen shall be placed in asuitable holder so that it is not appreciably deformed beforetesting.8. Test Conditions8.1 The plasticity and recovery values obtained for a givensample will depend largely upon the manner in which the tests
23、pecimen is prepared. It is therefore imperative that whencomparisons are made between similar materials, the testspecimen preparation should be in accordance with somerigidly specified method. This is necessary because the plas-ticity and recovery may be affected by the amount of mechani-cal working
24、 and the conditions under which such work is done.This effect is not constant for all materials. The time intervalbetween test specimen preparation and testing is important andshould be the same for test specimens between which com-parisons are to be made.8.2 The test temperature shall be 23 (room t
25、emperature), 40,70, 85, or 100C unless another temperature is agreed upon.The most frequently used temperature is 23C.8.3 Readings may be taken at any desired interval followingthe application of the load. The most frequently used intervalsare between 3 and 10 min.FIG. 1 One Type of Parallel Plate P
26、lastometerFIG. 2 Die for Forming Test SpecimenD9260829. Plasticity Procedure9.1 Set the indicator to read zero with two thicknesses of thetest surface between the plates. Condition the plastometer atthe test temperature until temperature equilibrium is achieved.9.2 Place the test specimen between th
27、e two test surfaces toprevent sticking of the test specimen to the plates.9.3 If required, condition the test specimen at the testtemperature for 15 6 0.5 min.9.4 Quickly place the test specimen between the two paral-lel plates, lower the mass, and at the end of the required timeinterval, read the t
28、hickness gauge to hundredths of a millime-tre. Record the height of the specimen in millimetres as h1.9.5 Calculate plasticity, P, as follows:P 5 100h1(1)10. Recovery Procedures10.1 Recovery values may be determined by the proceduredescribed in either 10.2 or 10.3, but the results will differ.10.2 P
29、rocedure A:10.2.1 After determining the plasticity as described inSection 9, immediately remove the test specimen from theplastometer and allow it to cool exactly 1 min at 23 6 2C.Then measure the height of the specimen with the two testsurfaces using the dial micrometer gauge specified in 5.1.5.Rec
30、ord this reading as h2.10.2.2 Calculate recovery, RA, as follows:RA5 100 h22 h1! (2)10.3 Procedure B:10.3.1 Follow the procedure described in Section 9 fordetermining plasticity, except that the test specimen shall becompressed to a height of 5 mm for 30 s. This may be done byplacing three spacers 5
31、.00 6 0.01 mm in thickness on twothicknesses of test surface at suitable positions between theplates to ensure parallelism and prevent misalignment of theplates.10.3.2 At the end of the compression period, remove thespecimen from between the plates and permit it to recover for5 min at the test tempe
32、rature.10.3.3 At the end of the 5-min recovery period, measure theheight of the specimen with the micrometer gauge specified in5.1.5. Record as h3.10.3.4 Calculate recovery, RB, as follows:RB5 100 h32 5! (3)11. Report11.1 Report the following information:11.1.1 Sample Identification:11.1.1.1 A full
33、description of the sample and its origin,11.1.1.2 Compound details, where appropriate,11.1.1.3 Preparation method of the test piece (plied orsolid), and11.1.1.4 Time between preparation and test.11.1.2 Test Conditions:11.1.2.1 Test surface used,11.1.2.2 Test temperature,11.1.2.3 Time, in minutes, th
34、e force was applied to the testpiece,11.1.2.4 Recovery time, in minutes, and11.1.2.5 Date of the test.11.1.3 Test Results:11.1.3.1 Plasticity number, P, and11.1.3.2 Recovery number, RAor RB.12. Precision and Bias12.1 These precision and bias statements have been pre-pared in accordance with Practice
35、 D 4483. Please refer toPractice D 4483 for terminology and other testing and statisti-cal concept explanations.12.2 The Type 1 precision was determined from an inter-laboratory study of three compounds that were mixed in onelaboratory. Four laboratories prepared samples and tested eachcompound.12.3
36、 A “test result” for this plasticity and recovery testingrepresents one measurement with a parallel plate plastometer.12.4 Table 1 lists the precision data. A Type 1 precision, asdefined in Practice D 4483, includes as components of varia-tion, the specimen preparation and testing operation withinea
37、ch laboratory, but not the mixing or compound preparationcomponents of variation.12.5 The precision of this test method may be expressed inthe format of the following statements which use an “appro-priate value” of r, R,(r), or (R), that is, that value to be used indecisions about test results (obta
38、ined with the test method).The appropriate value is that value of r or R associated with amean level in Table 1 closest to the mean level underconsideration (at any given time, for any given material) inroutine testing operations.12.6 RepeatabilityThe repeatability, r, of this test methodhas been es
39、tablished as the appropriate value tabulated in Table1. Two single test results, obtained under normal test methodprocedures, that differ by more than this tabulated r (for anygiven level) must be considered as derived from different ornon-identical sample populations.12.7 ReproducibilityThe reprodu
40、cibility, R, of this testmethod has been established as the appropriate value tabulatedin Table 1. Two single test results obtained in two differentlaboratories, under normal test method procedures, that differby more than the tabulated R (for any given level) must beconsidered to have come from dif
41、ferent or non-identical samplepopulations.12.8 Repeatability and reproducibility expressed as a per-cent of the mean level, (r) and (R), have equivalent applicationstatements as above for r and R. For the (r) and (R) statements,the difference in the two single test results is expressed as apercent o
42、f the arithmetic mean of the two test results.12.9 BiasIn test method terminology, bias is the differ-ence between an average test value and the reference (or true)test property value. Reference values do not exist for this testmethod since the values of plasticity and recovery are exclu-sively defi
43、ned by the test method. Bias, therefore, cannot bedetermined.13. Keywords13.1 elastic properties; flow properties; parallel plate plas-tometer; plasticity; plasticity and recovery; plastometer; Will-iams plastometerD926083ASTM International takes no position respecting the validity of any patent rig
44、hts asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any
45、 time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments wi
46、ll receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by AS
47、TM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); o
48、r through the ASTM website(www.astm.org).TABLE 1 Type 1 PrecisionTestTest Tem-perature, CRangeof ValuesAWithin LaboratoryBBetween LaboratoryBSrr (r)BSRR (R)CPlasticity 70 415755 22.7 64.2 11.0 64.2 181.7 31.1Plasticity 100 350630 17.7 50.1 10.2 25.5 72.2 14.7Recovery 70 50250 28.6 80.9 54.0 55.7 157
49、.6 105.0Recovery 100 30190 15.8 44.7 40.6 21.0 59.4 54.0AUnits=mm3 100.BSr= repeatability standard deviation, in measurement units.r = repeatability in measurement units.(r) = repeatability (relative) percent.SR= reproducibility standard deviation, in measurement units.R = reproducibility in measurement units.(R) = reproducibility (relative) percent.CMidpoint of range used to calculate (r) and (R).D926084
