1、Designation: B111/B111M 11B111/B111M 16Standard Specification forCopper and Copper-Alloy Seamless Condenser Tubes andFerrule Stock1This standard is issued under the fixed designation B111/B111M; the number immediately following the designation indicates the yearof original adoption or, in the case o
2、f revision, the year of last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope*1.1 This sp
3、ecification2 establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys upto 318 in. 80 mm inclusive, in diameter, for use in surface condensers, evaporators, and heat exchangers. The following coppersand copper alloys are specified:3 (WarningMercury is a de
4、finite health hazard in use and disposal. (See 12.1.)Copper orCopperAlloyUNS No.PreviouslyUsedDesignationDescriptionC10100 OFE Oxygen-free electronicC10200 OFA Oxygen-free without residual deoxidantsC10300 . . . Oxygen-free, extra low phosphorusC10800 . . . Oxygen-free, low phosphorusC12000 DLPA Pho
5、sphorized, low residual phosphorusC12200 DHPA Phosphorized, high residual phosphorusC14200 DPAA Phosphorized, arsenicalC19200 . . . Phosphorized, 1 % ironC23000 . . . Red BrassC28000 . . . Muntz MetalC44300 . . . Admiralty Metals, B, C, and DC44400 . . . . . .C44500 . . . . . .C60800 . . . Aluminum
6、BronzeC61300 . . . . . .C61400 . . . Aluminum Bronze, DC68700 . . . Aluminum Brass, BC70400 . . . 95-5 Copper-NickelC70600 . . . 90-10 Copper-NickelC70620 . . . 90-10 Copper-NickelWelding GradeC71000 . . . 80-20 Copper-NickelC71500 . . . 70-30 Copper-NickelC71520 . . . 70-30 Copper-NickelWelding Gra
7、deC71640 . . . Copper-nickel-iron-manganeseC72200 . . . . . .A Designations listed in Classification B224.1.2 UnitsThe values stated in either SI units or inch-pound units are to be regarded separately as standard. The values statedin each system may not be exact equivalents; therefore, each system
8、shall be used independently of the other. Combining valuesfrom the two systems may result in non-conformance with the standard.1.3 The following safety hazards caveat pertains only to the test methods portion, Section 19, of this specification: This standarddoes not purport to address all of the saf
9、ety concerns, if any, associated with its use. It is the responsibility of the user of thisstandard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1 This specification is under the jurisdiction of ASTM Committee B05 on Copp
10、er and Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipe andTube.Current edition approved Oct. 1, 2011Oct. 1, 2016. Published November 2011November 2016. Originally approved in 1937. Last previous edition approved in 20092011as B111/B111M09.11. DOI: 10.1520/B0111_B0111M-1
11、1.10.1520/B0111_B0111M-16.2 For ASME Boiler and Pressure Vessel Code applications, see related Specification SB-111 in Section II of the Code.3 The UNS system for copper and copper alloys (see Practice E527) is a simple expansion of the former standard designation system accomplished by the addition
12、 of aprefix “C” and a suffix “00.” The suffix can be used to accommodate composition variations of the base alloy.This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not
13、 be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current versionof the standard as published by ASTM is to be considered the official document.*A Summary of Changes section appears at the end
14、 of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1(WarningMercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medicalissues. Mercury, or its vapor, has been demonstrat
15、ed to be hazardous to health and corrosive to materials. Caution should be takenwhen handling mercury and mercury containing products. See the applicable product Safety Data Sheet (SDS) for additionalinformation. Users should be aware that selling mercury and/or mercury containing products in your s
16、tate or country may beprohibited by law.)2. Referenced Documents2.1 The following documents in the current issue of the Annual Book of ASTM Standards form a part of this specification tothe extent referenced herein:2.2 ASTM Standards:4B153 Test Method for Expansion (Pin Test) of Copper and Copper-Al
17、loy Pipe and TubingB154 Test Method for Mercurous Nitrate Test for Copper AlloysB170 Specification for Oxygen-Free Electrolytic CopperRefinery ShapesB224 Classification of CoppersB846 Terminology for Copper and Copper AlloysB858 Test Method for Ammonia Vapor Test for Determining Susceptibility to St
18、ress Corrosion Cracking in Copper AlloysE8B968/B968M Test MethodsMethod for Tension Testing of Metallic MaterialsFlattening of Copper and Copper-Alloy Pipe andTubeE8ME8/E8M Test Methods for Tension Testing of Metallic Materials Metric (Withdrawn 2008)E29 Practice for Using Significant Digits in Test
19、 Data to Determine Conformance with SpecificationsE53 Test Method for Determination of Copper in Unalloyed Copper by GravimetryE54 Test Methods for Chemical Analysis of Special Brasses and Bronzes (Withdrawn 2002)5E62 Test Methods for Chemical Analysis of Copper and Copper Alloys (Photometric Method
20、s) (Withdrawn 2010)5E75 Test Methods for Chemical Analysis of Copper-Nickel and Copper-Nickel-Zinc Alloys (Withdrawn 2010)5E76 Test Methods for Chemical Analysis of Nickel-Copper Alloys (Withdrawn 2003)5E112 Test Methods for Determining Average Grain SizeE118 Test Methods for Chemical Analysis of Co
21、pper-Chromium Alloys (Withdrawn 2010)5E243 Practice for Electromagnetic (Eddy Current) Examination of Copper and Copper-Alloy TubesE255 Practice for Sampling Copper and Copper Alloys for the Determination of Chemical CompositionE478 Test Methods for Chemical Analysis of Copper AlloysE527 Practice fo
22、r Numbering Metals and Alloys in the Unified Numbering System (UNS)E2575 Test Method for Determination of Oxygen in Copper and Copper Alloys3. Terminology3.1 Definitions:3.1.1 For definitions of terms relating to copper and copper alloys, refer to Terminology B846.3.2 Definitions of Terms Specific t
23、o This Standard:3.2.1 capable ofthe test need not be performed by the producer of the material. However, should subsequent testing by thepurchaser establish that the material does not meet these requirements, the material shall be subject to rejection.4. Ordering Information4.1 Include the following
24、 information specified choices when placing orders for product under this specification:specification,as applicable:4.1.1 ASTM Designation and year of approval (for example, ASTM issue;B111/B111M 04),4.1.2 Copper or Copper Alloy UNS No. Designation (see Table 1),);4.1.3 Form (tube or ferrule stock),
25、4.1.3 Temper (see(Section 7Temper section),);4.1.4 Dimensions, outside diameter, and wall thickness, whether minimum or nominal (Dimensions(Section 14and PermissibleVariations Section),);4.1.5 How furnished (tube or ferrule stock);4.1.6 Quantitytotal weight or total length or number of pieces of eac
26、h size,size; and4.1.7 If product is purchased for agencies of the U.S. Government (see the Supplementary Requirements Section).Intendedapplication.4 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standard
27、svolume information, refer to the standards Document Summary page on the ASTM website.5 The last approved version of this historical standard is referenced on www.astm.org.B111/B111M 162TABLE 1 Chemical RequirementsCopper orCopperAlloy UNSNo.Composition, %CopperA Tin AluminumNickel,inclCobaltLead,ma
28、x Iron Zinc Manganese Arsenic Antimony Phosphorus ChromiumOtherNamedElementsC10100 99.99 minB 0.002 max . . . 0.0010 max 0.0005 max 0.0010 max 0.0001max0.00005 max 0.0005max0.0004 max 0.0003 max 0.0001 max CC10100 99.99 minA 0.0002 max . . . 0.0010 maxB 0.0005 max 0.0010 max 0.0001max0.00005 max 0.0
29、005max0.0004 max 0.0003 max 0.0001 max CC10200D 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . DC10200C 99.95 minD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . CC10300 99.95 minE . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0010.005 . . .
30、. . .C10300 99.95 minD . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0010.005 . . . . . .C10800 99.95 minE . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0050.012 . . . . . .C10800 99.95 minD . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0050.012 . . . . . .C12000E 99.90
31、 minD . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0040.012 . . . . . .C12200 99.9 minD . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.0150.040 . . . . . .C14200 99.40 min . . . . . . . . . . . . . . . . . . . . . 0.150.50 . . . 0.0150.040 . . . . . .C14200 99.4 minD . . . . . .
32、. . . . . . . . . . . . . . . 0.150.50 . . . 0.0150.040 . . . . . .C19200 98.5 min . . . . . . . . . . . . 0.81.2 0.20 max . . . . . . . . . 0.010.04 . . . . . .C23000 84.086.0 . . . . . . . . . 0.05 0.05 max remainder . . . . . . . . . . . . . . . . . .C28000 59.063.0 . . . . . . . . . 0.09 0.07 ma
33、x remainder . . . . . . . . . . . . . . . . . .C44300 70.073.0 0.91.2 . . . . . . 0.07 0.06 max remainder . . . 0.020.06 . . . . . . . . . . . .C44400 70.073.0 0.91.2 . . . . . . 0.07 0.06 max remainder . . . . . . 0.020.10 . . . . . . . . .C44500 70.073.0 0.91.2 . . . . . . 0.07 0.06 max remainder
34、. . . . . . . . . 0.020.10 . . . . . .C60800 remainderD . . . 5.06.5 . . . 0.10 0.10 max . . . . . . 0.020.35 . . . . . . . . . . . .C61300 remainder 0.200.50 6.07.5 0.15 max 0.01 2.03.0 0.10 max 0.20 max . . . . . . 0.015 max . . . F,GC61300 remainderD 0.200.50 6.07.5 0.15 max 0.01 2.03.0 0.10 max
35、0.20 max . . . . . . 0.015 max . . . F, GC61400 remainderD . . . 6.08.0 . . . 0.01 1.53.5 0.20 max 1.0 max . . . . . . 0.015 max . . . . . .C68700 76.079.0D . . . 1.82.5 . . . 0.07 0.06 max remainder . . . 0.020.06 . . . . . . . . . . . .C70400 remainderD . . . . . . 4.86.2 0.05 1.31.7 1.0 max 0.300
36、.8 . . . . . . . . . . . . . . .C70600 remainderD . . . . . . 9.011.0 0.05 1.01.8 1.0 max 1.0 max . . . . . . . . . . . . . . .C70620 86.5 minD . . . . . . 9.0-11.0 0.02 1.0-1.8 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 maxS.02 maxC71000 remainderD . . . . . . 19.023.0 0.05H 0.501.0 1.0 maxH
37、1.0 max . . . . . . H . . . HC71500 remainderD . . . . . . 29.033.0 0.05 0.401.0 1.0 max 1.0 max . . . . . . . . . . . . . . .C71520 65.0 minD . . . . . . 29.0-33.0 0.02 0.40-1.0 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 maxS.02 maxC71640 remainderD . . . . . . 29.032.0 0.05H 1.72.3 1.0 maxH
38、1.52.5 . . . . . . H . . . C.06 maxS.03maxHC72200 remainderD . . . . . . 15.018.0 0.05H 0.501.0 1.0 maxH 1.0 max . . . . . . H 0.300.70 Si.03maxTi.03maxHA Copper (including silver).A This value is exclusive of silver and shall be determined by difference of “impurity total” from 100 %. “Impurity tot
39、al” is defined as the sum of sulfur, silver, lead, tin, bismuth, arsenic, antimony, iron, nickel, mercury, zinc,phosphorus, selenium, tellurium, manganese, cadmium, and oxygen present in the sample.B Not including Cobalt.C Impurity Additional impurity maximums in ppmpercent for alloy C10100 shall be
40、: antimony 4, arsenic 5, bismuth 1, cadmium 1, iron 10, lead 5, manganese 0.5, mercury 1, nickel 10, oxygen 5, phosphorus 3, selenium3, silver 25, sulfur 15, tellurium 2, tin 2, and zinc 1.bismuth 0.0001, cadmium 0.0001, oxygen 0.0005, selenium 0.0003, sulfur 0.0015, tellurium 0.0002, mercury 0.0001
41、. For C10200, oxygen should be 0.0010 max.D Oxygen in C10200 shall be 10 ppm max. Copper (including silver).E Copper plus sum of named elements shall be 99.95 % min. This includes oxygen-free Cu which contains P in an amount agreed upon.F Silicon Silicon shall be 0.10 % max.G When the product is for
42、 subsequent welding applications and is so specified by the purchaser, chromium shall be 0.05 % max, cadmium 0.05 % max, zinc 0.05 % max, and zirconium 0.05 % max.H When the product is for subsequent welding applications, and so specified by the purchaser, zinc shall be 0.50 % max, lead 0.02 % max,
43、phosphorus 0.02 % max, sulfur 0.02 % max, and carbon 0.05 % max.B111/B111M1634.2 The following options are available and should be but may not be included unless specified at the time of placing of theorder when required:4.2.1 Tension Test required per ASME Boiler and Pressure Vessel Code, Mechanica
44、l PropertiesCode (see Section 8section.).4.2.2 Pressure Hydrostatic or pneumatic test as an alternative to eddy current test (Nondestructive(Section 13Testing Section).).4.2.3 If the cut ends of the tubes do not need to be deburred (Workmanship,(Section 15Finish, and Appearance section).).4.2.4 If t
45、he product is to be subsequently welded (Table 1, Footnotes G and H).4.2.5 Residual Stress TestAmmonia Vapor Test or Mercurous Nitrate Test (Performance(Section 12Requirements Section).).4.2.6 For Ammonia Vapor Test, risk level (pH value) if other than 10.4.2.7 Heat identification or traceability de
46、tails (Number of tests and Retests section).details.4.2.8 Certification (Certification(Section 23Section).).4.2.9 Mill Test Report (Mill(Section 24Test Report Section).).4.2.10 If a subsequent thermal treatment after straightening is required (Temper(Section 7section).).4.2.11 If product is purchase
47、d for agencies of the U.S. Government (see Supplementary Requirements section of thisspecification for additional requirements, if required).5. Materials and Manufacture5.1 MaterialsMaterials: The material shall be of such quality and purity that the finished product shall have the propertiesand cha
48、racteristics prescribed in this specification.5.1.1 The material of manufacture shall be a form of such purity and soundness as to be suitable for processing into the productsprescribed herein.5.1.2 When specified in the contract or purchase order that heat identification or traceability is required
49、, the purchaser shallspecify the details desired.65.2 ManufactureManufacture: The product shall be produced by processes such as casting, extrusion, drawing, annealing,straightening, trimming, and other processes which may produce a seamless tube in the specified condition.5.2.1 The product shall be manufactured by such hot-working, cold-working, annealing, straightening, trimming, and otherprocesses as to produce a uniform seamless tube in the finished product.5.2.2 The product shall be hot- or cold-worked to
