1、NORME INTERNATIONALE CEI IEC INTERNATIONAL STANDARD 61619 Premiredition Firstedition 199704 Numroderfrence Referencenumber CEI/IEC61619:1997 Isolantsliquides Contaminationparlespolychlorobiphnyles(PCB) Mthodededterminationparchromatographie enphasegazeusesurcolonnecapillaire Insulatingliquids Contam
2、inationbypolychlorinatedbiphenyls(PCBs) Methodofdeterminationbycapillarycolumngas chromatographyValiditdelaprsentepublication LecontenutechniquedespublicationsdelaCEIestcons tammentrevuparlaCEIafinquilreflteltatactuelde latechnique. Desrenseignementsrelatifsladatedereconfirmationde lapublicationsont
3、disponiblesauprsduBureauCentralde laCEI. Lesrenseignementsrelatifscesrvisions,ltablis sementdesditionsrvisesetauxamendementspeuvent treobtenusauprsdesComitsnationauxdelaCEIet danslesdocumentscidessous: BulletindelaCEI AnnuairedelaCEI Publiannuellement CataloguedespublicationsdelaCEI Publiannuellemen
4、tetmisjourrgulirement Terminologie Encequiconcernelaterminologiegnrale,lelecteurse reporteralaCEI50:VocabulaireElectrotechniqueInter national(VEI),quiseprsentesousformedechapitres sparstraitantchacundunsujetdfini.Desdtails completssurleVEIpeuventtreobtenussurdemande. Voirgalementledictionnairemultil
5、inguedelaCEI. Lestermesetdfinitionsfigurantdanslaprsentepubli cationonttsoittirsduVEI,soitspcifiquement approuvsauxfinsdecettepublication. Symbolesgraphiquesetlittraux Pourlessymbolesgraphiques,lessymboleslittrauxetles signesdusagegnralapprouvsparlaCEI,lelecteur consultera: laCEI27: Symboleslittraux
6、utiliseren lectrotechnique; laCEI417: Symbolesgraphiquesutilisables surlematriel.Index,relevetcompilationdes feuillesindividuelles; laCEI617: Symbolesgraphiquespourschmas; etpourlesappareilslectromdicaux, laCEI878: Symbolesgraphiquespour quipementslectriquesenpratiquemdicale. Lessymbolesetsignescont
7、enusdanslaprsentepubli cationonttsoittirsdelaCEI27,delaCEI417,dela CEI617et/oudelaCEI878,soitspcifiquementapprouvs auxfinsdecettepublication. PublicationsdelaCEItabliesparle mmecomitdtudes Lattentiondulecteurestattiresurleslistesfigurantlafin decettepublication,quinumrentlespublicationsdela CEIprpar
8、esparlecomitdtudesquiatablila prsentepublication. Validityofthispublication ThetechnicalcontentofIECpublicationsiskeptunder constantreviewbytheIEC,thusensuringthatthecontent reflectscurrenttechnology. Informationrelatingtothedateofthereconfirmationofthe publicationisavailablefromtheIECCentralOffice.
9、 Informationontherevisionwork,theissueofrevised editionsandamendmentsmaybeobtainedfromIEC NationalCommitteesandfromthefollowingIEC sources: IECBulletin IECYearbook Publishedyearly CatalogueofIECpublications Publishedyearlywithregularupdates Terminology Forgeneralterminology,readersarereferredtoIEC50
10、: InternationalElectrotechnicalVocabulary (IEV),whichis issuedintheformofseparatechapterseachdealing withaspecificfield.FulldetailsoftheIEVwillbe suppliedonrequest.SeealsotheIECMultilingual Dictionary. Thetermsanddefinitionscontainedinthepresentpubli cationhaveeitherbeentakenfromtheIEVorhavebeen spe
11、cificallyapprovedforthepurposeofthispublication. Graphicalandlettersymbols Forgraphicalsymbols,andlettersymbolsandsigns approvedbytheIECforgeneraluse,readersarereferredto publications: IEC27: Lettersymbolstobeusedinelectrical technology; IEC417: Graphicalsymbolsforuseon equipment.Index,surveyandcomp
12、ilationofthe singlesheets; IEC617: Graphicalsymbolsfordiagrams; andformedicalelectricalequipment, IEC878:Graphicalsymbolsforelectromedical equipmentinmedicalpractice. Thesymbolsandsignscontainedinthepresentpublication haveeitherbeentakenfromIEC27,IEC417,IEC617 and/orIEC878,orhavebeenspecificallyappr
13、ovedforthe purposeofthispublication. IECpublicationspreparedbythesame technicalcommittee Theattentionofreadersisdrawntotheendpagesofthis publicationwhichlisttheIECpublicationsissuedbythe technicalcommitteewhichhaspreparedthepresent publication.NORME INTERNATIONALE CEI IEC INTERNATIONAL STANDARD 6161
14、9 Premiredition Firstedition 199704 Isolantsliquides Contaminationparlespolychlorobiphnyles(PCB) Mthodededterminationparchromatographie enphasegazeusesurcolonnecapillaire Insulatingliquids Contaminationbypolychlorinatedbiphenyls(PCBs) Methodofdeterminationbycapillarycolumngas chromatography V Pourpr
15、ix,voircatalogueenvigueur Forprice,seecurrentcatalogue CODEPRIX PRICECODE IEC1997Droitsdereproductionrservs Copyrightallrightsreserved Aucunepartiedecettepublicationnepeuttrereproduiteniut ilise sousquelqueformequecesoitetparaucunprocd,lectronique oumcanique,ycomprislaphotocopieetlesmicrofilms,sans
16、laccordcritdelditeur. Nopartofthispublicationmaybereproducedorut ilizedin anyformorbyanymeans,electronicormechanical,including photocopyingandmicrofilm,withoutpermissioninwritingfrom thepublisher InternationalElectrotechnicalCommission Telefax:+41229190300 3,ruedeVarembGeneva,Switzerland IECwebsiteh
17、ttp:/www.iec.ch CommissionElectrotechniqueInternationale InternationalElectrotechnicalCommission email:inmailiec.ch2 61619CEI:1997 SOMMAIRE Pages AVANTPROPOS. . 4 Articles 1 Domainedapplicationetobjet 6 2 Rfrencenormative 6 3 Dfinitions 6 4 Principe 8 5 Ractifsetmatrielsauxiliaires 8 6 Appareillage.
18、 12 7 Echantillon . 16 8 Conditionsopratoiresduchromatographe. 16 9 Systmedetraitementdesdonnes . 18 10 Contrledufonctionnementinstrumental 20 11 Procdure 24 12 Rapportdessai 34 13 Limitededtection . 34 14 Fidlit 36 Annexes A Mlangedessai . 38 B Informationsgnrales. 52 C Bibliographie 6261619IEC:199
19、7 3 CONTENTS Page FOREWORD 5 Clause 1 Scopeandobject 7 2 Normativereference. 7 3 Definitions 7 4 Principle. 9 5 Reagentsandauxiliarymaterials 9 6 Apparatus 13 7 Sample 17 8 Chromatographoperatingconditions 17 9 Dataprocessingsystem . 19 10 Checksofinstrumentalperformance. 21 11 Procedure 25 12 Testr
20、eport . 35 13 Detectionlimit 35 14 Precision 37 Annexes A Testmixtures . 39 B Generalinformations 53 C Bibliography . 624 61619CEI:1997 COMMISSIONLECTROTECHNIQUEINTERNATIONALE ISOLANTSLIQUIDES CONTAMINATIONPARLESPOLYCHLOROBIPHNYLES(PCB) MTHODEDEDTERMINATIONPARCHROMATOGRAPHIE ENPHASEGAZEUSESURCOLONNE
21、CAPILLAIRE AVANTPROPOS 1) LaCEI(CommissionElectrotechniqueInternationale)estuneorganisationmondialedenormalisationcompose delensembledescomitslectrotechniquesnationaux(ComitsnationauxdelaCEI).LaCEIapourobjetde favoriserlacooprationinternationalepourtouteslesquestionsdenormalisationdanslesdomainesde
22、llectricitetdellectronique.Aceteffet,laCEI,entreautresactivits,publiedesNormesinternationales. Leurlaborationestconfiedescomitsdtudes,auxtravauxdesquelstoutComitnationalintressparle sujettraitpeutparticiper.Lesorganisationsinternationales,gouvernementalesetnongouvernementales,en liaisonaveclaCEI,par
23、ticipentgalementauxtravaux.LaCEIcollaboretroitementaveclOrganisation InternationaledeNormalisation(ISO),selondesconditionsfixesparaccordentrelesdeuxorganisations. 2) LesdcisionsouaccordsofficielsdelaCEIconcernantlesquestionstechniquesreprsentent,danslamesure dupossibleunaccordinternationalsurlessuje
24、tstudis,tantdonnquelesComitsnationauxintresss sontreprsentsdanschaquecomitdtudes. 3) Lesdocumentsproduitsseprsententsouslaformederecommandationsinternationales.Ilssontpublis commenormes,rapportstechniquesouguidesetagrscommetelsparlesComitsnationaux. 4) Danslebutdencouragerlunificationinternationale,
25、lesComitsnationauxdelaCEIsengagentappliquerde faontransparente,danstoutelamesurepossible,lesNormesinternationalesdelaCEIdansleursnormes nationalesetrgionales.ToutedivergenceentrelanormedelaCEIetlanormenationaleourgionale correspondantedoittreindiqueentermesclairsdanscettedernire. 5) LaCEInafixaucune
26、procdureconcernantlemarquagecommeindicationdapprobationetsaresponsabilit nestpasengagequandunmatrielestdclarconformelunedesesnormes. 6) LattentionestattiresurlefaitquecertainsdeslmentsdelaprsenteNormeinternationalepeuventfaire lobjetdedroitsdepropritintellectuelleoudedroitsanalogues.LaCEInesauraittr
27、etenuepour responsabledenepasavoiridentifidetelsdroitsdepropritetdenepasavoirsignalleurexistence. LaNormeinternationaleCEI61619attablieparlecomitdtudes10delaCEI:Fluides pourapplicationslectrotechniques. Letextedecettenormeestissudesdocumentssuivants: FDIS Rapportdevote 10/379/FDIS 10/408/RVD Lerappo
28、rtdevoteindiqudansletableaucidessusdonnetouteinformationsurlevoteayant aboutilapprobationdecettenorme. LannexeAfaitpartieintgrantedecettenorme. LesannexesBetCsontdonnesuniquementtitredinformation.61619IEC:1997 5 INTERNATIONALELECTROTECHNICALCOMMISSION INSULATINGLIQUIDS CONTAMINATIONBYPOLYCHLORINATED
29、BIPHENYLS(PCBs) METHODOFDETERMINATIONBY CAPILLARYCOLUMNGASCHROMATOGRAPHY FOREWORD 1) TheIEC(InternationalElectrotechnicalCommission)isaworldwideorganizationforstandardizationcomprising allnationalelectrotechnicalcommittees(IECNationalCommittees).TheobjectoftheIECistopromote internationalcooperationo
30、nallquestionsconcerningstandardizationintheelectricalandelectronicfields.To thisendandinadditiontootheractivities,theIECpublishesInternationalStandards.Theirpreparationis entrustedtotechnicalcommittees;anyIECNationalCommitteeinterestedinthesubjectdealtwithmay participateinthispreparatorywork.Interna
31、tional,governmentalandnongovernmentalorganizationsliaising withtheIECalsoparticipateinthispreparation.TheIECcollaboratescloselywiththeInternationalOrganization forStandardization(ISO)inaccordancewithconditionsdeterminedbyagreementbetweenthetwo organizations. 2) TheformaldecisionsoragreementsoftheIEC
32、ontechnicalmattersexpress,asnearlyaspossible,an internationalconsensusofopinionontherelevantsubjectssinceeachtechnicalcommitteehasrepresentation fromallinterestedNationalCommittees. 3) Thedocumentsproducedhavetheformofrecommendationsforinternationaluseandarepublishedintheform ofstandards,technicalre
33、portsorguidesandtheyareacceptedbytheNationalCommitteesinthatsense. 4) Inordertopromoteinternationalunification,IECNationalCommitteesundertaketoapplyIECInternational Standardstransparentlytothemaximumextentpossibleintheirnationalandregionalstandards.Any divergencebetweentheIECStandardandthecorrespond
34、ingnationalorregionalstandardshallbeclearly indicatedinthelatter. 5) TheIECprovidesnomarkingproceduretoindicateitsapprovalandcannotberenderedresponsibleforany equipmentdeclaredtobeinconformitywithoneofitsstandards. 6) AttentionisdrawntothepossibilitythatsomeoftheelementsofthisInternationalStandardma
35、ybethesubject ofpatentrights.TheIECshallnotbeheldresponsibleforidentifyinganyorallsuchpatentrights. InternationalStandardIEC61619hasbeenpreparedbytechnicalcommittee10:Fluidsfor electrotechnicalapplications. Thetextofthisstandardisbasedonthefollowingdocuments: FDIS Reportonvoting 10/379/FDIS 10/408/R
36、VD Fullinformationonthevotingfortheapprovalofthisstandardcanbefoundinthereporton votingindicatedintheabovetable. AnnexAformsanintegralpartofthisstandard. AnnexesBandCareforinformationonly.6 61619CEI:1997 ISOLANTSLIQUIDES CONTAMINATIONPARLESPOLYCHLOROBIPHNYLES(PCB) MTHODEDEDTERMINATIONPARCHROMATOGRAP
37、HIE ENPHASEGAZEUSESURCOLONNECAPILLAIRE 1 Domainedapplicationetobjet LaprsenteNormeinternationalespcifieunemthodededterminationdelaconcentration despolychlorobiphnyles(PCB)danslesliquidesisolantsnonhalogns,parchromatographie enphasegazeusesurcolonnecapillairehautersolutionutilisantundtecteurcapture d
38、lectrons(ECD). LamthodedonnelateneurtotaleenPCBetestparticulirementutilequanduneanalyse dtailledescongnresdesPCBestncessaire.DautresmthodestellequelaCEI60997 peuventtreutiliseslorsquuneanalysemoinsdtailleestacceptable. Lamthodeestapplicableauxliquidesisolantsneufs,rgnrs(ycomprislesproduits dchlorset
39、traitschimiquementet/ouphysiquement),ouenservicecontaminspardes PCB. 2Rfrence normative Ledocumentnormatifsuivantcontientdesdispositionsqui,parsuitedelarfrencequiyest faite,constituentdesdispositionsvalablespourlaprsenteNormeinternationale.Aumoment delapublication,lditionindiquetaitenvigueur.Toutdoc
40、umentnormatifestsujetrvision etlespartiesprenantesauxaccordsfondssurlaprsenteNormeinternationalesontinvites rechercherlapossibilitdappliquerlditionlaplusrcentedudocumentnormatifindiqu ciaprs.LesmembresdelaCEIetdelISOpossdentleregistredesNormesinternationales envigueur. CEI60475:1974, Mthodedchantill
41、onnagedesdilectriquesliquides 3Dfinitions PourlesbesoinsdelaprsenteNormeinternationale,lesdfinitionssuivantessappliquent: 3.1 Polychlorobiphnyles(PCB) Biphnylesubstituparundixatomesdechlore. NOTEPourlesbesoinslgaux,lescongnresavecun,deuxoudixatomesdechlorepeuventtreexclusde cettedfinition. 3.2 Congn
42、re Touslesdrivschlorsdubiphnyle,quelquesoitlenombredatomesdechlore,sont nommscongnres. NOTEIlya209congnresdePCBpossibles.CeuxcisontrpertorisdansletableauB.1.Lesnumros descongnres(UICPA) * sontdestinsfaciliterleuridentification;ilsnereprsententpaslordredlution chromatographique. * UnionInternationaledeChimiePureetApplique61619IEC:1997 7 INSULATINGLIQUIDS CONTAMINATIONBYPOLYCHLORINATEDBIPHENYLS(PCBs) METHODOFDETERMINATIO
